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Reactions of Electron-Deficient Intermediates

  • Francis A. Carey
  • Richard J. Sundberg
Part of the Advanced Organic Chemistry book series

Abstract

The reactions to be described in this chapter have in common the formal involvement of even-electron intermediates having unfilled orbitals of low energy. The most familiar of these intermediates are carbonium ions. Sections 9.4 and 9.6 contain examples of reactions of carbonium ions that are of synthetic value; the discussion of these.reactions supplements the more mechanistically-oriented discussion presented in Part A, Chapter 5. Also important are the neutral divalent carbon and monovalent nitrogen species, carbenes and nitrenes, respectively.

Keywords

Insertion Reaction Diazo Compound Beckmann Rearrangement Hydrazoic Acid Carbene Intermediate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1983

Authors and Affiliations

  • Francis A. Carey
    • 1
  • Richard J. Sundberg
    • 1
  1. 1.University of VirginiaCharlottesvilleUSA

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