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Collective Electronic Oscillations on C60

  • Marek T. Michalewicz
  • Mukunda P. Das

Abstract

The C 60 molecule, known also as buckyball, has a very interesting history. During 1980–85 mass spectroscopic studies of carbon by laser vaporisation of graphite revealed magic numbers of carbon clusters [1,2]. A special stablity was found for C 60 and C 70 in the joint Sussex-Rice experiment [2] and at the same time the correct structure was identified. The structure is analogous to the geodesic domes invented by Buckminster Fuller, hence the name Buckminsterfullerene or in short fullerene. In 1990 fullerene was isolated and a major breakthrough took place after Krätchmer et. al. [3] were successful in producing sizable quantities of the new compound. Apart from C 60 and C 70 other stable 3D cage-shaped molecules, for example C 28, C 32, C 50, C 84, C 240, C 540 were identified. During the past 4–5 years the study of the fullerenes has been fascinating because of several of its remarkable properties, such as the interesting chemistry, crystalline structure and structural transitions, electronic structure, collective electronic and vibrational properties, optical properties, phase transition and ferromagnetism and superconductivity upon doping. [4–10].

Keywords

Valence Electron Local Density Approximation Electron Energy Loss Spectroscopy High Energy Peak Electron Energy Loss Spectroscopy Spectrum 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. [1]
    E.A. Rohlfing, D. Cox and A. Kaldor, J.Chem. Phys., 81 (1984) 3322.ADSCrossRefGoogle Scholar
  2. [2]
    H.W. Kroto, J.R. Heath, S.C. O’Brien, R.F. Curl and R.E. Smalley. Nature, 318, (1985) 162.ADSCrossRefGoogle Scholar
  3. [3]
    W. Krätchmer, L.D. Lamb, K. Fostiropoulos and D.R. Huffman, Nature, 347 (1990) 354.ADSCrossRefGoogle Scholar
  4. [4]
    H.W. Kroto, A.W. Allaf and S.P. Balm, Chem. Rev., 91 (1991) 1213. This review contains extensive references to the original papers on the discovery of C 60..CrossRefGoogle Scholar
  5. [5]
    R. Taylor and R.M. Walton, Nature, 363 (1993) 685.ADSCrossRefGoogle Scholar
  6. [6]
    J.H. Weaver and D.M. Poirier, “Solid state properties of fullerenes and fullerenebased materials” preprint, to appear in: Solid State PhysicsVol. 48, Academic Press, New York, 1994.Google Scholar
  7. [7]
    W.E. Pickett “Electrons and phonons in C60- based materials” preprint, to appear in: Solid State PhysicsVol. 48, Academic Press, New York, 1994.Google Scholar
  8. [8]
    R.C. Haddon, Accounts of Chemical Research 25 (1992) 127.CrossRefGoogle Scholar
  9. [9]
    R.C. Haddon, A.F. Hebard, M.J. Rosseinsky, D.W. Murphy, S.H. Glarum, T.T.M. Palstra, A.P. Ramirez, S.J. Duclos, R.M. Fleming, T. Siegrist and R. Tycko, in: “Fullerenes: Synthesis, properties, and chemistry of large carbon clusters”, G.S. Hammond and V.J. Kuck, Eds., American Chemical Society, 1992, Chapter 5, pp.71-89.Google Scholar
  10. [10]
    The current bibliography on fullerenes can be found by sending a single line message: “BIBLIO” to bucky@soll.lrsm.upenn.edu. To learn about information services on fullerene physics and chemistry on Internet send one line message: “IN-TRO” to the same electronic address.Google Scholar
  11. [11]
    J.H. Weaver, J.L. Martins, T. Komeda, Y. Chen, T.R. Ohno, G.H. Kroll, N. Troullier, R.E. Haufner and R.E. Smalley, Phys. Rev. Lett. 66 (1991) 1741.ADSCrossRefGoogle Scholar
  12. [12]
    Y. Saito, H. Shinohara and A. Ohshita, Jap. J. Appl. Phys. 30, (1991) L1068.ADSCrossRefGoogle Scholar
  13. [13]
    P.L. Hansen, P.S Fallon and W. Kratchmer, Chem. Phys. Lett., 181 (1991) 367.ADSCrossRefGoogle Scholar
  14. [14]
    R. Kuzuo, M. Terauchi, M. Tanaka, Y. Saito and H. Shinohara, Jap. J. Appl. Phys., 30, part B, (1991) L1817.ADSCrossRefGoogle Scholar
  15. [15]
    G. Gensterblum, J.J. Pireaux, P.A. Thiry, R. Caudano, J.P. Vigneron, Ph. Lambin, A.A. Lucas and W. Krätschmer, Phys. Rev. Lett., 67 (1991) 2171.ADSCrossRefGoogle Scholar
  16. [16]
    J.W. Keller and M.A. Coplan, Chem. Phys. Lett, 193 (1992) 89.ADSCrossRefGoogle Scholar
  17. [17]
    A.A. Lucas, J. Phys. Chem. Solids 53 (1992) 1415.ADSCrossRefGoogle Scholar
  18. [18]
