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Chemiluminescence Reactions Involving Metal Vapors

  • C. J. Duthlert
  • H. P. Broida

Abstract

A brief survey of recent experimental work on metal vapors at our laboratories is given. Results of chemiluminescence of group Ia and IIb metal atoms excited by a Lewis-Rayleigh nitrogen afterglow are presented. For group Ia atoms, we have found evidence that the exciting species in the afterglow is N2(A) rather than N2(X)v as previously proposed. A demonstration of spin conservation during collisions of the second kind is seen in the excitation of group IIb atoms and relative quenching of electronically excited nitrogen states is noted.

Keywords

Translational Energy Alkali Atom Excited State Energy Triplet Level Spin Conservation 
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References

  1. 1.
    R. J. Oldman and H. P. Broida, J. Chem. Phys. 51, 2764 (1969).CrossRefGoogle Scholar
  2. 2.
    For a review of this work see S. E. Johnson, Ph.D. Thesis, University of California, Santa Barbara, 1971.Google Scholar
  3. 3.
    R. W. Field, R. S. Bradford, D. O. Harris, and H. P. Broida, J. Chem. Phys. 56, 4712 (1972); ibid. 57, 2209 (1972).Google Scholar
  4. 4.
    C. J. Duthler, S. E. Johnson, and H. P. Broida, Phys. Rev. Letters 26, 1236 (1971).CrossRefGoogle Scholar
  5. 5.
    G. Capelle, R. S. Bradford, and H. P. Broida, J. Chem. Phys. (to be submitted).Google Scholar
  6. 6.
    C. J. Duthler and H. P. Broida, J. Chem. Phys. (submitted).Google Scholar
  7. 7.
    A. N. Wright and C. A. Winkler, Active Nitrogen ( Academic, New York, 1968 ).Google Scholar
  8. 8.
    A. M. Bass and H. P. Broida, J. Res. Natl. Bur. Std. 67A, 379 (1963).CrossRefGoogle Scholar
  9. 9.
    A. G. Mitchell and M. W. Zemansky, Resonance Radiation and Excited Atoms ( Cambridge University Press, London, 1961 ).Google Scholar
  10. 10.
    A. G. Gaydon and I. R. Hurle, Symp. Combust. 8th, Pasadena, Calif., 1960 (1962), p. 309.Google Scholar
  11. 11.
    I. R. Hurle, J. Chem. Phys. 41, 3911 (1964).CrossRefGoogle Scholar
  12. 12.
    E. L. Milne, J. Chem. Phys. 52, 5360 (1970).CrossRefGoogle Scholar
  13. 13.
    W. L. Starr, J. Chem. Phys. 43, 73 (1965).CrossRefGoogle Scholar
  14. 14.
    W. L. Starr and T. M. Shaw, J. Chem. Phys. 44, 4181 (1966).CrossRefGoogle Scholar
  15. 15.
    H. F. Krause, J. Fricke, and W. L. Fite, J. Chem. Phys. 56, 4593 (1972).CrossRefGoogle Scholar
  16. 16.
    R. G. Gann, F. Kaufman, and M. A. Biondi (to be published).Google Scholar
  17. 17.
    W. R. Brennen and G. B. Kistiakowsky, J. Chem. Phys. 44, 2695 (1966).CrossRefGoogle Scholar
  18. 18.
    R. A. Young and G. A. St. John, J. Chem. Phys. 48, 2572 (1968).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1973

Authors and Affiliations

  • C. J. Duthlert
    • 1
  • H. P. Broida
    • 1
  1. 1.Department of PhysicsUniversity of California Santa BarbaraUSA

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