Abstract
Spectroscopic measurements of aqueous electrolyte solutions have been made for nearly 50 years, and electrochemical measurements for very much longer. Although some relationships between infrared measurements of vibrational bands and electrochemical data have at times been noted, no relationships have, to our knowledge, so far been reported for chargetransfer-to-solvent (CTTS) spectra. Further, all the previous relationships have not sought to interrelate the theoretical understanding of the nature of the transition with that of electrochemical measurements. In this chapter we report and discuss such a relationship, and show that an all-embracing account is now available, which extends from infinitely dilute, through saturated salt solutions, to, in principle, the anhydrous salts.
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Griffiths, T.R., Wijayanayake, R.H. (1981). A Direct Correspondence between Spectroscopic Measurements and Electrochemical Data and Theories. In: Inman, D., Lovering, D.G. (eds) Ionic Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0920-9_6
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DOI: https://doi.org/10.1007/978-1-4757-0920-9_6
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