    A. Lucas, G. Gensterblum, J.J. Pireaux, P.A. Thiry, R. Caudano, J.P. Vigneron and Ph. Lambin, it Phys. Rev. B 45 (1992) 13694.ADSCrossRefGoogle Scholar
  19. [19]
    Y.M. Shulga, V.I. Rubtsov, A.P. Moravskii and A.S. Lobach, Doklady Acad. Nauk(in Russian) preprint April 1992.Google Scholar
  20. [20]
    E. Sohmen. J. Fink and W. Krätschmer, Z. Phys. BCondensed Matter, 86, (1992) 87.ADSCrossRefGoogle Scholar
  21. [21]
    H. Cohen, E. Kolodney, T. Maniv and M. Folman, Solid State Comm. 81 (1992) 183.ADSCrossRefGoogle Scholar
  22. [22]
    Y. Saito, N. Suzuki, H. Shinohara, T. Hayashi and M. Tomita, Ultramicroscopy, 41 (1992) 1.Google Scholar
  23. [23]
    V.I. Rubtsov and Y.M. Shulga, Zh. Eksp. Teor. Fiz. 103 (1993) 1026.Google Scholar
  24. [24]
    Y.M. Shulga, V.I. Rubtsov and A.S. Lobach, Z. Phys. B(1993) preprint.Google Scholar
  25. [25]
    I.V. Hertel, H. Steger, J. de Vries, B. Weisser, C. Manzel, B. Kamke and W. Kamke, Phys. Rev. Lett. 68 (1992) 784.ADSCrossRefGoogle Scholar
  26. [26]
    J.H. Weaver, in Handbook of Surface Imaging and Visualisation, A.T. Hubbard, Ed., CRC Press, Boca Raton, 1993.Google Scholar
  27. [27]
    Y.M. Shulga, A.P. Moravskii, A.S. Lobach and V.I. Rubtsov, JETP Letters 55 (1992) 132.ADSGoogle Scholar
  28. [28]
    K. Yabana and G.F. Bertsch, Physica Scripta 48 (1993) 633.ADSCrossRefGoogle Scholar
  29. [29]
    K. Yabana and G.F. Bertsch, “Inelastic electron scattering on Ceoclusters” preprint.Google Scholar
  30. [30]
    N. Van Giai and E. Lipparini, Z. Phys. D 27 (1993) 193.ADSCrossRefGoogle Scholar
  31. [31]
    M.T. Michalewicz and M.P. Das, Solid State Comm., 84 (1992) 1121.ADSCrossRefGoogle Scholar
  32. [32]
    Ph. Lambin and A.A. Lucas, Fullerene Science and Technology 1 (1993) 159.CrossRefGoogle Scholar
  33. [33]
    G. Barton and C. Eberlein, J. Chem. Phys., 95, (1991) 1512.ADSCrossRefGoogle Scholar
  34. [34]
    B. Carazza, “On the plasmon-like excitations of atomic clusters with application to fullerene” (1994) preprint.Google Scholar
  35. [35]
    P. Senet, L. Henrard, Ph. Lambin and A.A. Lucas, “A one parameter model of the uv spectra of carbon” Proceedings of The International Winter School on Progress in Fullerene Research, Kirchberg, preprint.Google Scholar
  36. [36]
    Ph. Lambin, A.A. Lucas and J.-P. Vigneron, Phys. Rev. B 46 (1992) 1796.ADSCrossRefGoogle Scholar
  37. [37]
    D. Östling, P. Apell and A. Rosen, Europhys. Lett. 21 (1993) 539.ADSCrossRefGoogle Scholar
  38. [38]
    A. Bulgac and N. Ju, Phys. Rev. B, 46 (1992) 4297.ADSCrossRefGoogle Scholar
  39. [39]
    G.F. Bertsch, A. Bulgac, D. Tomanek and Y. Wang, Phys. Rev. Lett. 67 (1991) 2690.ADSCrossRefGoogle Scholar
  40. [40]
    S.G. Louie and E. L. Shirley, J. Phys. Chem. Solids 54 (1993) 1767.ADSCrossRefGoogle Scholar
  41. [41]
    A.A. Lucas and J.H. Weaver, “Electron spectroscopies of C 60 and C 70 fullerites and füllendes” (1992) preprint.Google Scholar
  42. [42]
    N.W. Ashcroft, Europhys. Lett. 16 355 (1991).ADSCrossRefGoogle Scholar
  43. [43]
    MNDO90 written by M.J.S Dewar and co-workers is a part of UniChem™ quantum chemistry software environment from Cray Research™.Google Scholar
  44. [44]
    M. Abramowitz and I.A. Stegun, Handbook of Mathematical Functions, New York: Dover, 1972, Ch.10.Google Scholar
  45. [45]
    S. Saito and A. Oshiyama, Phys. Rev. Lett. 66 2637 (1991).ADSCrossRefGoogle Scholar
  46. [46]
    S.C. Erwin and W.E. Pickett, Science 254,842(1991).ADSCrossRefGoogle Scholar
  47. [47]
    S. Satpathy, V.P. Antropov, O.K. Andersen, O. Jepson, O. Gunnarsson and A.I. Liechtenstein, Phys. Rev. B (to be published).Google Scholar
  48. [48]
    M. T. Michalewicz, Phys. Rev. B, 45 (1992) 13664.ADSCrossRefGoogle Scholar
  49. [49]
    M. T. Michalewicz, in: Topics in Condensed Matter Physics, M.P. Das, Ed., Nova Science Publishers, New York, 1994.Google Scholar

Copyright information

© Springer Science+Business Media New York 1995

Authors and Affiliations

  • Marek T. Michalewicz
    • 1
  • Mukunda P. Das
    • 2
  1. 1.Supercomputing Support Group, Division of Information TechnologyCommonwealth Scientific and Industrial Research OrganisationCarltonAustralia
  2. 2.Department of Theoretical Physics, Research School of Physical Sciences and EngineeringThe Australian National UniversityAustralia

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