Thermodynamic Aspects

  • Narayan S. Tavare
Part of the The Springer Chemical Engineering Series book series (PCES)


In this chapter, the thermodynamic aspects required in the analysis of crystallization processes are considered. Solubility characteristics are the first such information that should be known about the crystallizing system and are often key to the industrial operation. They not only provide useful guidelines for the method of supersaturation generation and choice of a crystallizer system, but also help determine the maximum possible yield of crystalline phase.


Barium Sulfate Thermodynamic Aspect Double Salt Triangular Diagram Anhydrous Salt 


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  1. An, So-Song, “Studies on the separation of o- and p-chloronitrobenzene Part 2 Solid-liquid equilibrium of a three-component system,” HwahakKwa Hwahak Kongop 20, 289–294 (1977).Google Scholar
  2. Chivate, M. R. and Shah, S. ML, “Separation of m-cresol and p-cresol by extractive crystallization,” Chem. Eng. Sci. 5, 232–241 (1956).CrossRefGoogle Scholar
  3. Dikshit, R. C. and Chivate, M. R., “Separation of ortho and para nitrochlorobenzenes by extractive crystallization,” Chem. Eng. Sci. 25, 311–317 (1970).CrossRefGoogle Scholar
  4. International Critical Tables (ICT): Vol IV: “Phase equilibria data”, Washburn, E. W. (Ed.), National Research Council, McGraw Hill, New York, pp. 1–432 (1928).Google Scholar
  5. Jadhav, V. K., Chivate, M. R. and Tavare, N. S., “Separation of p-cresol from its mixture with 2,6-xylenol by adductive crystallization,” J. Chem. Eng. Data 36, 249–251 (1991).CrossRefGoogle Scholar
  6. Jadhav, V. K., Chivate, M. R. and Tavare, N. S., “Separation of phenol from its mixture with o-cresol by adductive crystallization,” J. Chem. Eng. Data 37, 232–235 (1992).CrossRefGoogle Scholar
  7. Ostwald, W., “Studien über die bildung und Umwandlung fester körper”, Zeitschrift für Physilische Chemie, 22, 289–330 (1897).Google Scholar
  8. Raynaud-Lacroze, P. O., and Tavare, N. S., “Separation of 2-Naphthol: Hydrotropy and Precipitation,” Ind. Eng. Chem. Res. 32, 685–691 (1993).CrossRefGoogle Scholar
  9. Robinson, R. A. and Stokes, R. H., Electrolyte Solutions, 2nd ed., Butterworth, London (1959).Google Scholar
  10. Taguchi, K., Precipitation of Barium Sulphate: Kinetics of Nucleation and Growth and the Influence of Mixing, Ph. D. thesis, Victoria University of Manchester, Manchester (1993).Google Scholar
  11. Tare, J. P. and Chivate, M. R., “Selection of a solvent for adductive crystallization,” Chem. Eng. Sci. 31, 893–899 (1976a).CrossRefGoogle Scholar
  12. Tare, J. P. and Chivate, M. R., “Separation of close boiling isomers by adductive and extractive crystallizer,” AIChE Symp. Sen No. 153, 72, 95–99 (1976).Google Scholar
  13. Tavare, N. S., “Batch crystallizers: A review,” Chem. Eng. Commun. 61, 259–318 (1987).CrossRefGoogle Scholar

Further Reading

  1. Bowden, S. T.: The Phase Rule and Phase Reactions, MacMillan, London (1938).Google Scholar
  2. Findlay, A. and Campbell, A. N.: The Phase Rule and Its Applications, 9th ed., Longmans, London (1951).Google Scholar
  3. Ferguson, F. D. and Jones T. K.: The Phase Rule, Butterworths, London (1966).Google Scholar
  4. Le Roy, D. J. and Wetmore, F. E. W.: Principles of Phase Equilibria, International Chemical Series, McGraw Hill, New York (1951).Google Scholar
  5. Masing, G.: Ternary Systems, Dover Publications, New York (1944).Google Scholar
  6. Null, H. R.: Phase Equilibria in Process Design, Wiley, New York (1970).Google Scholar
  7. Nyvlt, J.: Solid-Liquid Phase Equilibria, Elsevier, Amsterdam (1977).Google Scholar
  8. Purdon, F. F. and Slater, V. W.: Aqueous Solutions and Phase Diagrams, Arnold and Co., London (1946).Google Scholar
  9. Ricci, J. E.: The Phase Rule and Heterogeneous Equilibrium, Van Nostrand, New York (1951).Google Scholar

Copyright information

© Springer Science+Business Media New York 1995

Authors and Affiliations

  • Narayan S. Tavare
    • 1
  1. 1.University of Manchester Institute of Science and Technology (UMIST)ManchesterUK

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