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Mössbauer Effect Methodology pp 15–36Cite as

Applications of Sn119m Mössbauer Spectroscopy to Chemical Problems

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Abstract

The first observation of the Mössbauer effect in Sn119 [1] was qickly followed by the application of Sn.119m Mössbauer spectroscopy to a chemical problem [2]. There are now almost two hundred research papers and notes which comprise the literature of Sn119m Mössbauer spectroscopy. The great majority of these describe applications to chemical problems. Spectroscopic methods are inherently capable of yielding three general types of information(1)identity of a substance(2) composition of a physical mixture, and (3) information concerning the structure and bonding of atoms in molecule. The first of these represents an application of the generally accepted principle that “identical species behave identically” and the second on the premise that physical mixing does not alter chemical nature two these two are analytical uses. It is the third type of information which the chemist is most anxious to have. In most cases it is impossible to derive exact theoretical predictions concerning the change of measurable parameters from first principles, and the practicingchemist must, therefore, rely on a large body of analogy upon which to build his hypoteses. In the case of a technique only recently introduced, to test a wide variety of substances in order to find the empirical correlations which relate the known chemical behavior to changes in the observable parameters. This process has already been seen occur in infrared and nuclear magnetic resonance spectroscopy. The present state of the science of Sn119m Mössbauer spectroscopy is reviewed.

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Authors and Affiliations

  1. Baker Laboratory, Cornell University, Ithaca, New York, USA

    J. J. Zuckerman

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  1. J. J. Zuckerman
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  1. Special Sources Department, New England Nuclear Corporation, Boston, Massachusetts, USA

    Irwin J. Gruverman (Head) (Head)

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Zuckerman, J.J. (1967). Applications of Sn119m Mössbauer Spectroscopy to Chemical Problems. In: Gruverman, I.J. (eds) Mössbauer Effect Methodology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-1547-7_2

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  • DOI: https://doi.org/10.1007/978-1-4757-1547-7_2

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-1549-1

  • Online ISBN: 978-1-4757-1547-7

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