Skip to main content

Four Decades of Progress in 14C Dating by Liquid Scintillation Counting and Spectrometry

  • Conference paper
Radiocarbon After Four Decades

Abstract

Liquid scintillation (LS) radiometry (the counting of nuclear emanations) has undergone continuous development since attempts were first made in the early 1950s to detect natural 14C by this method. The potential of detection of ionizing radiations from 3H, 14C and 32P, isotopes used extensively as tracers in biomedical and biological research, was the trigger that prompted the commercial development of LS counters, first by Lyle Packard, the founder of the Packard Instrument Company, USA and then by many others in the USA and Europe. Though efficient and technologically advanced for their times, the early counters had very high backgrounds and, hence, offered poor resolution of radioactive isotopes at environmental concentrations.

“Go forth and build a house of bricks” (the parent of the third little piggy)

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Alessio, M, Allegri, L, Bella, F and Improta, S 1976 Study of background characteristics by means of high efficiency liquid scintillation counter. Nuclear Instruments and Methods 137: 537–543.

    Article  Google Scholar 

  • Anderson, EC, Arnold, JR and Libby, WF 1951 Measurement of low level radiocarbon. Review of Scientific Instruments 22 (4): 225–230.

    Article  Google Scholar 

  • Arnold, JR 1954 Scintillation counting of natural radiocarbon: 1. The counting method. Science 119: 155–157.

    Article  Google Scholar 

  • Arnold, JR 1958 Archaeology and chemistry. In Bell, CG, Jr and Hayes, F, eds, Liquid Scintillation Counting. New York, Pergamon Press: 129–134.

    Google Scholar 

  • Audric, BN and Long, JVP 1954 Use of dissolved acetylene in liquid scintillation counters for the measurement of carbon-14 for low specific activity. Nature 173: 992993.

    Google Scholar 

  • Barker, H 1953 Radiocarbon dating: Large scale production of acetylene from organic material. Nature 172: 631–632.

    Article  Google Scholar 

  • Berthold, F 1980 A new approach to automatic photomultiplier stabilisation for photon and scintillation counters. In Peng, C-T, Horrocks, DL and Alpen, EL, eds, Liquid Scintillation Counting: Recent Applications and Developments. New York, Academic Press: 273–280.

    Google Scholar 

  • Birks, JB 1974 Towards an understanding of scintillation process in organic molecular systems. In Stanley, PE and Scoggins, B, eds, Liquid Scintillation Counting: Recent Developments. New York, Academic Press: 1–38.

    Chapter  Google Scholar 

  • Bowman, S 1986 The potential of the London underground for liquid scintillation counting. In Stuiver, M and Kra, RS, eds, Proceedings of the 12th International 14C conferences. Radiocarbon 28(2A): 592–596.

    Google Scholar 

  • Broda, R and Radoszewski, T 1982 Scintillation detector with anticoincidence shield for determination of radioactive concentration of standard solutions. In Povinec, P and Usacev, S, eds, Low Radioactivity Measurements and Applications. Bratislava, Slovenske Pedagogicke Nakladatelstvo: 329–333.

    Google Scholar 

  • Broser, I, von and Kallmann, H 1947 Über die Anregung von Leuchtstoffen durch schnelle Korpuskularteilchen. Zeitschrift für Naturforschung 2 (8): 439–440.

    Google Scholar 

  • Burleigh, R, Hewson, AD and Matthews, KJ 1977 Synthesis of benzene for low-level 14C measurement: A review. In Crook, MA and Johnson, P, eds, Liquid Scintillation Counting 5. London, Heyden: 205–209.

    Google Scholar 

  • Calf, GE and Airey, PE 1987 Liquid scintillation counting of carbon-14 in a heavily shielded site. In Ambrose, WR and Mummery, JMJ, eds, Archaeometry: Further Australian Studies. Canberra, ANU Press: 351–356.

