Skip to main content

Negative-Ion—Neutral Reactions

  • Chapter
Ion-Molecule Reactions

Abstract

This chapter is concerned principally with two-body reactions between negative ions and neutral molecules at low energies in the gas phase. Introductory material on the formation and disappearance of negative ions is also included. Emphasis is placed on results arising from the use of mass spectrometer ion sources or double mass spectrometers as the experimental technique. Additional information on negative-ion-neutral reactions may be found in Chapters 7, 8, 11, 15, and 16 of this book.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. P.J. Chantry and G.J. Schulz, Phys. Rev. 156, 134 (1967).

    CAS  Google Scholar 

  2. W.R. Henderson, W.L. Fite, and R.T. Brackmann, Phys. Rev. 183, 157 (1969).

    CAS  Google Scholar 

  3. G.J. Schulz and D. Spence, Phys. Rev. Lett. 22, 47 (1969).

    CAS  Google Scholar 

  4. P.J. Chantry, J. Chem. Phys. 51, 3369 (1969).

    CAS  Google Scholar 

  5. G.J. Schulz, J. Chem. Phys. 34, 1778(1961).

    CAS  Google Scholar 

  6. A.V. Phelps, Can. J. Chem. 47, 1783 (1969).

    CAS  Google Scholar 

  7. J.L. Pack and A.V. Phelps, J. Chem. Phys. 45, 4316 (1966).

    CAS  Google Scholar 

  8. J.D. Craggs and H.S.W. Massey, in “Handbuch der Physik,” Vol. 37, p. 362. Springer Verlag, Berlin (1959).

    Google Scholar 

  9. R.S. Berry, Chem. Revs. 69, 533 (1969).

    CAS  Google Scholar 

  10. Ya. M. Fogel, V.F. Kozlov, and A.A. Kalmykov, Soviet Phys.-JETP 36, 963 (1959).

    Google Scholar 

  11. B. Brehm, M.A. Gusinow, and J.L. Hall, Phys. Rev. Lett. 19, 737 (1967).

    CAS  Google Scholar 

  12. L.M. Branscomb, in “Atomic and Molecular Processes” (D.R. Bates, ed.), Chapter 4, Academic Press, New York (1962).

    Google Scholar 

  13. E.W. McDaniel, “Collision Phenomena in Ionized Gases,” Chapter 8, John Wiley and Sons, New York (1964).

    Google Scholar 

  14. J.L. Franklin, P.M. Hierl, and D.A. Whan, J. Chem. Phys. 47, 3148 (1967).

    CAS  Google Scholar 

  15. K. Birkinshaw, A.J. Masson, D. Hyatt, L. Matus, I. Opauszky, and M.J. Henchman, Advan. Mass. Spectry. 4, 379 (1968).

    CAS  Google Scholar 

  16. K.R. Ryan, J.H. Futrell, and C.D. Miller, Rev. Sci. Instr. 37, 107 (1966).

    CAS  Google Scholar 

  17. J.F. Paulson, “Abstracts of Sixth Int. Conf. on the Physics of Electronic and Atomic Collisions,” p. 75, MIT Press, Cambridge, Mass. (1969).

