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Application of the Corresponding States Principle to Mixtures of Low Molecular Weight Gases at Low Temperatures and Elevated Pressures

  • T. W. Leland
  • R. Kobayashi
  • W. H. Mueller
Conference paper
Part of the Advances in Cryogenic Engineering book series (ACRE, volume 6)

Abstract

There are two main avenues of approach in applying the corresponding states principle to multicomponent systems. One is through the use of reduced virial coefficients introduced by Guggenheim [1], Guggenheim and McGlashan [2], and further developed by Prausnitz and Gunn [3]. The other is through the use of composition dependent pseudo- critical properties proposed originally by Kay [4] with later improvements by Joffe [5], Stewart et al. [6] and Leland and Mueller [7]. The method of reduced virials is more rigorous theoretically but tine thermo-dynamic properties evaluated from it are limited to conditions under which the gas behavior can be described by equations involving only the second virial. The method of pseudo-criticals, while more empirical in nature, does not completely neglect the effect of higher virials.

Keywords

Force Constant Quantum Effect Virial Coefficient Reference Substance High Virials 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1961

Authors and Affiliations

  • T. W. Leland
    • 1
  • R. Kobayashi
    • 1
  • W. H. Mueller
    • 1
  1. 1.Rice UniversityHoustonUSA

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