Abstract
At the last Cryogenic Engineering Conference, Zudkevitch and Gray [1] presented a paper on the importance of fluid property predictions to the design of liquefied natural gas (LNG) processes. This paper was disturbing in that it illustrated the serious consequences of discrepancies in calculated properties small enough to bring some degree of satisfaction to those who work at these predictions. In some cases an uncertainty as small as 4 K in a bubble point temperature or a 1% error in liquid density can have exceptionally adverse economic effects. Although there has been notable progress in predicting properties of liquefied natural gas mixtures [2,3], there still remains a challenge to achieve this degree of accuracy consistently. Furthermore, the challenge is even more severe in that we must soon deal with a whole new range of fluids arising from coal and shale processing.
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References
D. Zudkevitch and R. D. Gray, in: Advances in Cryogenic Engineering, Vol. 20, Plenum Press, New York (1975), p. 103.
G. D. Fisher and T. W. Leland, Ind. Eng. Chem. Fundamentals 9:537 (1970).
J. Mollerup and J. S. Rowlinson, Chem. Eng. Sci. 29:1373 (1974).
J. S. Rowlinson, Liquids and Liquid Mixtures, 2nd ed., Butterworths, London (1969).
J. A. Pople, Proc. Roy. Soc. (London) A221:498, 508 (1954).
D. Cook and J. S. Rowlinson, Proc. Roy. Soc. (London) A219:405 (1953).
Y. D. Chen and W. A. Steele,J. Chem. Phys. 50:1428 (1969)
Y. D. Chen and W. A. Steele,J. Chem. Phys. 52:5284 (1970).
K. E. Gubbins, C. G. Gray, P. A. Eglestaff, and M. S. Ananth, Mol Phys. 25:1353 (1973)
K. E. Gubbins, C. G. Gray, P. A. Eglestaff, and M. S. Ananth, Mol Phys. 23:187 (1972).
K. C. Mo and K. E. Gubbins, Chem. Phys. Utters 27:144 (1974).
K. C. Mo, K. E. Gubbins, G. Jacucci, and I. R. McDonald, Mol. Phys. 27:1173 (1974).
G. S. Rushbrooke, G. Stell, and J. S. Hoye, Mol. Phys. 26:1199 (1973).
W. A. Steele and S. I. Sandler, J. Chem. Phys. 61:1315 (1974).
S. S. Wang, P. A. Eglestaff, C. G. Gray, and K. E. Gubbins, Chem. Phys. Letters 24:453 (1974).
T. W. Leland and P. S. Chappelear, Ind. Eng. Chem. 60:15 (1968).
P. L. Chueh and J. M. Prausnitz, AIChE J. 13:1099, 1107 (1967).
M. J. Hiza and A. G. Duncan, Phys. Fluids 12:1531 (1969).
G. H. Hudson and J. C. McCoubrey, Trans. Faraday Soc. 56:761 (1960).
R. C. Reid and T. W. Leland, AIChE J. 11:228 (1965)
R. C. Reid and T. W. Leland, AIChE J. 12:1227 (1966).
B. M. Axilrod and E. Teller,J. Chem. Phys. 11:299 (1943).
R. J. Bell and A. E. Kingston, Proc. Phys. Soc. 88:901 (1966).
G. A. Mansoori and T. W. Leland,J. Chem. Soc, Faraday Trans. II 68:320 (1972).
J. A. Barker, R. A. Fisher, and R. O. Watts, Mol. Phys. 21:657 (1971).
T. L. Hill, Statistical Mechanics, McGraw-Hill, New York (1956).
B. J. Alder and T. W. Wainwright,J. Chem. Phys. 33:1439 (1960).
A. Rahman, Phys. Rev. 136:A405 (1964).
W. W. Wood and F. R. Parker, J. Chem. Phys. 27:720 (1957).
I. R. McDonald and K. Singer, Chemistry in Britain 9:54 (1973).
J. L. Lebowitz, Phys. Rev. 133:A895 (1964).
