Applications of AC Complex Impedance Spectroscopy to Fast Ion Conducting Lithium Silicate Gels

  • Lisa C. Klein
  • Shu-Fang Ho
  • Sung-Ping Szu
  • Martha Greenblatt

Abstract

Alkali silicate gels, and in particular, lithium silicate gels, have been studied over the last ten years because they represent a new approach to preparing fast ion conductors.1Initially, the idea was that gel-prepared alkali silicates and conventional melted alkali silicates were chemically and structurally identical.2, 3 This turns out not to be the case.4The fact that gel-prepared glasses and conventional glasses are not identical in all ways has set off an explosion of experimental studies on gels.5, 6 At the same time, this fact has created an expectation that physical properties, especially transport properties, will not be the same in gel-prepared and conventional silicates of similar composition. Based on this expectation, the interest in transport properties has increased and many fast ion conductors from gels have been synthesized and characterized.7

Keywords

Porosity Hydrolysis Crystallization Silicate Mold 

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Copyright information

© Springer Science+Business Media New York 1991

Authors and Affiliations

  • Lisa C. Klein
    • 1
  • Shu-Fang Ho
    • 1
  • Sung-Ping Szu
    • 1
  • Martha Greenblatt
    • 1
  1. 1.Ceramics DepartmentRutgers - The State University of New JerseyPiscatawayUSA

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