    Google Scholar 

  • Calf, GE and Polach, HA 1974 Teflon vials for liquid scintillation counting of carbon-14 samples. In Stanley, PE and Scoggins, B, eds, Liquid Scintillation Counting: Recent Developments. New York, Academic Press: 224–234.

    Google Scholar 

  • Cook, GT and Polach, HA 1991 Low-level liquid scintillation counting workshop. In Ross, H, Noakes, J and Spaulding, J, eds, New Trends in Liquid Scintillation Counting and Organic Scintillators. Chelsea, Michigan, Lewis Publishers: 691–694.

    Google Scholar 

  • Ediss, C 1980 A multichannel analyser interface for a Beckman 9000 liquid scintillation counter. In Peng, C-T, Horrocks, DL and Alpen, EL, eds, Liquid Scintillation Counting: Recent Applications and Developments. New York, Academic Press: 281–289.

    Google Scholar 

  • Eichinger, L, Rauret, W, Salvamoser, J and Wolf, M 1980 Large-volume liquid scintillation counting of carbon-14. In Stuiver, M and Kra, RS, eds, Proceedings of the 10th International 14C Conference. Radiocarbon 22(2): 417–427.

    Google Scholar 

  • Geyh, MA 1969 Problems in radiocarbon dating of small samples by means of acetylene, ethane or benzene. International Journal of Applied Radiation and Isotopes 20: 463–466.

    Article  Google Scholar 

  • Geyh, MA 1990 Radiocarbon dating problems using acetylene as counting gas. In Long, A, Kra, RS and Scott, EM, eds, Proceedings of the International Workshop on Intercomparison of 14C Laboratories. Radiocarbon 32(3): 321–324.

    Google Scholar 

  • Gupta, SK and Polach, HA 1985 Radiocarbon Dating Practices at ANU. Canberra, Radiocarbon Laboratory, ANU: 176 p.

    Google Scholar 

  • Haas, H 1979 Specific problems with liquid scintillation counting of small benzene volumes and background count rate estimations. In Berger, R and Suess, HE, eds, Radiocarbon Dating. Proceedings of the 9th International 14C Conference. Berkeley, University of California Press: 246–255.

    Google Scholar 

  • Hays, FN, Williams, DL and Rogers, B 1953 Liquid scintillation counting of natural C-14. Physical Review 92: 512–513.

    Article  Google Scholar 

  • Hiebert, RD and Watts, RI 1953 Fast coincidence circuit for H3 and C14 measurements. Nucleonics 11 (12): 38–41.

    Google Scholar 

  • Hogg, A, Polach, II, Robertson, S and Noakes, J 1991 Application of high purity synthetic quartz vials to liquid scintillation low-level 14C counting of benzene. In Ross, H, Noakes, J and Spaulding, J, eds, New Trends in Liquid Scintillation Counting and Organic Scintillators. Chelsea, Michigan, Lewis Publishers: 123–131.

    Google Scholar 

  • Hood, D, Hatfield, R, Patrick, C, Stipp, J, Tamers, M, Leidl, R, Lyons, B, Polach, H, Robertson, S and Zhou, W 1989 Radon removal during benzene preparation for radiocarbon dating by liquid scintillation spectrometry. In Long, A and Kra, RS, eds, Proceedings of the 13th International i4C Conference. Radiocarbon: 31(3): 254259.

    Google Scholar 

  • Horrocks, DL 1970 Pulse shape discrimination with organic scintillation solutions. Applied Spectroscopy 24: 397–404

    Article  Google Scholar 

  • Horrocks, DL 1974 Applications of Liquid Scintillation Counting. New York, Academic Press: 346 p.

    Google Scholar 

  • Horrocks, DL 1985 Studies of background sources in liquid scintillation counting. International Journal of Applied Radiation and Isotopes 36 (8): 609–617.

    Article  Google Scholar 

  • Iwakura, T, Kasida, Y, Inoue, Y and Tokunaga, N 1979 A low-background liquid scintillation counter for measurement of low-level tritium. In Behaviour of tritium in the environment. IAEA Proceedings Series. Vienna, IAEA: 163–171.