J. L. Lebowitz and J. S. Rowlinson,J. Chem. Phys. 41:133 (1964).
H. C. Andersen, J. D. Weeks, and D. Chandler, Phys. Rev. A4:1597 (1971).
T. W. Leland, P. S. Chappelear, and B. W. Gamson, AIChE J. 8:482 (1962).
T. W. Leland, J. S. Rowlinson, and G. A. Sather, Trans. Faraday Soc. 64:1447 (1968).
L. Verlet, Phys. Rev. 165:201 (1968).
K. E. Gubbins, private communication (1975).
C. H. Twu, K. E. Gubbins, and C. G. Gray, Mol. Phys. 29:713 (1975).
I. Prigogine, The Molecular Theory of Solutions, North-Holland, Amsterdam, Interscience, New York (1957).
J. H. Hildebrand and R. B. Scott, The Solubility of Non-Electrolytes, Reinhold, New York (1950).
K. C. Chao and J. D. Seader, AIChE J. 7:598 (1961).
E. W. Lyckman, C. A. Eckert, and J. M. Prausnitz, Chem. Eng. Sci. 20:703 (1965).
A. Bellemans and E. De Vos, to be published.
J. M. Prausnitz, W. C. Edminster, and K. C. Chao, AIChE J. 6:214 (1960).
J. Gonsalves, Ph.D. Dissertation, Rice University, Houston, Texas (1977).
T. L. Hill, Introduction to Statistical Thermodynamics, Addison-Wesley, Reading, Massachusetts (1960).
J. O. Hirschfelder, C. F. Curtiss, and R. B. Bird, Molecular Theory of Gases and Liquids, John Wiley, New York (1954).
J. A. Barker and D. Henderson,J. Chem. Phys. 47:4714 (1967).
N. F. Carnahan and K. E. Starling,J. Chem. Phys. 51:635 (1969).
G. A. Mansoori, N. F. Carnahan, K. E. Starling, and T. W. Leland,J. Chem. Phys. 54:1523 (1971).
H. L. Frisch, J. L. Katz, E. Praestgaard, and J. L. Lebowitz, J. Phys. Chem. 70:2016 (1966).
G. A. Mansoori and T. W. Leland,J. Chem. Phys. 53:1931 (1970).
G. A. Mansoori, J. A. Provine, and F. B. Canfield,J. Chem. Phys. 51:5295 (1969).
R. W. Zwanzig,J. Chem. Phys. 22:1420 (1954).
J. S. Rowlinson, Mol. Phys. 7:349 (1964)
J. S. Rowlinson, Mol. Phys. 8:107 (1965).
R. M. Gibbons, Mol. Phys. 17:81 (1969).
M. Rigby,J. Chem. Phys. 53:1021 (1970).
L. Verlet and J. J. Weis, Phys. Rev. A 5:939 (1972).
P. J. Leonard, D. Henderson, and J. A. Barker, Trans. Faraday Soc. 66:2439 (1970).
E. W. Grundke and D. Henderson, Mol. Phys. 24:269 (1972).
H. Reis, H. L. Frisch, and J. L. Lebowitz, J. Chem. Phys. 31:369 (1959).
M. S. Wertheim,J. Chem. Phys. 55:4291 (1971).
S. Sung and D. Chandler, J. Chem. Phys. 56:4989 (1972).
G. Stell, J. Rasaiah, and H. Narang, Mol. Phys. 23:393 (1972).
B. L. Rogers and J. M. Prausnitz, Trans. Faraday Soc. 67:3474 (1971).
J. W. Leach, P. S. Chappelear, and T. W. Leland, Proc. Amer. Petroleum Inst., Section III 46:223 (1966).
J. W. Leach, P. S. Chappelear, and T. W. Leland, AIChE J. 14:568 (1968).
K. E. Starling, Hydrocarbon Processing 50(3): 101; (4): 139; (6): 116; (7): 115; (9): 171; (10):90(1972); 51(2):86;(5):107(1973).
N. S. Snider and T. M. Herrington,J. Chem. Phys. 47:2248 (1967).
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Leland, T.W. (1960). Recent Developments in the Theory of Fluid Mixtures. In: Timmerhaus, K.D., Weitzel, D.H. (eds) Advances in Cryogenic Engineering. Advances in Cryogenic Engineering, vol 21. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0208-8_56
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