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Review on Structural and Chemical Properties of Transition Metal Phosphorus Trisulfides MPS3

Part of the NATO ASI Series book series (NSSB, volume 148)

Abstract

Layered phases are rather attractive compounds because they present many unusual physical and chemical properties that are not commonly encountered in three dimensional materials. Let us mention charge density waves occurrence, 2D anisotropic magnetic behaviour, strong anisotropy of conductivity for example. These specific properties are the consequence of space oriented and mainly covalent bondings taking place in the slabs that compose the structure. Transition metal dichalcogenides (T.M.D.C.) represent a significant and well known series of layered materials. In these, strongly bonded slabs composed of two anionic planes enclosing a cationic one, develop in infinite sheets. Stacking of such cation-chalcogen sandwiches leaves empty spaces between the layers otherwise weakly bonded to each other.

Keywords

Octahedral Site Electronic Band Structure Cationic Radius Magnetic Chain Intercalation Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1986

Authors and Affiliations

  • R. Brec
    • 1
  1. 1.Laboratoire de Chimie des SolidesNantes CedexFrance

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