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Hydrogen Mobility at High Concentrations

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Metal Hydrides

Part of the book series: NATO Advanced Study Institutes Series ((NSSB,volume 76))

Abstract

The roles of crystal structure, hydrogen site occupancy, phase transition, and isotope substitution on the hydrogen diffusion behavior will be considered. After brief discussions of general diffusion concepts and the experimental methods that have been most often used to determine the hydrogen mobility in the high concentration metal hydride phases, the nuclear magnetic resonance techniques that have been extensively applied in hydride diffusion studies will be reviewed in some detail. The emphasis will be on relating measured nuclear relaxation times with diffusion parameters as well as NMR techniques to directly measure the hydrogen diffusion constants. The diversity of diffusion behavior will be illustrated with several specific metal hydride systems including: PDHx, γ-TiHx and structurally related TiCuH, and VHx. Plausible models of the microscopic diffusion mechanisms will also be presented and compared with the observed diffusion behavior in these systems.

Operated by Monsanto Research Corp. for the U.S. Department of Energy under Contract No. DE-AC04-76-DP000.53.

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References

  1. J. Völkl and G. Alefeld, in Diffusion in Solids, Recent Developments, Ed, A. S. Nowick and J. J. Burton ( Academic, New York, 1975 ), p. 231.

    Google Scholar 

  2. J. Völkl and G. Alefeld, in Hydrogen in Metals I - Basic Properties, Ed. by G. Alefeld and J. Völkl ( Springer-Verlag, Berlin, 1978 ), p. 321.

    Chapter  Google Scholar 

  3. R. M. Cotts, Ber. Bunsenges. Physik. Chem. 76, 760 (1972).

    CAS  Google Scholar 

  4. R. M. Cotts, in Hydrogen in Metals I - Basic Properties, Ed. by G. Alefeld and J. Völkl ( Springer-Verlag, Berlin, 1978 ), p. 227.

    Chapter  Google Scholar 

  5. K. Sköld, in Hydrogen in Metals I - Basic Properties, Ed. by G. Alefeld and J. Völkl ( Springer-Verlag, Berlin, 1978 ), p. 267.

    Chapter  Google Scholar 

  6. A. Abragam, Principles of Nuclear Magnetism ( Oxford, London, 1961 ).

    Google Scholar 

  7. H. Y. Carr and E. M. Purcell, Phys. Rev. 94, 630 (1954)

    Article  CAS  Google Scholar 

  8. S. Meiboom and D. Gill, Rev. Sci. Instru. 29, 688 (1958).

    Article  CAS  Google Scholar 

  9. D. Zamir and R. M. Cotts, Phys. Rev. 134, A666 (1964)

    Article  Google Scholar 

  10. D. Zamir and R. M. Cotts, Proc. XIII Colloque Ampere (North Holland, Amsterdam (1964)), p. 276.

    Google Scholar 

  11. C. Korn and D. Zamir, J. Phys. Chem. Solids 31, 489 (1970).

    Article  CAS  Google Scholar 

  12. E. O. Stejskal and J. E. Tanner, J. Chem. Phys. 42, 288 (1965).

    Article  CAS  Google Scholar 

  13. W. D. Williams, E. F. W. Seymour, and R. M. Cotts, J. Magn. Reson. 31, 271 (1978).

    Google Scholar 

  14. R. F. Karlicek, Jr. and I. J. Lowe, J. Magn. Reson. 37, 75 (1980).

    CAS  Google Scholar 

  15. G. K. Schoep, N. J. Poulis, and R. R. Arons, Physica 75, 297 (1974).

    Article  CAS  Google Scholar 

  16. P. P. Davis, E. F. W. Seymour, D. Zamir, W. D. Williams, and R. M. Cotts, J. Less-Comm. Met. 49, 159 (1976).

    Article  CAS  Google Scholar 

  17. A. Schmalz and F. Noack, Ber. Bunsenges, Phys, Chem. 78, 339 (1974).

    Google Scholar 

  18. L. D. Bustard, R. M. Cotts, and E. F. W. Seymour, Zeitz. Phys. Chem, N. F. 115, 247 (1979)

    Article  CAS  Google Scholar 

  19. L. D. Bustard, R. M. Gotts, and E. F. W. Seymour, submitted to Phys. Rev.

    Google Scholar 

  20. C. L. Bisson and W. D. Wilson, in Effects Hydrogen Behavior Proc. Int. Conf. 1975, A. W. Thompson and I. M. Berstein (Eds.) AIME (1976), p. 416.

