Abstract
The reaction was carried out in a 100-ml round-bottomed flask fitted with reflux condenser protected by a calcium chloride tube. In order to trap the hydrogen chloride and sulfur dioxide formed in the reaction the end of the calcium chloride tube was connected to a Tishchenko vessel containing a solution of caustic alkali. A solution of 12.6 g (0.1 mole) of 5-methy1–2-furoic acid (see p. 23), m.p. 108–109°, in 40 ml of dry benzene was introduced into the flask, and a solution of 13.1 g (0.11 mole) of freshly distilled thionyl chloride in 30 ml of dry benzene was added.
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Literature Cited
H. B. Hill and C. R. Sanger, Am. Chem. J. 20, 171 (1898).
A. L. Mndzhoian, V. G. Afrikian, and M. T. Grigorian, Doklady Akad. Nauk Arm. SSR (Proc. Acad. Sci. Armenian SSR) 17, 169 (1953)
J. R. Willard and C. S. Hamilton, J. Am. Chem. Soc. 75, 237 (1953).
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Mndzhoian, A.L. (1959). 5-Methyl-2-Furoyl Chloride. In: Mndzhoian, A.L. (eds) Syntheses of Heterocyclic Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6658-5_25
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DOI: https://doi.org/10.1007/978-1-4757-6658-5_25
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