    Google Scholar 

  18. J. F. Paulson, F. Dale, and S. A. Studniarz, Int. J. Mass Spectrom. Ion Phys. 5, 113 (1970).

    CAS  Google Scholar 

  19. C.L. Pekeris, Phys. Rev. 126, 1470 (1962).

    CAS  Google Scholar 

  20. M.J. Woolf, M. Schwarzschild, and W. K. Rose, Astrophys. J. 140, 833 (1964).

    CAS  Google Scholar 

  21. D. Wobschall, J.R. Graham, and D.P. Malone, J. Chem. Phys. 42, 3955 (1965).

    CAS  Google Scholar 

  22. R. Fischer, H. Neuert, K. Peuckert-Kraus, and D. Vogt, Z. Naturforsch. 21a, 501 (1966).

    Google Scholar 

  23. H.O. Pritchard, Chem. Rev. 52, 529 (1953).

    CAS  Google Scholar 

  24. J.L. Pack and A.V. Phelps, J. Chem. Phys. 44, 1870 (1966).

    CAS  Google Scholar 

  25. D. Vogt, B. Hauffe, and H. Neuert, Z. Physik 232, 439 (1970).

    CAS  Google Scholar 

  26. J. F. Paulson, unpublished results.

    Google Scholar 

  27. D. B. Dunkin, F. C. Fehsenfeld, and E. E. Ferguson, J. Chem. Phys. 53, 987 (1970).

    CAS  Google Scholar 

  28. T.L. Bailey and P. Mahadevan, J. Chem. Phys. 52, 179 (1970).

    CAS  Google Scholar 

  29. J. A.D. Stockdale, R.N. Compton, and P.W. Reinhardt, Phys. Rev. Lett. 21, 664 (1968).

    CAS  Google Scholar 

  30. J.A.D. Stockdale, R.N. Compton, and P.W. Reinhardt, Phys. Rev. 184, 81 (1969).

    CAS  Google Scholar 

  31. J.F. Paulson, in “Ion-Molecule Reactions in Gases” (Advances in Chemistry Series, No. 58, P.J. Ausloos, ed.), p. 28, American Chemical Society, Washington, D.C. (1966).

    Google Scholar 

  32. M.L. Seman and L.M. Branscomb, Phys. Rev. 125, 1602 (1962).

    CAS  Google Scholar 

  33. J.L. Hall and M.W. Siegel, J. Chem. Phys. 48, 943 (1968).

    CAS  Google Scholar 

  34. J.F. Paulson, J. Chem. Phys. 52, 5520 (1970).

    Google Scholar 

  35. F. C. Fehsenfeld and E. E. Ferguson, J. Chem. Phys. 53, 2614 (1970).

    CAS  Google Scholar 

  36. E. W. McDaniel, “Collision Phenomena in Ionized Gases,” p. 372, John Wiley and Sons, New York (1964).

    Google Scholar 

  37. B.L. Moiseiwitsch, Advan. Atomic Molec. Phys. 1, 61 (1965).

    Google Scholar 

  38. P.J. Chantry and G.J. Schulz, Phys. Rev. 156, 134 (1967).

    CAS  Google Scholar 

  39. L.M. Branscomb, D.S. Burch, S.J. Smith, and S. Geltman. Phys. Rev. 111, 504 (1958).

    CAS  Google Scholar 

  40. J.D. Martin and T.L. Bailey, J. Chem. Phys. 49, 1977 (1968).

    CAS  Google Scholar 

  41. F. C. Fehsenfeld, E. E. Ferguson, and A. L. Schmeltekopf, J. Chem. Phys. 45, 1844 (1966).

    CAS  Google Scholar 

  42. F.C. Fehsenfeld and E.E. Ferfuson, J. Chem. Phys. 51, 3512 (1969).

    CAS  Google Scholar 

  43. J.L. Moruzzi, J.W. Ekin, and A.V. Phelps, J. Chem. Phys. 48, 3070 (1968).

    CAS  Google Scholar 

  44. A.E. Roche and C.C. Goodyear, J. Phys. B 2, 191 (1969).

    Google Scholar 

  45. D. Vogt, Int. J. Mass Spectrom. Ion Phys. 3, 81 (1969).

    CAS  Google Scholar 

  46. J. A. Rutherford and B.R. Turner, J. Geophys. Res. 72, 3795 (1967).

    CAS  Google Scholar 

  47. G. Herzberg, “Electronic Spectra of Polyatomic Molecules,” D. Van Nostrand, Princeton, N.J. (1966).

    Google Scholar 

  48. A. G. Gaydon, “Dissociation Energies and Spectra of Diatomic Molecules,” 3rd ed., Chapman and Hall, London (1968).

    Google Scholar 

  49. L.M. Branscomb, Phys. Rev. 148, 11 (1966).

    CAS  Google Scholar 

  50. E.E. Ferguson, Advan. Electron. Electron Phys. 24, 23 (1968).

    Google Scholar 

  51. B.P. Burtt and J. Henis, J. Chem. Phys. 41, 1510 (1964).

    CAS  Google Scholar 

  52. P.J. Chantry, J. Chem. Phys. 51, 3380 (1969).

    CAS  Google Scholar 

  53. J. Schaeffer and J.M.S. Henis, J. Chem. Phys. 49, 5377 (1968).

    Google Scholar 

  54. J.F. Paulson, J. Chem. Phys. 52, 959 (1970).

    CAS  Google Scholar 

  55. C.F. Giese, in “Ion-Molecule Reactions in Gases” (Advances in Chemistry Series, No. 58, P.J. Ausloos, ed.), p. 20, American Chemical Society, Washington, D.C. (1966).