    Google Scholar 

  • Jerde, RL, Peterson, LE and Stein, W 1967 Effects of high energy radiation on noise pulses from photomultiplier tubes. Review of Scientific Instruments 38(10): 13871395.

    Google Scholar 

  • Jiang, H, Luu, S, Fu, S, Zhang, W, Zhang, T, Ye, Y, Li, M, Fu, P, Wang, S, Peng, Ch and Jiang, P 1983 Model DYS low-level liquid scintillation counter. In McQuarrie, SA, Ediss, C and Wiebe, LI, eds, Advances in Scintillation Counting. Alberta, University of Alberta Press: 478–493.

    Google Scholar 

  • Kaihola, L 1991 Liquid scintillation counting performance using glass vials with the Wallac 1220 QuantulusTM. In Ross, H, Noakes, J and Spaulding, J, eds, New Trends in Liquid Scintillation Counting and Organic Scintillators. Chelsea, Michigan, Lewis Publishers: 495–500.

    Google Scholar 

  • Kaihola, L and Oikari, T 1991 Some factors affecting alpha particle detection in liquid scintillation spectrometry. In Ross, H, Noakes, J and Spaulding, J, eds, New Trends in Liquid Scintillation Counting and Organic Scintillators. Chelsea, Michigan, Lewis Publishers: 211–218.

    Google Scholar 

  • Kananen, K, Ala-Uotila, M, Oikari, T and Soini, E 1984 A study of the effect of humidity and use of an ioniser on static electricity using an LKB-Wallac 1211 RackBeta liquid scintillation counter. Wallac Report, Turku, Finland: 1–9.

    Google Scholar 

  • Kojola, H, Polach, H, Nurmi, J, Oikari, T and Soini, E 1984 High resolution low-level liquid scintillation beta-spectrometer. International Journal of Applied Radiation and Isotopes 35 (10): 949–952.

    Article  Google Scholar 

  • Kuc, T and Rozanski, K 1978 A small volume teflon-copper vial for 14C low level liquid scintillation counting. International Journal of Applied Radiation and Isotopes 30: 452–454.

    Article  Google Scholar 

  • Laney, BH 1971 Electronic rejection of optical crosstalk in a twin phototube scintillation counter. In Horrocks, DL and Peng, C-T, eds, Organic Scintillators and Scintillation Counting. New York, Academic Press: 991–1003.

    Chapter  Google Scholar 

  • McKlveen, JW and McDowell, WJ 1984 Liquid scintillation alpha spectrometry techniques. Nuclear Instruments and Methods 223: 372–376.

    Article  Google Scholar 

  • Mook, WG 1983 International comparison of proportional gas counters for 14C activity measurements. In Stuiver, M and Kra, RS, eds, Proceedings of the 11th International 14C Conference. Radiocarbon 25(2): 475–484.

    Google Scholar 

  • Noakes, JE 1977 Considerations for achieving low level radioactivity measurements with liquid scintillation counters. In Crook, MA and Johnson, P, eds, Liquid Scintillation Counting 4. London, Heyden: 189–206.

    Google Scholar 

  • Noakes, JE, Isbell, AF, Stipp, JJ and Hood, DW 1963 Benzene synthesis by low temperature catalysis for radiocarbon dating. Geochimica et Cosmochimica Acta 27: 797–804.

    Article  Google Scholar 

  • Noakes, JE, Kim, SM and Stipp, JJ 1965 Chemical and counting advances in liquid scintillation counting. In Chatters, RM and Olson, EA, eds, Proceedings of the 6th International Conference on Radiocarbon and Tritium Dating. USAAEC, CONF — 650652: 68–92.

    Google Scholar 

  • Noakes, JE, Neary, MP and Spaulding, JD 1973 Tritium measurements with a new liquid scintillation counter. Nuclear Instruments and Methods 109: 177–187.

    Article  Google Scholar 

  • Noakes, JE 1974 A new liquid scintillation counter for measurements of trace amounts of 3H and 14C. In Stanley, PE and Scoggins, B, eds, Liquid Scintillation Counting: Recent Developments. New York, Academic Press: 53–66.

