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Preparation of Silica-Based Membrane for H2 Separation by Multi-Step Pore Modification

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Abstract

Because inorganic membranes have an excellent chemical and thermal stability, they can be used in water desalination, ultrafiltration process in food industries, waste water treatment and separation of gas mixtures.1 Inorganic membrane can be classified into two types; namely, non-porous(dense) membranes and porous membranes.2 The important factors in the membrane separation process are both the permeability and the selectivity. However, the selectivity of a membrane decreases as the permeability increases. This trend is confirmed by the corelation of selectivity versus permeability.3 Since the polymer membrane is non-porous, the fluxes and permeabilities are very small. However, as the separation occurs via the so-called solution-diffusion mechanism, the selectivity of polymer membrane is much high.4 The mechanism of gas separation by a porous alumina membrane or Vycor glass, is closely related to the membrane pore size relative to the permeate molecule size as well as other physical and chemical properties of the membrane and the permeate species.5,6

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References

  1. A.F.M. Leenarrs, K. Keizer and A.J. Burggraaf, The preparation and characterization of alumina membranes with ultra-fine pores — part 1. Microstructural investigations on non-supported membranes J. Mater. Sci. 19 1077–1088 (1984).

    Article  Google Scholar 

  2. J.G Wijmans and R.W. Baker, The solution-diffusion model: a review J. Memb. Sci. 107 1–21 (1995).

    Article  CAS  Google Scholar 

  3. L. M. Robeson, Correlation of separation factor versus permeability for polymeric membrane J. Memb.Sci. 62 165–185 (1991).

    Article  CAS  Google Scholar 

  4. W. J. Koros and G. K., Fleming Membrane-based gas separation J. Memb.Sci. 83 1–80 (1993).

    Article  CAS  Google Scholar 

  5. D. Li and S. T., Hwang Preparation and characterization of silicon based inorganic membrane for gas separation J. Memb.Sci. 59 331–352 (1991).

    Article  CAS  Google Scholar 

  6. R. J. R. Uhlhorm, K. Keizer and A. J. Burrggaaf, Gas and surface diffusion in modified g-alumina systems J. Memb.Sci. 46 225–241 (1989).

    Article  Google Scholar 

  7. Y. K. Cho, K. W. Han, and K. H. Lee, Separation of CO2 by modified γ-Al2O3 membranes at high temperature. J. Memb. Sci. 104 219–230 (1995).

    Article  CAS  Google Scholar 

  8. K. Keizer, R. J. R. Uhlhorn, R. J. V. Vuren and A. J. Burrggaaf, Gas separation mechanisms in microporous modified y-Al2O3 membranes J. Memb. Sci. 39 285–300 (1988).

    Article  CAS  Google Scholar 

  9. A. Yamasaki and H. Inoue, Surface diffusion of organic vapor mixtures through porous glass J. Memb. Sci. 59 233–248 (1991).

    Article  CAS  Google Scholar 

  10. K.-Y. Yoon, J.-H. So, I.-H. Cho, S. B. Park, W.-H. Hong, and S.-M. Yang, Preparation of alumina membrane for hydrogen separation by multi-step pore modification 7th World Filtration Congress, Budapest, Hungary (1996).

    Google Scholar 

  11. S.-J. Lee, S.-M. Yang, and S. B. Park., Synthesis of palladium impregnated alumina membrane for hydrogen separation. J. Memb. Sci. 96 223–232 (1994).

    Article  CAS  Google Scholar 

  12. S.-Y. Lee, S.-J. Lee, S.-J. Kwon, S.-M. Yang, and S. B. Park, Preparation of sol-gel driven alumina membrane modified by soaking and vapor deposition method J. Memb. Sci. 108 97–105 (1995).

    Article  CAS  Google Scholar 

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© 1998 Springer Science+Business Media New York

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So, JH., Yang, SM., Park, S.B. (1998). Preparation of Silica-Based Membrane for H2 Separation by Multi-Step Pore Modification. In: Prasad, P.N., Mark, J.E., Kandil, S.H., Kafafi, Z.H. (eds) Science and Technology of Polymers and Advanced Materials. Springer, Boston, MA. https://doi.org/10.1007/978-1-4899-0112-5_69

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  • DOI: https://doi.org/10.1007/978-1-4899-0112-5_69

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4899-0114-9

  • Online ISBN: 978-1-4899-0112-5

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