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Disjoining Pressure

  • B. V. Derjaguin
  • N. V. Churaev
  • V. M. Muller

Abstract

Chapter 1 gave a general outline of the effects of long-range forces at interfaces. Surface forces of two kinds must be distinguished. First, there are the forces acting in the interfacial region on molecules, leading to departures of the appropriate intensive properties from their values in the bulk phase. These forces or effects are either of a dispersion nature (molecular or van der Waals forces, as will be discussed in Chapter 4), or originate with the macroscopic electrostatic field created by a nonuniform distribution of ions of both signs (formation of ionic double layers) or, finally, are functions of a special structure of interfacial layers. These forces and effects are responsible for the appearance and magnitude of the interfacial tension and potential jump. The study of interfacial molecular forces has a long history, but these forces are not discussed in detail in the present monograph.

Keywords

Bulk Phase Surface Force Mechanical Equilibrium Disjoin Pressure Pressure Tensor 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1987

Authors and Affiliations

  • B. V. Derjaguin
    • 1
  • N. V. Churaev
    • 1
  • V. M. Muller
    • 1
  1. 1.Institute of Physical ChemistryAcademy of Sciences of the USSRMoscowUSSR

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