Characterization of Biomass Ashes

  • Bengt-Johan Skrifvars
  • Mikko Hupa
  • Antero Moilanen
  • Ragnar Lundqvist

Abstract

Energy production from combustion or gasification of biomass has recently attracted increased interest. These fuels form a valuable indigenous energy resource for some countries. They represent also an attractive way to decrease CO2 emissions from the energy production. The development of new combustion and gasification techniques, such as atmospheric or pressurized fluidized bed combustion and gasification has also made it possible to utilize biomass in a more feasible way than before. The availability of these new energy conversion systems is, however, still unknown. Among other questions the behavior of ash can be critical.

In this paper we present some initial results from an ash characterization work performed on 10 different types of biomass ashes with the focus on the new energy conversion systems. The characterization methods were the following:
  1. 1)

    Ash thermal behavior analyzed with a combined differential thermal, thermogravimetric analyzer (DTA/TGA).

     
  2. 2)

    Ash sintering tendency with the compression strength sintering testing method. Ashes tested in both oxidizing and reducing conditions, in temperatures ranging from 500–1000°C. Selected ashes tested further in 100% CO2(g).

     
  3. 3)

    Chemical analyses of the ashes and sintering tested samples.

     
  4. 4)

    Standard fuel characterization analyses.

     
  5. 5)

    Reactivity analyses for selected biomasses.

     

The results showed clear differences in the thermal behavior of the ashes. The sintering tendencies varied significantly. The chemical analyses showed that ashes rich in silicon started to sinter at 800–900°C both in oxidizing and reducing conditions, while ashes with low silicon content did not. These ashes showed instead an increase in sintering at approximately 700°C and a decrease above 700°C when CO2(g) was present in the gas atmosphere. In some cases the sintering tendency of the ash also correlated with the gasification reactivity of the corresponding biomass.

The results and their relevance to full scale conversion systems are discussed in the paper.

Keywords

Biomass Combustion Furnace Silicate Steam 

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References

  1. Barnhart, D. H., Williams, P. C.: Trans. ASME 78, 1229 (1956).Google Scholar
  2. Baxter, L.: Biomass and Bioenergy 4 (2), 89 (1993)CrossRefGoogle Scholar
  3. Dawson, M., Brown, R., C.: Fuel 71, 585 (1991).CrossRefGoogle Scholar
  4. Hupa, M., Skrifvars, B-J., Moilanen, A.: J. Inst. Energy 62, 131 (1989)Google Scholar
  5. Moilanen, A., Kurkela, E.: Gasifications reactivity of solid biomass fuels, Proc. of the 210th ACS Div. of Fuel Chemistry Conference, Vol. 40, No 3, pp. 688–693, 1995.Google Scholar
  6. Nordin, A.: Fuel 74, 615 (1995)CrossRefGoogle Scholar
  7. Nordin, A., Skrifvars, B-J, Öhman, M., Hupa, M.: “Agglomeration and defluidization in FBC of biomass fuels - Mechanisms and measures for prevention”, presented at the Eng. Found. Conf., July 16–21, 1995, Waterville Valley, NH, USAGoogle Scholar
  8. Skrifvars, B-J., Hupa, Hyöty, P.: J. Inst. Energy 64, 196 (1991)Google Scholar
  9. Skrifvars, B-J., Hupa, Hiltunen, M.: Ind. & Eng. Chem. Res. 31, 1026 (1992)CrossRefGoogle Scholar
  10. Skrifvars, B-J., Hupa, Backman, R., Hiltunen, M.: Fuel 73, 171 (1994)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1996

Authors and Affiliations

  • Bengt-Johan Skrifvars
    • 1
  • Mikko Hupa
    • 1
  • Antero Moilanen
    • 2
  • Ragnar Lundqvist
    • 3
  1. 1.Åbo Akademi UniversityTurkuFinland
  2. 2.VTT EnergyEspooFinland
  3. 3.Foster Wheeler Energia OYHelsinkiFinland

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