    Chapter  Google Scholar 

  • Noakes, JE and Valenta, RJ 1989 Low background liquid scintillation counting using an active sample holder and pulse discrimination electronics. In Long, A and Kra

    Google Scholar 

  • RS, eds, Proceedings of the 13th International 14C Conference. Radiocarbon 31(3): 332–341.

    Google Scholar 

  • Nydal, R 1983 The radon problem in 14C counting. In Stuiver, M and Kra, RS, eds, Proceedings of the 11th International 14C Conference. Radiocarbon 25(2): 501–510.

    Google Scholar 

  • Oikari, T, Kojola, H, Nurmi, J and Kaihola, L 1987 Simultaneous counting of low alpha-and beta-particle with liquid scintillation spectrometry and pulse shape analysis. International Journal of Applied Radiation and Isotopes 38 (10): 875–878.

    Article  Google Scholar 

  • Pearson, GW 1979 Precise measurement by liquid scintillation counting. Radiocarbon 21 (1): 1–21.

    Google Scholar 

  • Pietig, F, von and Scharpenseel, HW 1964 Alterbestimmung mit Flüssigheits-Scintillations-Spectrometer, über die Wirksamkeit von Abschirmungsabnahmen. Atompraxis 7: 1–3.

    Google Scholar 

  • Polach, HA 1969 Optimisation of liquid scintillation radiocarbon age determinations and reporting of ages. Atomic Energy in Australia 12 (3): 21–28.

    Google Scholar 

  • Polach, HA 1974 Application of liquid scintillation spectrometers to radiocarbon dating. In Stanley, PE and Scoggins, B, eds, Liquid Scintillation Counting: Recent Developments. New York, Academic Press: 153171.

    Google Scholar 

  • Polach, HA 1987 Evaluation and status of liquid scintillation counting for radiocarbon dating. Radiocarbon 29 (1): 1–11.

    Google Scholar 

  • Polach, HA, Gower, J and Fraser, I 1972 Synthesis of high purity benzene for radiocarbon dating by the liquid scintillation method. In Rafter, TA and Taylor, T, eds, Proceedings of the 8th International 14 C Conference. Wellington, Royal Society of New Zealand: 145–157.

    Google Scholar 

  • Polach, HA Polach, H, Gower, J, Kojola, H and Heinonen, A 1983a An ideal vial and cocktail for low-level scintillation counting. In McQuarrie, SA, Ediss, C and Wiebe, LI, eds, Advances in Scintillation Counting. Alberta, University of Alberta Press: 508–525.

    Google Scholar 

  • Polach, H and Kaihola, L 1988 Determina Four Decades of LS Counting and Spectrometry 213 tion of radon by liquid scintillation alpha/ beta particle spectrometry. Radiocarbon 30 (1): 19–24.

    Google Scholar 

  • Polach, H, Kaihola, L, Robertson, S and Haas, H 1988 Small sample 14C dating by liquid scintillation spectrometry. Radiocarbon 30 (2): 153–155.

    Google Scholar 

  • Polach, H, Kojola, H, Nurmi, J and Soini, E 1984 Multiparameter liquid scintillation spectrometry. In Wölfli, W, Polach, H and Anderson, HII, eds, Accelerator mass spectrometry, AMS-84. Nuclear Instruments and Methods 233[B5](2): 439–442.

    Google Scholar 

  • Polach, H, Nurmi, J, Kojola, H and Soini, E 1983b Electronic optimization of scintillation counters for detection of low-level 3H and 14C. In McQuarrie, SA, Ediss, C and Wiebe, LI, eds, Advances in Scintillation Counting. Alberta, University of Alberta Press: 420–441.

    Google Scholar 

  • Polach, H, Robertson, S, Butterfield, D, Gower, J and Soini, E 1983c The `windowless’ approach to scintillation counting: low-level 14C as an example. In McQuarrie, SA, Ediss, C and Wiebe, LI, eds, Advances in Scintillation Counting. Alberta, University of Alberta Press: 494507.

