Advertisement

The Thermodynamic Estimation of the Surface Energy of Solids

  • L. M. Shcherbakov
Conference paper

Abstract

Surface phenomena play an important part in metallurgical production processes. A detailed analysis of this part is given in a number of articles of the present collection [1], and also in text books [2–4]. The question of the numerical estimation of the surface energy of solids becomes one of considerable importance. Unfortunately, there are no direct methods of measurement similar to those known for liquids, and therefore the use of various indirect or purely mathematical methods is unavoidable. The possible methods of the thermodynamic estimation of the surface energy of solids will be discussed.

Keywords

Surface Tension Surface Energy Disperse System Surface Phenomenon Limit Transition 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature Cited

  1. 1.
    A. I. Belyaev, this volume, p. 3; V. I. Yavoiskii, ibid., p. 17; V. N. Eremenko and V. I. Nizhenko, ibid., p. 28Google Scholar
  2. 2.
    V. D. Kuznetsov, Surface Energy of Solids, Moscow, 1954.Google Scholar
  3. 3.
    L. L. Kunin, Surface Phenomena in Metals, Moscow, 1955.Google Scholar
  4. 4.
    V. K. Semenchenko, Surface Phenomena in Metals and Alloys, 1957.Google Scholar
  5. 5.
    Van der Walls, Z. phys. Chem. 13:657, 1894.Google Scholar
  6. 6.
    G. Bakker, Z. phys. Chem. 104:10, 1923; G. Bakker, Kapillaritat und Oberflachenspannung, Handb. d. experim. Physik, VI, Vienna-Hamburg, p. 1928.Google Scholar
  7. 7.
    J. W. Gibbs, Thermodynamic Papers [Russian translation], 1955.Google Scholar
  8. 8.
    P. E. Strebeiko, Effect of Crushing on Transition Temperatures, Dissertation, IONKh Akad. Nauk SSSR, 1939.Google Scholar
  9. 9.
    Yu. V. Vul’f, Selected Papers on Crystal Physics and Crystallography, Moscow-Leningrad, 1952, p. 96.Google Scholar
  10. 10.
    L. M. Shcherbakov, Phase Equilibria in Systems with Developed Interfaces, Dissertation, IFKh Akad. Nauk SSSR, 1950.Google Scholar
  11. 11.
    Born and Stern, Stizungsber, d. preuss. Akad. 33:901, 1919.Google Scholar
  12. 12.
    Ya. I. Frenkel’, Electrical Theory of Solids, 1924Google Scholar
  13. 13.
    A. E. Glauberman, Zh. Fiz. Khim. 23:124, 1949; S. N. Zadumkin, Dokl. Akad. Nauk SSSR, 12:453, 1957; S. N. Zadumkin, Izv. Vuzov, Fiz. (2): 151, 1958.Google Scholar
  14. 14.
    J. Stefan, Ann. Physik 29:655, 1886.CrossRefGoogle Scholar
  15. 15.
    P. I. Walden, Z. phys. Chem. 5:129, 257, 1909.Google Scholar
  16. 16.
    L. M. Shcherbakov and V. I. Rykov, Kolloidn, Zh. 23:221, 1961.Google Scholar
  17. 17.
    W. Ostwald, Z. phys. Chem. 34:495,1900.Google Scholar
  18. 18.
    H. Freundlich, Kapillarchemie, Vol. I, Leipzig, 1930, p. 268.Google Scholar
  19. 19.
    A. Huliet, Z. phys. Chem. 37:385, 1901; (47):357, 1904.Google Scholar
  20. 20.
    S. Glasstone, J. Chem. Soc. 119:1589, 1922.Google Scholar
  21. 21.
    M. L. Dundon, J. Am. Chem. Soc. 45:2658, 1923CrossRefGoogle Scholar
