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Scanning Tunneling Microscopy and Atomic Force Microscopy Studies of Conducting Polymer Films

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Atomic Force Microscopy/Scanning Tunneling Microscopy

Abstract

The techniques of scanning tunneling microscopy, tunneling spectroscopy, and atomic force microscopy have been used to study the nanometer-scale morphology of conducting polymer films. Scanning tunneling microscopy and atomic force microscopy allow for images to be obtained with molecular or atomic resolution on these surfaces. The technique of tunneling spectroscopy allows for the study of the local electronic structure on surfaces. In this report, we have investigated the surface structure of aniline, hydroxyaniline and borate functionalized aniline thin films.

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References

  1. E. Genies, A. Boylc, M. Lapkowski, C. Tsintavis, Polyanilinc: a historical survey, Synth. Met.36:139-Ig2 (1990).

    Google Scholar 

  2. G. Zotti, Electrochemical sensors based on polyconjugated conducting polymers, Synth. Met. 51: 373–382 (1992).

    Article  CAS  Google Scholar 

  3. T. Hanawa, H. Hashimoto, S. Kuwabata, H. Yoneyama, Gas sensitivities of electropolymerized polythiophene films, Synth. Met. 30: 173–181 (1989).

    Article  CAS  Google Scholar 

  4. A. Boyle, E. Genies, M. Lapkowski, Application of electronic conducting polymers as sensors: polyaniline in the solid state for detection of solvent vapors and polypyrrole for detection of biological ions in solution, Synth. Met. 28: C769 - C774 (1989).

    Article  CAS  Google Scholar 

  5. T. Skotheim, P. Hale, H. Karan, Y. Okamoto, L. Samuelson, S. Tripathy, Derivatized Polypyrrole langmuir-blodgett films, applications to bioelectronics, Synth. Met. 41–43: 1433–1437 (1991).

    Article  Google Scholar 

  6. L. Couves, S. Porter, Polypyrrole as a potentiometric glucose sensor, Synth. Met. 28: C761 - C768 (1989).

    Article  CAS  Google Scholar 

  7. C. Koopal, R. Czajka, M. Feiters, R. Nolte, B. Ruiter, R. Schasfoort, H. Van Kempen, Polypyrrole microtubles and their use in the construction of a third generation biosensor, Synth. Met. 51: 397–405 (1992).

    Article  CAS  Google Scholar 

  8. B. Wheeler, K. Cantrell, G. Caple, J. Francis, S. Grey, S. Vogel, Electrochemical amine sensors using carboxylate functionalized polythiophent films, J. Electrochem. Soc. 136: 27692770 (1989).

    Google Scholar 

  9. J. Ginder, A. Epstein, A. MacDiarmid, A. Richter, Insulator to metal transition in polyaniline. Solid State Commun. 63: 97–101 (1987).

    Article  CAS  Google Scholar 

  10. J. Travers, F. Genoud, C. Menardo, M. Nechtschein, Polyaniline: a material still under discussion, Synth. Met. 35: 159–168 (1990).

    Article  CAS  Google Scholar 

  11. F. Zuo, M. Angelopoulos, A. Epstein, A. MacDiarmid, Transport studies of protonated emeraldine polymer: a granular polymeric metal system, Phys. Rev. B. 36: 3475–3478 (1987).

    Article  CAS  Google Scholar 

  12. K. Mizoguchi, C. Menardo, M. Nechtschein, J. Travers, Spin dynamics in the conducting polymer polyaniline, Phys. Rev. Lett. 63: 66–69 (1989).

    Article  CAS  Google Scholar 

  13. T. Porter, G. Caple, C. Lee, P. Oden, Surface structural study of poly-hydroxyaniline and aniline(3-aminophenylboronic acid) co-polymer films, J. Vac. Sci. Technol. A10 (4): 606–610 (1992).

    Article  CAS  Google Scholar 

  14. T. Porter, G. Caple, C. Lee, B. Wheeler, Scanning tunneling microscopy studies of substituted polyaniline thin films, J. Vac. Sci. Technol. A9 (3): 1452–1456 (1991).

    Article  CAS  Google Scholar 

  15. D. Bonnell, M. Angelopoulos, Spatially localized electronic structure in polyaniline by scanning tunneling spectroscopy, Synth. Met. 33: 301–310 (1989).

    Article  CAS  Google Scholar 

  16. T. Porter, G. Caple, P. Oden, Surface structural study of poly-hydroxyaniline, Surf Sci. 259: 221–230 (1991).

    Article  CAS  Google Scholar 

  17. T. Porter, G. Caple, R. Dillingham, T. Jones, C. Lee, B. Wheeler, Scanning tunneling microscopy and x-ray photoelectron spectroscopy studies of borate substituted polyaniline, Synth. Met. 40: 187–196 (1991).

    Article  CAS  Google Scholar 

  18. T. Porter, G. Caple, S. Jeffers, R. Swift, B. Wheeler, Scanning tunneling microscopy studies of polythiophene and poly-3-bromothiophene films, Surf. Sci. 238: L433 - L438 (1990).

    Article  CAS  Google Scholar 

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© 1994 Springer Science+Business Media New York

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Porter, T.L. (1994). Scanning Tunneling Microscopy and Atomic Force Microscopy Studies of Conducting Polymer Films. In: Cohen, S.H., Bray, M.T., Lightbody, M.L. (eds) Atomic Force Microscopy/Scanning Tunneling Microscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9322-2_24

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  • DOI: https://doi.org/10.1007/978-1-4757-9322-2_24

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9324-6

  • Online ISBN: 978-1-4757-9322-2

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