    Google Scholar 

  56. R.F. Stebbings, B.R. Turner, and J.A. Rutherford, J. Geophys. Res. 71, 771 (1966).

    CAS  Google Scholar 

  57. J.J. Kaufman and W.S. Koski, J. Chem. Phys. 50, 1942 (1969).

    CAS  Google Scholar 

  58. J.F. Paulson, J. Chem. Phys. 52, 963 (1970).

    CAS  Google Scholar 

  59. R.K. Curran, Phys. Rev. 125, 910 (1962).

    CAS  Google Scholar 

  60. A. Henglein and G. A. Muccini, Chemical Effects of Nuclear Transformations, pp. 89–98, International Atomic Energy Agency, Vienna (1961).

    Google Scholar 

  61. A. Henglein and G.A. Muccini, J. Chem. Phys. 31, 1426 (1959).

    CAS  Google Scholar 

  62. E.E. Ferguson, F.C. Fehsenfeld, and A. L. Schmeltekopf, in “Advances in Chemistry Series,” No. 80, p. 83, American Chemical Society, Washington, D.C. (1969).

    Google Scholar 

  63. W.R. Snow, R D. Rundel, and R. Geballe, Phys. Rev. 178, 228 (1969).

    CAS  Google Scholar 

  64. J. Berkowitz, W.A. Chupka, and D. Gutman, private communication (1970).

    Google Scholar 

  65. F.R. Gilmore, J. Quant. Spectry. Radiative Transfer 5, 369 (1965).

    CAS  Google Scholar 

  66. A.L. Farragher, F.M. Page, and R.C. Wheeler, Disc. Faraday Soc. 37, 203 (1964).

    Google Scholar 

  67. F.C. Fehsenfeld and E.E. Ferguson, Planet. Space Sci. 16, 701 (1968).

    CAS  Google Scholar 

  68. W.C. Lineberger and B.W. Woodward, Phys. Rev. Letters 25, 424 (1970).

    CAS  Google Scholar 

  69. B. Steiner, J. Chem. Phys. 49, 5097 (1968).

    CAS  Google Scholar 

  70. P. Warneck, Chem. Phys. Lett. 3, 532 (1969).

    CAS  Google Scholar 

  71. E.E. Ferguson, Can. J. Chem. 47, 1815 (1969).

    CAS  Google Scholar 

  72. A.D. Walsh, J. Chem. Soc. 1953, 2260.

    Google Scholar 

  73. E. E. Ferguson, F. C. Fehsenfeld, and A. L. Schmeltekopf, J. Chem. Phys. 47, 3085 (1967).

    CAS  Google Scholar 

  74. A.V. Phelps, Rev. Mod. Phys. 40, 399 (1968).

    CAS  Google Scholar 

  75. R.J. Cook and D.H. Whiffen, J. Phys. Chem. 71, 93 (1967).

    CAS  Google Scholar 

  76. J.N. Bardsley, J. Chem. Phys. 51, 3384 (1969).

    CAS  Google Scholar 

  77. C.R. Claydon, G.A. Segal, and H.S. Taylor, J. Chem. Phys. 52, 3387 (1970).

    CAS  Google Scholar 

  78. F.C. Fehsenfeld, A.L. Schmeltekopf, H.I. Schiff, and E.E. Ferguson, Planetary Space Sci. 15, 373 (1967).

    CAS  Google Scholar 

  79. K. Peuckert-Kraus, Ann. Physik 18, 288 (1966).

    CAS  Google Scholar 

  80. K. Kraus, W. Muller-Duysing, and H. Neuert, Z. Naturforsch. 16a, 1385 (1961).

    CAS  Google Scholar 

  81. K. Kraus, W. Muller-Duysing, and H. Neuert, in “Proc. Fifth Int. Conf. on Ionization Phenomena in Gases,” p. 1221, North-Holland Publishing Co., Amsterdam, (1961).

