The Study of Interactions between Iron Particles Encapsulated in Zeolites of the Faujasit-Type and the Matrix

  • Ahadul I. Quazi
  • F. Schmidt


Fe(CO)5·Zeolite-adducts were thermally decomposed under vacuum and under argon gas atmosphere. While small as well as relatively large iron clusters were formed under vacuum decomposition, Fe(II) and [Fe3(CO)11] species were formed under argon gas atmosphere. In order to identify the formed particles, a variety of measurements was carried out, such as thermal desorption spectroscopy (TDS), Mössbauer Effect spectroscopy (MES), IR-spectroscopy and magnetic measurements.


Magnetic Measurement Isomer Shift Quadrupole Splitting Iron Particle Zeolite Type 
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Copyright information

© Plenum Press, New York 1987

Authors and Affiliations

  • Ahadul I. Quazi
    • 2
  • F. Schmidt
    • 1
  1. 1.Institut für Physikalische ChemieUniversität HamburgHamburg 13Germany
  2. 2.Department of ChemistryUniversity of MichiganAnn ArborUSA

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