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Increased Superconducting Critical Current Density in Internal Tin Niobium-Tin (Nb3Sn) Composite Wires by Magnesium Doping

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Advances in Cryogenic Engineering Materials

Part of the book series: An International Cryogenic Materials Conference Publication ((ACRE,volume 40))

Abstract

Requirements for AC superconducting machines such as ITER, MagLev, and power applications continue to drive the development of superconducting wires. There are several challenges in producing wire with good properties for AC applications. Nb-Ti composite wires have been manufactured with sub-micron filaments, often at the cost of a significant reduction in the critical current density (Jc).1 For Nb3Sn wire, the physical filament diameter (d) is often much smaller than the effective filament diameter (deff) due to coupling of the filaments during the reaction heat treatment. Filament coupling causes significant increases in the cooling load per cycle relative to uncoupled filaments. The increase in power dissipation per cycle may affect the magnet stability and in the case of cable in conduit conductors it may shorten the length of cable cooled by a single helium inlet.

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References

  1. I. Hlasnik, et al., “Properties of superconducting NbTi superfine filament composites with diameters _0.1 µm,” Cryogenics, 25: 558 (1985).

    Article  CAS  Google Scholar 

  2. W.K. McDonald, “Composite construction process and superconductor produced thereby,” United States Patent #4, 262, 412 (1981).

    Google Scholar 

  3. W.K. McDonald, “Expanded metal containing wires and filaments,” United States Patent #4, 414, 428 (1983).

    Google Scholar 

  4. D.B. Smathers, “Process for making filamentary superconductors using tin-magnesium eutectics,” United States Patent #4973527 (1990).

    Google Scholar 

  5. D.B. Smathers, “Alloy core modifications for tin core superconducting materials,” United States Patent #5098798 (1992).

    Google Scholar 

  6. D.B. Smathers, Al5 superconductors, in:“Metals Handbook,” volume 2, 10th edition, ASM International (1990).

    Google Scholar 

  7. K. Togano, T. Asano, K. Tachikawa, “Effects of magnesium addition to the Cu-Sn matrix in the composite processed Nb3Sn superconductor,” J. Less Common Metals, 68: 15 (1979).

    Article  CAS  Google Scholar 

  8. I.W. Wu, et al., “The influence of magnesium addition to the bronze on the critical current of bronze-processed multifilamentary Nb3Sn,” IEEE Trans. Mag., Mag-19: 1437 (1983).

    Google Scholar 

  9. T. Kuroda, et al., “Internal-tin-processed Nb3Sn multifilamentary wires alloyed with Mg, Zn + Ti, and Tithrough the Sn core,” Adv. Cryo. Eng. Matt., 32: 1108 (1986).

    Google Scholar 

  10. I.W. Wu, et al., “Critical current density of bronze-processed multifilamentary Nb3Sn wires with magnesium addition to the matrix,” App. Phys. Let., 45: 792 (1984).

    Google Scholar 

  11. J.Q. Xu, et al., “Superconducting and metallurgical properties of Nb3Sn wires processed by internal tin route including hydrostatic extrusion,” Cryogenics, 29: 87 (1989).

    Article  CAS  Google Scholar 

  12. A. Borsese, et al., “Heat of formation of magnesium-tin alloys,” Zeitschrift fur Metallkunde, 66: 226 (1975).

    Google Scholar 

  13. M.B. Siddall and D.B Smathers, “Method for critical current testing: software corrections,” IEEE Trans. Mag., Mag-25: 1823 (1989).

    Google Scholar 

  14. M. Hansen, “Constitution of Binary Alloys,” McGraw-Hill Book Company, New York (1958).

    Google Scholar 

  15. J. Ellmer, et al., “On the liquidus in tin-rich Sn-Mg alloys,” Met. Trans., 4: 889 (1973).

    Google Scholar 

  16. J.W. Ekin, “Effect of uniaxial strain on Nb3Sn with Mg additions,” NBS-IR, 86–3044: 30 (1986).

    Google Scholar 

  17. Y.A. Chang, et al. “Phase Diagrams and Thermodynamic properties of ternary copper-metal systems,” International Copper Research Association, Inc. (1979).

    Google Scholar 

  18. D.B. Smathers, et al., “Properties of idealized designs of Nb3Sn composites,” IEEE Trans. Mag., Mag-21: 1133 (1985).

    Google Scholar 

  19. K.R. Marken, et al., “Characterization studies of a fully reacted high bronze to niobium ratio filamentary Nb3Sn composite,” Adv. Cryo. Eng. Mati., 32: 967 (1986).

    Article  CAS  Google Scholar 

  20. K.R. Marken, “Characterization Studies of Bronze-Process Filamentary Nb3Sn Composites,” Ph.D. Thesis, University of Wisconsin-Madison (1986).

    Google Scholar 

  21. K. Tachikawa, et al., “Composite processed V3Cu with improved current-carrying capacities in high magnetic fields,” IEEE Trans. Mag., Mag-15: 391 (1979).

    Google Scholar 

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© 1994 Springer Science+Business Media New York

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McKinnell, J.C., Siddall, M.B., O’Larey, P.M., Smathers, D.B. (1994). Increased Superconducting Critical Current Density in Internal Tin Niobium-Tin (Nb3Sn) Composite Wires by Magnesium Doping. In: Reed, R.P., Fickett, F.R., Summers, L.T., Stieg, M. (eds) Advances in Cryogenic Engineering Materials . An International Cryogenic Materials Conference Publication, vol 40. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-9053-5_121

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  • DOI: https://doi.org/10.1007/978-1-4757-9053-5_121

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-9055-9

  • Online ISBN: 978-1-4757-9053-5

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