    Google Scholar 

  82. J.G. Dillard and J.L. Franklin, J. Chem. Phys. 48, 2349 (1968).

    CAS  Google Scholar 

  83. J.G. Dillard and J.L. Franklin, J. Chem. Phys. 48, 2353 (1968).

    CAS  Google Scholar 

  84. F. C. Fehsenfeld, A. L. Schmeltekopf, D. B. Dunkin, and E. E. Ferguson, ESSA Technical Report ERL 135-AL-3, U.S. Department of Commerce, Boulder, Colorado 1969; available from the Superintendent of Documents, U.S. Government Printing Office, Washington, D. C.

    Google Scholar 

  85. Bibliography of Atomic and Molecular Collision Processes, compiled by the Atomic and Molecular Processes Information Center, Oak Ridge National Laboratory, Oak Ridge, Tenn.; available from the Clearing House for Federal Scientific and Technical Information, National Bureau of Standards, U.S. Department of Commerce, Springfield, Virginia.

    Google Scholar 

  86. G.A. Sinnott, “Bibliography of Ion-Molecule Reaction Rate Data,” JILA Information Center Report No. 9, University of Colorado, Boulder, 1969.

    Google Scholar 

  87. V. Cermak, A. Dalgarno, E. E. Ferguson, L. Friedman, and E. W. McDaniel, “Ton-Molecule Reactions,” John Wiley and Sons, New York (1970).

    Google Scholar 

  88. W.A. Chupka, J. Berkowitz, and D. Gutman, J. Chem. Phys. 55, 2724 (1971).

    CAS  Google Scholar 

  89. J. Berkowitz, W.A. Chupka, and D. Gutman, J. Chem. Phys. 55, 2733 (1971).

    CAS  Google Scholar 

  90. T.O. Tiernan, B. M. Hughes, and C. Lifschitz, J. Chem. Phys. 55, 5692 (1971).

    CAS  Google Scholar 

  91. C. Lifschitz, B. M. Hughes, and T. O. Tiernan, Chem. Phys. Letters 7, 469 (1970).

    Google Scholar 

  92. P.R. Kinsman and J. A. Rees, Int. J. Mass Spectrom. Ion Phys. 5, 71 (1970).

    CAS  Google Scholar 

  93. R.M. Snuggs, D.J. Volz, I.R. Gatland, J.H. Schummers, D.W. Martin, and E.W. McDaniel, Phys. Rev. A3, 487 (1971).

    Google Scholar 

  94. D.A. Parks, Trans. Far. Soc. 67, 711 (1971).

    Google Scholar 

  95. L.G. McKnight, Phys. Rev. A2, 762 (1970).

    Google Scholar 

  96. J.A.D. Stockdale, R.N. Compton, and P.W. Reinhardt, Int. J. Mass Spectrom. Ion Phys. 4, 401 (1970).

    CAS  Google Scholar 

  97. D.K. Bohme and L.B. Young, J. Am. Chem. Soc. 92, 3301 (1970).

    CAS  Google Scholar 

  98. M. Arshadi, R. Yamdagni, and P. Kebarle, J. Phys. Chem. 74, 1475 (1970).

    CAS  Google Scholar 

  99. M. Arshadi and P. Kebarle, J. Phys. Chem. 74, 1483 (1970).

    CAS  Google Scholar 

  100. L.J. Puckett and W.C. Lineberger, Phys. Rev. A1, 1635 (1970).

    Google Scholar 

  101. E.E. Ferguson, Accounts Chem. Res. 3, 402 (1970).

    CAS  Google Scholar 

  102. L.G. McKnight and J.M. Sawina, Phys. Rev. A4, 1043 (1971).

    Google Scholar 

  103. F.C. Fehsenfeld, J. Chem. Phys. 54, 438 (1971).

    CAS  Google Scholar 

  104. T.C. Rhyne and J.G. Dillard, Int. J. Mass Spectrom. Ion Phys. 7, 371 (1971).

    CAS  Google Scholar 

  105. A. DiDomenico, D.K. Sen Sharma, J.L. Franklin, and J.G. Dillard, J. Chem. Phys. 54, 4460 (1971).

    CAS  Google Scholar 

  106. R. E. Center, J. Chem. Phys. 56, 371 (1972).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1972 Plenum Press, New York

About this chapter

Cite this chapter

Paulson, J.F. (1972). Negative-Ion—Neutral Reactions. In: Franklin, J.L. (eds) Ion-Molecule Reactions. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0088-6_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4757-0088-6_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4757-0090-9

  • Online ISBN: 978-1-4757-0088-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics