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Recent Advances in Titration Calorimetry

  • Lee D. Hansen
  • Reed M. Izatt
  • Delbert J. Eatough
  • Trescott E. Jensen
  • James J. Christensen

Abstract

Calorimeters applicable for the measurement of thermodynamic parameters by the continuous titration technique have existed for about fifteen years. During this time, problems associated with the components of the calorimeter (i.e. constant temperature bath, constant rate buret, reaction vessel, temperature sensing circuit, and data analysis procedure) have gradually been solved so that the continuous titration method now gives results comparable in accuracy to those obtained in conventional solution calorimeters. Inexpensive research quality titration calorimeters have become available commercially in the last few years.

Keywords

Reaction Vessel Constant Temperature Bath Peltier Cooler Wafer Control Titrant TUBE1 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Literature describing this instrument is available from Tronac, Inc., 1804 South Columbia Lane, Orem, Utah 84057Google Scholar
  2. 2.
    Christensen, J. J., Gardner, J. W., Eatough, D. J., Izatt, R. M., Watts, P. J., and Hart, R. M., Rev. Sci. Instrum., 44, 481 (1973)CrossRefGoogle Scholar
  3. 3.
    Eatough, D. J., Christensen, J. J., and Izatt, R. M., Thermochimica Acta, 3, 219 (1972).CrossRefGoogle Scholar
  4. 4.
    Hansen, L. D., Jensen, T. E., Mayne, S., Eatough, D. J., Izatt, R. M., and Christensen, J. J., J. Chem. Thermo., submitted for publication.Google Scholar
  5. 5.
    Parker, V. B., “Thermal Properties of Aqueous Uni-univalent Electrolytes”, NSRDS-NBS 2, U.S. Government Printing Office, Washington, D. C., 1965Google Scholar

Copyright information

© Springer Science+Business Media New York 1974

Authors and Affiliations

  • Lee D. Hansen
    • 1
  • Reed M. Izatt
    • 1
  • Delbert J. Eatough
    • 1
  • Trescott E. Jensen
    • 1
  • James J. Christensen
    • 1
  1. 1.Departments of Chemistry and Chemical Engineering and Contribution 57 from the Center for Thermochemical StudiesBrigham Young UniversityProvoUSA

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