Skip to main content

Surfaces of Small Particles

  • Chapter
Small Particles Technology

Abstract

Modern surface physics, using techniques such as x-ray photoelectron spectroscopy, XPS, low-energy ion scattering, LEIS, Auger Electron spectroscopy, AES, secondary ion mass spectroscopy, SIMS, electron microscopy of different types, thermal desorption spectroscopy, and several other techniques, makes possible a detailed characterization of the surface of small particles in particular. Common to all these techniques, however, is that the material must be studied as a dry solid and often under very low pressure. Many of the small particles discussed in this book, on the other hand, are born in water and in most applications they are used, at least initially, in the form of aqueous dispersions. The surface of the small particles will, of course, be affected by the water and indeed other components present in the dispersion. Moreover, the surface properties of small particles in aqueous dispersions can often be drastically changed by deliberate modification of the particle surface. The most important methods for studying the properties of small particles in aqueous dispersions are acid-base titration, electrophoresis, and adsorption of cations, usually metal cations and anions, onto the particles.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Alexander, G. B., U. S. Patent 2,913, 419 (1956).

    Google Scholar 

  • Alexander, G. B., U. S. Patent 2,974, 108 (1961).

    Google Scholar 

  • Alexander, G. B., and Iler, R. K., U. S. Patent 2,897, 797 (1959).

    Google Scholar 

  • Alexander, G. B., and Iler, R. K., U. S. Patent 3,007, 878 (1961).

    Google Scholar 

  • Asplund, T. and Otterstedt, J-E., unpublished work (1995).

    Google Scholar 

  • Allen, L. H., and Matijevic, E., J. Colloid and Interface Sci., 31, 287 (1969).

    Article  CAS  Google Scholar 

  • Allen, L. H., and Matejevic, E., J. Colloid and Interface Sci., 33, 420 (1970).

    Article  Google Scholar 

  • Baudin, I., Ricard, I., and Audebert, R., J. Colloid Interface Sci. 138, 324 (1990).

    Article  CAS  Google Scholar 

  • Bergna, H. E., U. S. Patent 4,217, 240 (1980).

    Google Scholar 

  • Bergna, H. E., The Colloid Chemistry of Silica. Advances in Chemistry Series 234, American Chemical Society, Washington, D. C. (1994).

    Google Scholar 

  • Bleier, A., and Goddard, E.D., Colloids and Surfaces, 1, 407 (1980).

    Article  CAS  Google Scholar 

  • Brinker, C. J., and Scherer, G. W. Sol-Gel Science, Academic Press, San Diego, 1990.

    Google Scholar 

  • Buchhammer, H-M., Kramer, G., and Lunkwitz, K., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 95, 299 (1995).

    Article  CAS  Google Scholar 

  • Buchhammer, H-M., Petzhold, G., and Lunkwitz, K., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 76, 81 (1993).

    Article  CAS  Google Scholar 

  • Cattania, M. G., Ardizzone, S., Bianchi, C. L., and Carella, S., Colloids Surf., 76, 233 (1993).

    Article  CAS  Google Scholar 

  • De Boer, R. K., Angew. Chem., 75, 383 (1985).

    Google Scholar 

  • De Boer, R. K., and Vleeskens, J. M. K., Ned. Akad. Wet. Ser. B, 61, 2 (1958).

    Google Scholar 

  • Denoyel, R., Darand, G., Lafuma, F., and Audebert, R., J. Colloid Interface Sci 139, 281 (1990).

    Article  CAS  Google Scholar 

  • Evans, D. F., and Wennerström, H., The Colloidal Domain, VCH Publishers (1994).

    Google Scholar 

  • Everett, D.H., Basic Principles of Colloid Science, Royal Society of Chemistry, London (1988).

    Google Scholar 

  • Firment, L.E., Bergna, H.E., Swartzfager, D.G., Bierstedt, P.E., and van Kavelaar, M. L., Surface Interface Anal., 14, 46 (1989).

