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Photophysical and Photochemical Properties of Gold(l) Complexes

  • Chapter
Book cover Optoelectronic Properties of Inorganic Compounds

Part of the book series: Modern Inorganic Chemistry ((MICE))

Abstract

Transition metal complexes with an open-shell configuration (dn, n < 10) have received considerable attention for their interesting photophysical properties. The binuclear metal-metal bonded complexes of RhI, IrI, and PtII display rich photochemistry.1 One example of particular interest is the PtII complex, [Pt2(H2P2O5)4]4−, which has an excited state that is better oxidant and reductant than its ground state,2 and undergoes facile atom-transfer reactions with a variety of organic substrates.3 However, perhaps the most extensively studied transition metal complexes in this area are based on [Ru(bpy)3]2+, bpy = bipyridine. The complexes have been used in the study of both electron and energy transfer reactions and contributed a great deal to the understanding of photochemistry in inorganic systems.4

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Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, TX, 77843-3255, USA

    Jennifer M. Forward & John P. Fackler Jr.

  2. Oak Ridge National Laboratory, Chemical and Analytical Sciences Division, Oak Ridge, TN, 37831-6375, USA

    Zerihun Assefa

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  1. Jennifer M. Forward
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  2. John P. Fackler Jr.
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Editors and Affiliations

  1. Department of Chemistry and Biochemistry, Texas Tech University, 79409-1061, Lubbock, Texas, USA

    D. Max Roundhill

  2. Department of Chemistry, Texas A&M University, 77843-3255, College Station, Texas, USA

    John P. Fackler Jr.

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Forward, J.M., Fackler, J.P., Assefa, Z. (1999). Photophysical and Photochemical Properties of Gold(l) Complexes. In: Roundhill, D.M., Fackler, J.P. (eds) Optoelectronic Properties of Inorganic Compounds. Modern Inorganic Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-6101-6_6

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