    Google Scholar 

  21. C. F. Melius and T. H. Upton, Bull. Am. Phys. Soc. 23, 234 (1978).

    Google Scholar 

  22. R. C. Bowman, Jr., A. Attalla, and A. J. Maeland, Solid State Comm. 27, 501 (1978).

    Article  CAS  Google Scholar 

  23. A. Santoro, A. Maeland, and J. J. Rush, Acta Cryst. B34, 3059 (1978).

    Article  Google Scholar 

  24. T. Schober and H. Wenzl, in Hydrogen in Metals II - Application Orientation Properties, Ed. by G. Alefeld and J. Völk1 (Springer-Verlag, 1978 ), p. 11.

    Google Scholar 

  25. K. W. Kehr, in Hydrogen in Metals I - Basic Properties, Ed. by G. Alefeld and J. Völkl ( Springer-Verlag, Berlin, 1978 ), p. 197.

    Chapter  Google Scholar 

  26. G. Bambakidis, M. W. Pershing, and R. C. Bowman, Jr., Scrip. Met. 13, 441 (1979).

    Article  CAS  Google Scholar 

  27. R. C. Bowman, Jr. and W. E. Tadlock (to be published).

    Google Scholar 

  28. H. Asano and M. Hirabayashi in 2nd Int. Cong. Hydrogen in Metal, Paris, 1977, 106.

    Google Scholar 

  29. R. C. Bowman, Jr., A. Attalla, and W. E. Tadlock, Int. J. Hydrogen Energy 1, 421 (1977).

    Article  CAS  Google Scholar 

  30. Y. Fukai and S. Kazama, Acta Met. 25, 59 (1977).

    Article  CAS  Google Scholar 

  31. P. A. Fedders, Phys. Rev. B18, 1055 (1978).

    CAS  Google Scholar 

  32. H. T. Weaver, Phys. Lett 35A, 417 (1971)

    Google Scholar 

  33. H. T. Weaver and J. P. Van Dyke, Phys. Rev. B6, 694 (1972).

    CAS  Google Scholar 

  34. M. Bogdan, V. Simplaceanu, and D. Lupu, in Proceedings of XXth Congress AMPERE, Ed. by E. Kundla, E. Lippman, and T. Saluvere ( Springer-Verlag, Berlin, 1979 ), p. 131.

    Google Scholar 

  35. H. G. Bohn, Jül-Ber. Jül-853-FF (Report), (1972).

    Google Scholar 

  36. R. C. Bowman, Jr., A. Attalla, and B. D. Craft (to be published).

    Google Scholar 

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Author notes

  1. R. C. Bowman Jr.

    Present address: Division of Chemistry and Chemical Engineering, California Inst. of Technology, Pasadena, CA, 91125, USA

Authors and Affiliations

  1. Monsanto Research Corporation, Mound Facility, Miamisburg, Ohio, 45342, USA

    R. C. Bowman Jr.

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  1. R. C. Bowman Jr.
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Editors and Affiliations

  1. Wright State University, Dayton, Ohio, USA

    Gust Bambakidis

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© 1981 Springer Science+Business Media New York

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Bowman, R.C. (1981). Hydrogen Mobility at High Concentrations. In: Bambakidis, G. (eds) Metal Hydrides. NATO Advanced Study Institutes Series, vol 76. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5814-6_6

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  • DOI: https://doi.org/10.1007/978-1-4757-5814-6_6

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-5816-0

  • Online ISBN: 978-1-4757-5814-6

  • eBook Packages: Springer Book Archive

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