    Article  CAS  Google Scholar 

  • Furlong, D. N,The Colloid Chemistry of Silica. Advances in Chemistry Series, 234. American Chemical Society, Washington, D. C. (1994).

    Google Scholar 

  • Garg, A., and Matijevic, E., Langmuir, 4, 38 (1988).

    Article  CAS  Google Scholar 

  • Greenwood, P., and Otterstedt, J-E., unpublished work (1996).

    Google Scholar 

  • Hingston, F. J., and Raupach, M., Austral. J. Soil Res., 5, 295 (1967).

    Article  CAS  Google Scholar 

  • Hohl, H., and Stumm, W., J. Colloid Interface Sci., 43, 409 (1976).

    Google Scholar 

  • Hsu, W. P., Rönnquist, L., and Matijevic, E., Langmuir 8, 31 (1988).

    Google Scholar 

  • Iler, R. K., J. Phys. Chem., 56, 673 (1952).

    Article  CAS  Google Scholar 

  • Iler, R. K., The Colloid Chemistry of Silica and Silicates, Cornell University Press, NY (1955).

    Google Scholar 

  • Iler, R. K., U. S. Patent 2,885, 366 1956 ).

    Google Scholar 

  • Iler, R. K., U. S. Patent 2,885, 366 1959 ).

    Google Scholar 

  • Iler, R. K., J. Colloid Interface Sci., 43, 399 (1973).

    Article  CAS  Google Scholar 

  • Iler, R. K., J. Colloid Interface Sci., 55, 25 (1976).

    Article  CAS  Google Scholar 

  • Iler, R. K., The Chemistry of Silica, John Wiley, New York (1979).

    Google Scholar 

  • Iler, R.K., J. Colloid Interface Sci., 75, 138 (1980).

    Article  CAS  Google Scholar 

  • Israelachvili, J Intermolecular and Surface Forces,2nd ed., Academic Press, London, 291 (1992).

    Google Scholar 

  • James, R. O. and Parks, G. A., Characterization of Aqueous Colloids by their Electrical Double Layer and Intrinsic Surface Chemical Properties. Surface and Colloid Science. E. Matijevic (ed.), Plenum Press, New York (1987).

    Google Scholar 

  • Kawaguchi, M., Kawaguchi, H., and Takahashi, A., J. Colloid Interface Sci., 124, 57 (1988).

    Google Scholar 

  • Killmann, E. and Sapuntzjis, P., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 86, 229 (1994).

    Article  CAS  Google Scholar 

  • Killmann, E., Sapuntzjis, P., and Maier, P., Macromol. Chem., Macromol. Symp., 61, 42 (1992).

    CAS  Google Scholar 

  • Kondo, S., Igarashi, M. and Nakai, K., Colloids and Surfaces, 63, 33 (1992).

    Article  CAS  Google Scholar 

  • James, R. O., and Healy, T. W., J. Colloid Interface Sci., 40, 42 (1972).

    Google Scholar 

  • Kirk, J. S., U. S. Patents 2,408,654–2, 408, 656 (1946).

    Google Scholar 

  • Lekki, J., and Lakowski, J., Trans. IMM, 80, 174 (1971).

    CAS  Google Scholar 

  • Liu, J. C., and Huang, C. P., Langmuir, 8, 1851 (1992).

    Article  CAS  Google Scholar 

  • MacMobility Program, Department of Mathematics, University of Melbourne, Parkville, Victoria 3052, Australia.

    Google Scholar 

  • Matijevic, E., and Allen, L. H., Sci. Technol., 3, 264 (1969).

    Article  CAS  Google Scholar 

  • Matijevic, E., and Schemer, P., J. Colloid Interface Sci., 63, 509 (1978).

    Article  CAS  Google Scholar 

  • Mabire, F., Audebert, R., and Quivoron, C., J. Colloid Interface Sci., 97, 120 (1984).

    Article  CAS  Google Scholar 

  • Milonjic, S. L., Colloids and Surfaces, 63, 113 (1992).

    Article  CAS  Google Scholar 

  • Mindick, M., and Thompson, A. C., U. S. Patent 3,252, 917 (1966).

