Skip to main content
SpringerLink
Log in
Book cover

Advances in Polyolefins pp 393–404Cite as

13C NMR Spectra of Polyolefins

  • Conference paper

  • 218 Accesses

Abstract

13C NMR spectroscopy has been used successfully to study ethylene and propylene polymers. Some common polymer systems are summarized as follows:

C3 — → isotactic C3 — → irregular C3

C2 — → stereoregular C2C3 — → EPR — → ethylene-propylene oil

where polymer microstructure becomes increasingly complex as one moves from left to right. The 13C NMR spectral features correspondingly increase in complexity from left to right. C2 and C3 refer to ethylene and propylene respectively.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. F. A. Bovey, Polymer Preprints, 10 (1), 9 (1969).

    CAS  Google Scholar 

  2. A. Zambelli, P. Locatelli, G. Bajo, and F. A. Bovey, Macromolecules, 8, 687 (1978).

    Article  Google Scholar 

  3. A. Zambelli, P. Locatelli, A. Provasoli, and D. R. Ferro, Macromolecules, 13, 267 (1980).

    Article  CAS  Google Scholar 

  4. F. C. Schilling and A. E. Tonelli, Macromolecules, 13, 270 (1980).

    Article  CAS  Google Scholar 

  5. H. N. Cheng and G. H. Lee, Polymer Bull., 13, 549 (1985).

    Article  CAS  Google Scholar 

  6. T. Asakura, I. Ando, A. Nishioka, Y. Doi, and T. Keii, Makromol. Chem., 178, 791 (1977).

    Article  CAS  Google Scholar 

  7. Y. Doi, Macromolecules, 12, 248 (1979).

    Article  CAS  Google Scholar 

  8. Y. Doi, Makromol. Chem., 180, 2447 (1979).

    Article  CAS  Google Scholar 

  9. H. N. Cheng, Polymer Bull., in press.

    Google Scholar 

  10. G. J. Ray, P. E. Johnson, and J. R. Knox, Macromolecules, 10, 773 (1977).

    Article  CAS  Google Scholar 

  11. J. M. Sanders and R. A. Komoroski, Macromolecules, 10, 1214 (1977).

    Article  CAS  Google Scholar 

  12. J. R. R. Paxson and J. C. Randall, Anal. Chem., 50, 1977 (1978).

    Article  Google Scholar 

  13. E. G. Brame, Jr. and H. E. Holmquist, Rubber Chem. Technol., 52, 1 (1979).

    Article  CAS  Google Scholar 

  14. H. N. Cheng, Anal. Chem., 54, 1828 (1982).

    Article  CAS  Google Scholar 

  15. C. J. Carman, R. A. Harrington, and C. E. Wilkes, Macromolecules, 10, 536 (1977).

    Article  CAS  Google Scholar 

  16. J. C. Randall, Macromolecules, 11, 33 (1978).

    Article  CAS  Google Scholar 

  17. W. V. Smith, J. Polymer Sci., Polymer Phys., Ed., 18, 1587 (1980).

    Article  CAS  Google Scholar 

  18. H. N. Cheng, Macromolecules, 17, 1950 (1984).

    Article  CAS  Google Scholar 

  19. H. N. Cheng and D. A. Smith, Paper presented at the National ACS meeting in Washington, D.C., 1983; manuscript in preparation.

    Google Scholar 

  20. H. N. Cheng and S. J. Ellingsen, J. Chem. Inf. Computer Sci., 23, 197 (1983).

    Article  CAS  Google Scholar 

  21. H. N. Cheng and M. A. Bennett, Anal. Chem., 56, 2320 (1984).

    Article  CAS  Google Scholar 

  22. A. Zambelli and G. Gatti, Macromolecules, 11, 485 (1978).

    Article  CAS  Google Scholar 

  23. A. Zambelli, G. Bajo, and E. Rigamonti, Makromol. Chem., 179, 1249 (1978).

    Article  CAS  Google Scholar 

  24. A. Zambelli, P. Locatelli, and G. Bajo, Macromolecules, 12, 154 (1979).

    Article  CAS  Google Scholar 

  25. A. Zambelli, M. C. Sacchi, and P. Locatelli, Macromolecules, 12, 783 (1979).

    Article  CAS  Google Scholar 

  26. A. E. Tonelli, Macromolecules, 11, 634 (1978).

    Article  CAS  Google Scholar 

  27. F. C. Schilling and A. E. Tonelli, Accts. Chem. Res., 14, 233 (1981).

    Article  Google Scholar 

  28. P. Freche, M.-F. Grenier-Loustalot, F. Metras, and A. Gascoin, Makromol. Chem., 184, 569 (1983).

    Article  CAS  Google Scholar 

  29. M. Moeller and H.-J. Cantor, Macromolecules, 17, 733 (1984).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Hercules Incorporated, Research Center, Wilmington, Delaware, 19894, USA

    H. N. Cheng & M. A. Bennett

Authors
  1. H. N. Cheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. A. Bennett
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. University of Southern Mississippi, Hattiesburg, Mississippi, USA

    Raymond B. Seymour

  2. Advanced Polymer Systems, Redwood City, California, USA

    Tai Cheng

Rights and permissions

Reprints and permissions

Copyright information

© 1987 Springer Science+Business Media New York

About this paper

Cite this paper

Cheng, H.N., Bennett, M.A. (1987). 13C NMR Spectra of Polyolefins. In: Seymour, R.B., Cheng, T. (eds) Advances in Polyolefins. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9095-5_29

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-9095-5_29

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9097-9

  • Online ISBN: 978-1-4757-9095-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation