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Calorimetric Studies of Pi-Molecular Complexes

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Analytical Calorimetry

Abstract

The work reported here is the result of an experimental calo-rimetric investigation of a series of intermolecular complexes which fall into the category labeled “charge transfer” complexes (1–5) or “donor-acceptor” complexes (4). Specifically, the systems studied consist of two compounds which are postulated to have an electron donor-acceptor relationship to one another (1). The donor molecules used were benzene, the methyl substituted benzenes, thianthrene, naphthalene, acenaphthalene, phenanthrene, and pyrene. The acceptor molecules were tetracyanoethylene (TCNE), 1,3,5-trinitrobenzene (TNB), and picric acid (1,3,5-trinitrophenol or PA). The calorimetric experiments were carried out in methylene chloride solution, all possible donor-acceptor combinations were used, and a 1:1 acceptor to donor complex constitution was assumed. These calorimetric investigations are the first studies of this type.

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Author information

Authors and Affiliations

  1. Departments of Chemistry, University of Texas at El Paso, Lubbock, USA

    William C. Herndon, Jerold Feuer & Roy E. Mitchell

  2. Departments of Chemistry, Texas Tech University, Lubbock, USA

    William C. Herndon & Roy E. Mitchell

Authors
  1. William C. Herndon
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  2. Jerold Feuer
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  3. Roy E. Mitchell
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Editor information

Editors and Affiliations

  1. Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts, USA

    Roger S. Porter (Head) (Head)

  2. Department of Chemistry and Institute of Materials Science, University of Connecticut, Storrs, Connecticut, USA

    Julian F. Johnson

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© 1974 Springer Science+Business Media New York

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Herndon, W.C., Feuer, J., Mitchell, R.E. (1974). Calorimetric Studies of Pi-Molecular Complexes. In: Porter, R.S., Johnson, J.F. (eds) Analytical Calorimetry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-4509-2_20

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  • DOI: https://doi.org/10.1007/978-1-4757-4509-2_20

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-4511-5

  • Online ISBN: 978-1-4757-4509-2

  • eBook Packages: Springer Book Archive

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