    Google Scholar 

  • Polach, HA and Stipp, JJ 1967 Improved synthesis techniques for methane and benzene radiocarbon dating. International Journal of Applied Radiation and Isotopes 18: 359–364.

    Article  Google Scholar 

  • Punning, JM and Rajamäe, R 1975 Some possibilities for decreasing the background of liquid scintillation beta-ray counter. In Povinec, P and Usacev, S, eds, Low Radioactivity Measurements and Applications. Bratislava, Slovenske Pedagogicke Nakladatelstvo: 169–171.

    Google Scholar 

  • Radnell, CJ and Muller, AB 1980 Memory effects in the production of benzene for radiocarbon dating. hi Stuiver, M and Kra, RS, eds, Proceedings of the 10th International 14C conference. Radiocarbon 22 (2): 479–486.

    Google Scholar 

  • Rapkin, E 1970 Development of the modern liquid scintillation counter. Iu Bransome, ED, Jr, ed, The Current Status of Liquid Scintillation Counting. New York, Grune and Stratton: 45–68.

    Google Scholar 

  • Reynolds, GT, Harrison, FB and Salvini, G 1950 Liquid scintillation counters. Physics Review 78: 488–493.

    Article  Google Scholar 

  • Rubin, M, Mysen, B and Polach, H 1984 Graphite sample preparation for AMS in a high pressure and high temperature press. In Wölfli, W, Polach, H and Anderson, HH, eds, Accelerator mass spectrometry, AMS-84. Nuclear Instruments and Methods 233[B5](2): 272–273.

    Google Scholar 

  • Schotterer, U and Oeschger, H 1980 Low-level liquid scintillation counting in an underground laboratory. In Stuiver, M and Kra, RS, eds, Proceedings of the 10th International 14C Conference. Radiocarbon 22(2): 505–511.

    Google Scholar 

  • Soini, E 1975a Stabilization of photo-multipliers in liquid scintillation counters. Review of Scientific Instruments 46: 980984.

    Google Scholar 

  • Soini, E 1975b Rejection of optical cross—talk in photomultiplier tubes in liquid scintillation counters. Wallac Report, Turku, Finland: 1–9.

    Google Scholar 

  • Soini, E 1977 Chemiluminescence monitoring and rejection in liquid scintillation counting. Wallac Report, Turku, Finland: 1–8.

    Google Scholar 

  • Stipp, JJ, Knauer, GA and Godell, IIG 1966 Florida State university radiocarbon dates I. Radiocarbon 8: 46–53.

    Google Scholar 

  • Tamers, MA 1965 Routine carbon-14 dating using liquid scintillation techniques. In Chatters, RM and Olson, EA, eds, Proceedings of the 6th International Conference on Radiocarbon and Tritium Dating. USAAEC, CONF-650652: 53–67.

    Google Scholar 

  • Tamers, MA 1975 Chemical yield optimisation of benzene synthesis for radiocarbon dating. International Journal of Applied Radiation and Isotopes 26: 676–682.

    Article  Google Scholar 

  • Valenta, R 1987 Reduced background scintillation counting. US Patent no. 4, 651, 006.

    Google Scholar 

  • Wang, CH 1970 Quench compensation by means of gain restoration. hi Bransome, ED, Jr, ed, The Current Status of Liquid Scintillation Counting. New York, Grune and Stratton: 305–312.

    Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1992 Springer Science+Business Media New York

About this paper

Cite this paper

Polach, H.A. (1992). Four Decades of Progress in 14C Dating by Liquid Scintillation Counting and Spectrometry. In: Taylor, R.E., Long, A., Kra, R.S. (eds) Radiocarbon After Four Decades. Springer, New York, NY. https://doi.org/10.1007/978-1-4757-4249-7_14

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-4249-7_14

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4757-4251-0

  • Online ISBN: 978-1-4757-4249-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics