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Ionic Liquids pp 339-362 | Cite as

Oxide Species in Molten Salts

  • A. A. El Hosary
  • D. H. Kerridge
  • A. M. Shams El Din

Abstract

Identification of oxide species and their interactions is probably the most complex problem in molten salt chemistry at the present time. A study of the literature reveals controversy, confusion, and numerous simple discrepancies, so that rapid and conclusive answers based on a generalized theory are not to be expected. However, careful attention to the precise conditions of the experimental measurements, i.e., temperature, concentrations, the presence or absence of certain ions which did not initially feature in the equations of the reaction sequence (e.g., the nature of M+) the container materials, etc. has shown that in the most complicated system for which data is plentiful (molten alkali metal nitrates) an attempt can now be made to construct a theory reconciling and embracing most, if not all, of the available evidence.

Keywords

Equilibrium Constant Molten Salt Oxide Species Oxygen Electrode Lithium Cation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1981

Authors and Affiliations

  • A. A. El Hosary
    • 1
  • D. H. Kerridge
    • 2
  • A. M. Shams El Din
    • 1
  1. 1.National Research CentreDokki, CairoEgypt
  2. 2.Chemistry DepartmentSouthampton UniversitySouthamptonEngland

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