    Google Scholar 

  • Moore, E. P., U. S. Patent 3,620, 978 (1971).

    Google Scholar 

  • Moudgil, M. and Somasundaran, P., Fundamentals of Adsorption, Proc. of the Engineering Foundation Conference, Schloss Elman, Fed. Rep. Ger., 355 (1984).

    Google Scholar 

  • Oestreicher, C. A., and McGlashan, D. W., AMME Annual Meeting, San Francisco, (1972).

    Google Scholar 

  • Otterstedt, J-E., unpublished work (1995).

    Google Scholar 

  • Otterstedt, O. E., Otterstedt, J-E., Ekdahl, J., Backman, J., and Anderson, C-H., J. Appl. Polym. Sci., 34, 2575 (1987).

    Article  CAS  Google Scholar 

  • Park, S. W., and Huang, C. P., J. Colloid Interface Sci., 117, 431 (1987)

    Article  CAS  Google Scholar 

  • Parks, G. A., Chem. Rev., 65, 177 (1965).

    Article  CAS  Google Scholar 

  • Partyka, S., Lindheimer, M., and Faucompre, B., Colloids and Surfaces A: Physicochemical and Engineering Aspects, 76, 267 (1993).

    Article  CAS  Google Scholar 

  • Pulfer, K., Schindler, P. W., Westall, J. C., and Grauer, R., J. Colloid Interface Sci., 101, 554 (1984).

    Article  CAS  Google Scholar 

  • Schindler, P. W., and Stumm, W., Aquatic Surface Chemistry: Chemical Processes at the Particle-Water Interface. Stumm, W.(ed.) John Wiley, New York (1987).

    Google Scholar 

  • Schindler, P. W., Fürst, B., Dick, R., and Wolf, P. U., J. Colloid Interface Sci., 55, 469 (1976).

    Article  CAS  Google Scholar 

  • Shaw, D. H., Introduction to Colloid and Surface Chemistry, Butterworths, London (1970).

    Google Scholar 

  • Stöber, W., Bauer, G., and Thomas, K., Ann. Chem., 604, 104 (1957).

    Article  Google Scholar 

  • Stumm, W., Kummert, R., and Sigg, L., Croatica Chemica Acta, 53, 292 (1980).

    Google Scholar 

  • Tada, H., Saitoh, Y., Miyata, K., Kawahara, H., J. Jpn. Soc. Colour Mater., 62, 399 (1989).

    CAS  Google Scholar 

  • Törncrona, A. and Otterstedt, J-E., unpublished work (1990).

    Google Scholar 

  • Törncrona, A., Löwendahl, L., Otterstedt, J-E., and Jansson, K., J. Mater. Chem., 6, 213 (1996).

    Article  Google Scholar 

  • Törncrona, A., Sterte, J., and Otterstedt, J-E.,J. Mater. Chem., 5, 121 (1995).

    Article  Google Scholar 

  • Vordonis, L., Akratopolu, A., Koutsoukos, P. G., and Lycourghiotis, A., Preparation of Catalyst IV, Louvain-la-Neuve, 309, Elsevier, Amsterdam (1987).

    Google Scholar 

  • Wang, T.K., and Audebert, R., J. Colloid Interface Sci., 119, 459 (1987).

    Article  CAS  Google Scholar 

  • Westall, J., and Hohl, H., Advan. Colloid Interface Sci., 2, 265 (1980).

    Article  Google Scholar 

  • Wong, K., Cabane, B., and Duplessix, R., J. Colloid Interface Sci., 123, 466 (1988).

    Article  CAS  Google Scholar 

  • Zhuravlev, L. T. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 74, 71 (1993).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1998 Springer Science+Business Media New York

About this chapter

Cite this chapter

Otterstedt, JE., Brandreth, D.A. (1998). Surfaces of Small Particles. In: Small Particles Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6523-6_6

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-6523-6_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4419-3301-0

  • Online ISBN: 978-1-4757-6523-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics