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Characterization of Bioactive Organotin Polymers: Fractionation and Determination of MW by SEC-GFAA

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Controlled Release of Pesticides and Pharmaceuticals

Abstract

Organometallic polymers (OMP’s), incorporating biocidal triorganotin moieties, chemically bonded to carboxyl groups pendant along polymer chains, are undergoing intensive development as longterm controlled-release, marine antifouling agents.1 Materials in this general class have been prepared by copolymerizing methyl-methacrylate and organotin-substituted methacrylates in a free radical initiated process.2 The polymers are incorporated within a polymeric binding substrate and coated over surfaces that are to be exposed to a marine-service environment. Tin-containing fragments tailored3 to prevent build-up of fouling micro-organisms4 are slowly leached out of the coating.5 The protective mechanism is not necessarily a simple chemical or physical process, and the macromolecular materials break down over a period of years.1,2

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Author information

Authors and Affiliations

  1. Chemical and Biodegradation Processes Group, Center for Materials Science, National Bureau of Standards, Washington, D.C., 20234, USA

    E. J. Parks & F. E. Brinckman

Authors
  1. E. J. Parks
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  2. F. E. Brinckman
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Editor information

Editors and Affiliations

  1. Southern Research Institute, Birmingham, Alabama, USA

    Danny H. Lewis

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© 1981 Springer Science+Business Media New York

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Parks, E.J., Brinckman, F.E. (1981). Characterization of Bioactive Organotin Polymers: Fractionation and Determination of MW by SEC-GFAA. In: Lewis, D.H. (eds) Controlled Release of Pesticides and Pharmaceuticals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0737-3_16

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  • DOI: https://doi.org/10.1007/978-1-4757-0737-3_16

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-0739-7

  • Online ISBN: 978-1-4757-0737-3

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