Abstract
There are two main avenues of approach in applying the corresponding states principle to multicomponent systems. One is through the use of reduced virial coefficients introduced by Guggenheim [1], Guggenheim and McGlashan [2], and further developed by Prausnitz and Gunn [3]. The other is through the use of composition dependent pseudo- critical properties proposed originally by Kay [4] with later improvements by Joffe [5], Stewart et al. [6] and Leland and Mueller [7]. The method of reduced virials is more rigorous theoretically but tine thermo-dynamic properties evaluated from it are limited to conditions under which the gas behavior can be described by equations involving only the second virial. The method of pseudo-criticals, while more empirical in nature, does not completely neglect the effect of higher virials.
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References
E. A. Guggenheim, Mixtures, 154–165, Clarendon Press, Oxford (1952).
E. A. Guggenheim and M. I. McGlashan, Proc. Roy. Soc (London), Vol. A206, 448 (1951).
J.M. Prausnitz and R.D. Gum, A. I. Ch. E. Jour., Vol. 4, 430 (1958);
ibid., Vol. 4, 494 (1958).
W. B. Kay, Ind. Eng. Chem., Vol. 33, 590 (1941).
J. Joffe, Ind. Eng, Chem., Vol. 39, 837 (1947).
W. E. Stewart, S. P. Burkhardt, and D. Voo, Paper presented at A. I. Ch. E. National Meeting, Kansas City, Mo., May 18 (1959).
T.W. Leiand Jr. and W.H. Mueller, Ind. Eng. Chem., Vol. 51, 591 (1959).
J.E. Kilpatrick, J. Chem. Phys., Vol. 21, 274 (1953).
F. London, Z. Physik, Vol. 63, 245 (1930);
ibid., Vol, 60, 491 (1930).
P. London Trans. Faraday Soc., Vol, 33, 8 (1937).
G. E. Uhlenbeck and E. Beth, Physics, Vol, 3, 729 (1936).
J.G. Kirkwood, Phys, Rev., Vol. 44, 31 (1933).
K.S. Pitzer, J. Chem. Phys., Vol. 7, 583 (1939).
R.J. Limbeck, Doctoral Dissertation, Amsterdam (1950).
J. de Boer, Physics, Vol. 14, 139 (1948);
ibid., Vol, 14, 149 (1948);
ibid., Vol. 14, 520 (1948).
J.O. Hirschfelder, C.F. Curtiss, and R.B. Bird, Molecular Theory of Gases, and Liquids, John Wiley and Sons, New York (1954).
W.H. Mueller, Ph.D. Thesis in Ch.E., Rice University, Dec. (1959).
W. H. Mueller, R. Kobayashi, and T.W. Leiand Jr., Paper presented at International Congress of Chemical Engineerieg, Joint Meeting of Institute Mexicano de Ingenieras Quimicos and A. I. Ch, E., June 19–22 (1960), Mexico City, D. F.(Publication forthcoming).
A. Michels, W. de Graaff, T. Wassenaar, J.M.H. Levelt, and P. Lowerse, Physics, Vol. 25, 25 (1959).
H. W. Wooliey, R. B. Scott, and P.O. Brickwedde, Nat. Bur. Std. Jour. Res., Vol. 41, 379 (1948).
K. Shifer, Z. Phys, Chem., Vol. 136, 85 (1937).
W.H. Mueller, T.W. Leiand Jr., and R. Kobayaski, Paper presented at International Congress of Chemical Engineering, Joint Meeting of Institute Mexicano de Ingenieros Quimicos and A. I. Ch. E., June 19–22 (1960), Mexico City, D. F. (Publication forthcoming in A. I. Ch, E. Journal).
H.W. Schamp Jr., E.A. Mason, A.C.B. Richardson, and A. Altman, Phys. of Fluids, Vol. 1, 329 (1958).
A. L. Lyderson, R. A. Greenkorn, and O. A. Hougen, “Generalized Thermodynamic Properties of Pure Fluids,” Univ. of Wis., Engr. Expt. Station, Rept. No, 4, Madison, Wisc. (1955).
W. H. Keesom, Helium, Chap. 2, Elsevier Press, New York (1942).
J. Otto, Handbuch der Experimentalphysik, Bd. 8, Part 2, 79, Leipzig (1929).
W.G. Schneider and J. A.H. Puffie, J. Chem, Phys.. Vol. 17, 751 (1949).
L. Holtoni and J. Otto, Z. Physik, Vol. 23, 77 (1924).
L. Boltorn and J. Otto, Z. Physik, Vol. 38, 359 (1926).
A. Michels, G. P. Nijhoff and A. J. Gerver, J. Am, Physik, Vol, 12, 562 (1932).
J. Mizushima, K. Ono, and A. Ohno, J. Chem. Phys., Vol, 21, 2107 (1953).
L. Holborn and J. Otto, Z. Physik, Vol, 33, 1 (1925).
E. Kanda, Science Repts. Research Insts, Tohoku Univ., Ser, E. Vol. 1, 157 (1946).
C.M. Knobler, J. J.M. Beemakker, and H.F.P. Knapp, Physica, Vol. 25, 909 (1959).
G.M. Kramer and j.G. Miller, J. Phys, Chem., Vol 61, 785 (1957).
R.C. Harper Jr. and J.G. Miller, Chem. Phys., Vol. 27, 36 (1957).
R. J. Lunbeck and A. J. H. Boerboom, Physica, Vol. 17, 76. (1951).
R. A. Gorski and j.G. Miller, J. Am. Chem. Soc., Vol. 75, 550 (1953).
T. L. Cottrell et al., Trans. Faraday Soc., Vol. 52, 156, 310 (1956).
J. Peuss and J. J.M. Beennakker, Physics, Vol. 22, 869 (1956).
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Leland, T.W., Kobayashi, R., Mueller, W.H. (1961). Application of the Corresponding States Principle to Mixtures of Low Molecular Weight Gases at Low Temperatures and Elevated Pressures. In: Timmerhaus, K.D. (eds) Advances in Cryogenic Engineering. Advances in Cryogenic Engineering, vol 6. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0534-8_45
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DOI: https://doi.org/10.1007/978-1-4757-0534-8_45
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