Advertisement

NMR Characterization of Heavy Alkali Metal-Organic Molecule Graphite Compounds Prepared from Highly-Oriented Pyrolytic Graphite

  • M. F. Quinton
  • F. Beguin
  • A. P. Legrand
Part of the NATO ASI Series book series (NSSB, volume 148)

Abstract

Many different organic molecules can be intercalated into binary heavy alkali metal-GIC’s [1]–[6]. It is expected that the electronic properties of the initial binary GIC will be modified due to the complexation of the alkali ions by the organic molecules [7][8]. Powdered samples of some ternary GIC’s of this kind have already been studied by 1H NMR [9]–[12] and 13C NMR [13]. In order to have more precise and reliable information, we have carried out 1H and 13C NMR studies with well-characterized samples prepared from HOPG.

Keywords

Spin Lattice Relaxation Spin Lattice Relaxation Time Sample Orientation Lattice Relaxation Time Graphitic Plane 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. [1]
    F. BEGUIN, R. SETTON, A. HAMWI, P. TOUZAIN, Mater. Sc. Eng. 40: 167 (1979)CrossRefGoogle Scholar
  2. [2]
    L. BONNETAIN, P. TOUZAIN, A. HAMWI, Mater. Sc. Eng. 31: 45 (1977)CrossRefGoogle Scholar
  3. [3]
    F. BEGUIN, R. SETTON, L. FACCHINI, A.P. LEGRAND, G. MERLE, C. MAI, Synth. Met. 2: 161 (1980)CrossRefGoogle Scholar
  4. [4]
    Yu. V. ISAEV, Yu. N. NOVIKOV, M.E. VOL’PIN, Synth. Met. 5: 23 (1982)CrossRefGoogle Scholar
  5. [5]
    J. JEGOUDEZ, C. MAZIERES, R. SETTON, Synth. Met. 7: 85 (1983)CrossRefGoogle Scholar
  6. [6]
    Yu. ISAEV, Yu. N. NOVIKOV, M.E. VOL’PIN, 1. RASHKOV, I. PANAYOTOV, Synth. Met. 6: 9 (1983)Google Scholar
  7. [7]
    J. AMIELL, P. DELHAES, F. BEGUIN, R. SETTON, Mater. Sc. Eng. 31: 243 (1977)CrossRefGoogle Scholar
  8. [8]
    A.P. LEGRAND, L. FACCHINI, D. BONNIN, J. BOUAT, M.F. QUINTON, F. BEGUIN, Synth. Met. 12: 175 (1985)CrossRefGoogle Scholar
  9. [9]
    M.F. QUINTON, L. FACCHINI, F. BEGU1N, A.P. LEGRAND, Rev. Chim. Min. 19: 407 (1982)Google Scholar
  10. [10]
    A.L. BLUMENFELD, E.I. FEDIN, Yu. V. ISAEV, Yu. N. NOVIKOV, Synth. Met. 6: 15 (1983)CrossRefGoogle Scholar
  11. [11]
    A.L. BLUMENFELD, Yu. V. ISAEV, Vu. N. NOVIKOV, Synth. Met. 10: 193 (1985)CrossRefGoogle Scholar
  12. [12]
    M.F. QUINTON, F. BEGUIN, A.P. LEGRAND, Synth. Met. 14: 179 (1986)CrossRefGoogle Scholar
  13. [13]
    L. FACCHINI, Thesis, Paris (1983)Google Scholar
  14. [14]
    W.J. LAFFERTY, A.W. ROBINSON, R.V. SAINT LOUIS, J.W. RUSSEL, H.L. STRAUSS, J. Chem. Phys. 42: 2915 (1965)CrossRefGoogle Scholar
  15. [15]
    J. CONARD, H. ESTRADE, P. LAUGINIE, H. FUZELIER, G. FURDIN, R. VASSE, Physica 99 B: 521 (1980)Google Scholar
  16. [16]
    K. MIME, Y. MANIWA, H. SUEMATSU, Y. IYE, S. TANUMA, Synt. Met. 8: 69 (1983)CrossRefGoogle Scholar
  17. [17]
    Y. MANIWA, K. KUME, H. SUEMATSU, S. TANUMA, J. Phys. Soc. of Japan 54. 2: 666 (1985)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1986

Authors and Affiliations

  • M. F. Quinton
    • 1
  • F. Beguin
    • 2
  • A. P. Legrand
    • 1
  1. 1.Laboratoire de Physique Quantique, UA 421E.S.P.C.I.Paris Cedex 05France
  2. 2.C.N.R.S.-C.R.O.S.I.Orleans CedexFrance

Personalised recommendations