Abstract
The band structure of the layered transition-metal dichalcogenides (TMD’s) is now fairly well understood (Liang, 1986, this volume). Of particular importance is the lowest-lying part of the conduction band which is known to contain a considerable dz 2 character: its energy position seems to be associated with its electronic filling as well as with the c/a ratio of the compound in question. Experimental evidence for such dependence is hereby given for the first time, through room-temperature optical transmission spectra of lithium-intercalated 1T- and 4Hb-TaS2.
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© 1986 Springer Science+Business Media New York
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Ghorayeb, A.M., Liang, W.Y., Yoffe, A.D. (1986). Band Structure Changes upon Lithium Intercalation of 1T- and 4Hb-TaS2 . In: Dresselhaus, M.S. (eds) Intercalation in Layered Materials. NATO ASI Series, vol 148. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-5556-5_6
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DOI: https://doi.org/10.1007/978-1-4757-5556-5_6
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