Abstract
Regions of phase separation, both stable and metastable, have now been detected in most simple silicate systems. Various aspects of phase separation have been discussed in detail in the literature, mainly from the thermodynamic standpoint, and many relationships in these phenomena have been explained. Application of the theory of ideal and regular solutions proved adequate for qualitative and in some instances also for quantitative description of phase-separation phenomena. However, thermodynamic treatment is concerned mainly with the state of the system and says very little about the nature of the phenomenon itself [1]. In this communication we attempt to examine, in general form, processes of phase separation in binary silicate systems, using known experimental data and analyzing various views of their nature.
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Literature Cited
I. N. Belyaev, Usp. Khim., 29:899 (1960).
B. E. Warren and A. C. Pincus, J. Am. Ceram. Soc., 23:301 (1940).
E. M. Levin and S. Block, J. Am. Ceram, Soc., 40:95, 113 (1957); 41:49 (1958).
E. M. Levin, J. Am. Ceram. Soc., 50:29 (1967).
N. V. Belov, Kristallografiya, 5:15 (1960).
O. A. Esin, Proceedings of the Second All-Union Conference on Theoretical and Applied Electrochemistry, Izd, Akad. Nauk Ukr. SSR, Kiev (1949), p. 215.
E. C. De Wys, Mineral. Mag., 32(249):471 (1960).
W. A. Weyl and E. C. Marboe, Glass Ind., 41:429, 487,549, 620, 687 (1960); 42:23, 76, 123, 194 (1961).
B. I. Markhasev and I. D. Sedletskii, Dokl. Akad. Nauk SSSR, 148:916 (1963); 154:1225 (1964).
A. Dietzel, Z. Elektrochem., 48(19):9 (1942).
F. P. Glasserv I. Warshaw, and K. Roy, Phys. Chern. Glasses, 1:39 (1960).
N. A. Toropov and F. Ya. Galakhov, Izv. Akad. Nauk SSSR., Otd. Khim. Nauk, No.2, p. 158 (1956).
M. L. Keith, J. Am. Ceram. Soc., 37:491 (1954).
G. S. Zhdanov, Physics of the Solid State, Izd, Mosk. Gos. Univ., Moscow (1962), p. 184.
F. Ya. Galakhov and S. F. Konovalova, Izv. Akad, Nauk SSSR, Sere Khim., No.8, p. 1373 (1964).
J. F. MacDowell, Ind. Eng. Chem., 58(3):38 (1966).
Y. Moria, D. H. Warrington, and R. W. Douglas, Phys. Chern. Glasses, 8, p. 19 (1967).
Ya. L. Oshanskii, Dokl. Akad, Nauk SSSR, 26:93 (1951).
R. J. Charles, Phys. Chem. Glasses, 8:185 (1967).
N. A. Toropov and V. A. Vasil’eva, Kristallografiya, 6:968 (1961).
N. A. Toropov and I. A. Bondar, Izv, Akad, Nauk SSSR Otd, Khim. Nauk, No.4, p, 544 (1961).
N. A. Toropov and I. A. Bondar, Izv, Akad. Nauk SSSR, Otd. Khim, Nauk, No.5, p. 739 (1961).
N. A Toropov and T. P. Kiseleva, ‘I’r, Leningr. Tekhnol. Inst. Im, Lensoveta, 52:76 (1961).
N. A. Toropov and I. A. Bondar, Izv. Akad, Nauk SSSR, Otd. Khim. Nauk, No.8, p. 1372 (1961).
N. A. Toropov, F. Ya. Galakhov, and S. F. Konovalova, Izv, Akad, Nauk SSSR, Otd. Khim. Nauk, No.4, p. 539 (1961).
N. A. Toropov, F. Ya. Galakhov, and S. F. Konovalova, Izv, Akad. Nauk SSSR., Otd, Khim. Nauk, No.8, p. 1365 (1961).
R. S. De Vries, R. Roy, and E. F. Osborn, Trans. Brit. Ceram, Soc., 53:525 (1954).
T. P. Seward III, D. R. Uhlmann, and D. Turnbull, J. Am. Ceram. Soc., 51:278 (1968).
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Galakhov, F.Y., Varshal, B.G. (1973). Causes of Phase Separation in Simple Silicate Systems. In: Porai-Koshits, E.A. (eds) Phase-Separation Phenomena in Glasses / Likvatsionnye Yavleniya v Steklakh / Ликвационные Явления в Стеклах. The Structure of Glass / Stekloobraznoe Sostoyanie / Стеклооьразное Состояние. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0157-9_2
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DOI: https://doi.org/10.1007/978-1-4757-0157-9_2
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