Advertisement

Physical Properties and Structure of Individual Radicals

  • E. G. Rozantsev
  • H. Ulrich

Abstract

The vapor pressure of the individual free radicals is their most important thermodynamic characteristic, having not only theoretical interest, but also great practical importance. Until very recently, this aspect has been investigated for only a few radicals [1]. Table 9 gives almost all the nitroxides and nitroxyls and the corresponding hydrides which have been studied.

Keywords

Dipole Moment Nitrogen Atom Spin Density Dissociation Energy Unpaired Electron 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    L. A. Kalashnikova, É. G. Rozantsev, and A. M. Chaikin, Izv. Akad. Nauk SSSR, Ser. Khim. 1965, 800.Google Scholar
  2. 2.
    S. Dushman, Scientific Foundations of Vacuum Technology, John Wiley and Sons, New York (1949).Google Scholar
  3. 3.
    M. Rossman and J. Yarwood, J. Chem. Phys. 21, 1406 (1953).CrossRefGoogle Scholar
  4. 4.
    Yu. A. Lebedev, É. G. Rozantsev, L. A. Kalashnikova, V. P. Lebedev, M. B. Neiman, and A. Ya. Apin, Dokl. Akad. Nauk SSSR 168, 104 (1966).Google Scholar
  5. 5.
    Yu. A. Lebedev, É. G. Rozantsev, M. B. Neiman, and Z. Ya. Apin, Zh. Fiz. Khim. 40, 2340 (1966).Google Scholar
  6. 6.
    C. Mortimer, Reaction Heats and Bond Strengths, Pergamon, Oxford (1962).Google Scholar
  7. 7.
    T. Cottrell, The Strengths of Chemical Bonds, Butterworths, London, 2nd ed. (1958).Google Scholar
  8. 8.
    M. Balasubramanian, Chem. Rev. 62, 691 (1962).Google Scholar
  9. 9.
    V. D. Sholle, É. G. Rozantsev, A. A. Prokofev, and S. P. Solodovnikov, Izv. Akad. Nauk SSSR, Ser. Khim. 1%7, 2628.Google Scholar
  10. 10.
    Ts. Téidzi, Reactions for Preparing Synthetic Polymers, GNTI, Moscow (1963).Google Scholar
  11. 11.
    É. G. Rozantsev and E. N. Gur’yanova, Izv. Akad. Nauk SSSR, Ser. Khim. 1966, 979.Google Scholar
  12. 12.
    É. G. Rozantsev, L. A. Krinitskaya, and M. B. Neiman, Izv. Akad. Nauk SSSR, Ser. Khim. 1966, 675.Google Scholar
  13. 13.
    L. Cambi, Gazz. Chico. Ital. 63, 579 (1933).Google Scholar
  14. 14.
    L. Cambi and L. Szegö, Ber. 64, 2591 (1931).Google Scholar
  15. 15.
    G. Berthier, H. Lemaire, A. Rassat, and N. Viellard, Theor. Chim. Acta 3, 213 (1965).CrossRefGoogle Scholar
  16. 16.
    Yu. Yu. Samitov and O. L. Lebedev, Fiz. Problemy Spektroskopii 2, 103 (1963).Google Scholar
  17. 17.
    Yu. Yu. Samitov and D. Ibraimov, Teor. i Éksperim. Khim. 1965(3), 387.Google Scholar
  18. 18.
    A. Mossel, C. Romers, and E. Havinga, Tetrahedron Letters 1963, 1247.Google Scholar
  19. 19.
    P. Groth and O. Hassel, Proc. Chem. Soc. 1963, 218.Google Scholar
  20. 20.
    M. Bhatt, G. Srinivasan, and P. Neelakantan, Tetrahedron 21, 291 (1965).CrossRefGoogle Scholar
  21. 21.
    É. G. Rozantsev Izv. Akad. Nauk SSSR Ser. Khim.1964, 2187.Google Scholar

Copyright information

© Springer Science+Business Media New York 1970

Authors and Affiliations

  • E. G. Rozantsev
    • 1
  • H. Ulrich
    • 2
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRMoscowUSSR
  2. 2.Donald S. Gilmore Research LaboratoriesThe Upjohn CompanyNorth HavenUSA

Personalised recommendations