  22. 22.
    M. Ya. Reznikov, Uch. Zap. Belorussk. Gos. Univ. p. 129.Google Scholar
  23. 23.
    W. J. Jones, Ann. Physik B41:441, 1913.CrossRefGoogle Scholar
  24. 24.
    V. K. Semenchenko, Zh. Fiz. Khim. (19):298, 1945.Google Scholar
  25. 25.
    V. I. Rykov, Uch. Zap, Kishinevsk. Gos. Univ. (1):37, 1949.Google Scholar
  26. 26.
    P. P. Ryazantsev and L. M. Shcherbakov, Kolloidn, Zh. 21:464, 1959.Google Scholar
  27. 27.
    S. G. Lipsett, F. M. Johnson, and O. Maas, J. Am,Chem. Soc. 49:925, 1927; (49):1940, 1927; (50):270, 1928.Google Scholar
  28. 28.
    G. S. Benson and G. W. Benson, J. Can. Chem. 33:232, 1955; G. S, Benson, H. P. Shreiber, and F. Zeggeren, Ibid, 34:1553, 1956; P. Balk and G. S. Benson, J.Phys. Chem. 63:1009, 1959.CrossRefGoogle Scholar
  29. 29.
    G. Tamman, Z. Anorg. Allgem. Chem, 110:166, 1920; F. Meissner, Ibid, 110:169, 1920.CrossRefGoogle Scholar
  30. 30.
    R. C. Sill and A. S. Skapski, J. Chem. Soc. 24:644, 1956; A. S. Skapski, R. Billups, and D. Casavant, Ibid, 31:1431, 1959.Google Scholar
  31. 31.
    L. S. Palatnik and Yu. F. Komnik, Fiz. Metal, i Metalloved. (9):374, 1960.Google Scholar
  32. 32.
    P. E. Strebeiko, Tr. Krasnodarsk. Khim,-Tekhn. Inst. (8):3, 1940.Google Scholar
  33. 33.
    B. Sreznevskii, Zh. Russk. Fiz.-Khim. Obshchestva, 15:39, 1883.Google Scholar
  34. 34.
    R. Helmholtz, Ann. Phys. B27:508, 1886CrossRefGoogle Scholar
  35. 35.
    M. L. Honllevique, J. Phys. Theor. et Appliq. 3:159, 1896.Google Scholar
  36. 36.
    L. M. Shcherbakov, Izv. Vuzov, Fiz. (4):77, 1959.Google Scholar
  37. 37.
    O. M. Poltorak, Zh. Fiz. Khim. 31:2477, 1957; 32:722, 1958; 34:3, 1960; O. M. Poltorak, Vestn. Mask. Univ., Ser. Mat. Mekhan., Astron., Fiz. iKhim. (5):165, 1958Google Scholar
  38. 38.
    L. M. Shcherbakov, Uch. Zap. Kishinevsk. Gos. Univ. (1):11, 1949; (5):117, 1952.Google Scholar
  39. 39.
    O. M. Todes, Zh. Fiz. Khim. 20:629, 1946; O. M. Todes and V, V. Khrushchev, Zh. Fiz. Khim, 21:301, 1947.Google Scholar
  40. 40.
    V. I. Danilov, Zh. Eksperim. i Teor. Fiz. 19:235, 1949; V, I. Danilov and A. I. Pomogaibo, Dokl. Akad. Nauk SSSR 68:843, 1949.Google Scholar
  41. 41.
    F. K. Gorskii, Zh. Eksperim. i Teor. Fiz. 18:24, 1948.Google Scholar
  42. 42.
    L. M. Shcherbakov, Tr. Tul’sk. Mekhan. Inst. (7):117, 1955; (8): 173, 1958; L. M. Shcherbakov, Researches in the Field of Surface Forces, Collection of papers presented at a conference on surface forces, April 1960, IFKh Akad. Nauk SSSR, 1961, p. 28.Google Scholar
  43. 43.
    L. M. Shcherbakov, Kolloidn. Zh. 23:215, 1961.Google Scholar
  44. 44.
    B. V. Deryagin and E. Obukhov, Kolloidn. Zh. (1):385, 1935; B. V. Deryagin and M. M. Kusakov, Izv. Akad. Nauk SSSR, Ser. Khim. (5):741, 1936; (6):1119, 1937; B, V. Deryagin and Z. M, Zorin, Zh. Fiz. Khim. 20:1755, 1955.Google Scholar
  45. 45.
    E. A. Guggenheim, Modern Thermodynamics [Russian translation], Moscow, 1941, p. 44.Google Scholar
  46. 46.
    L. M. Shcherbakov and I. Rykov, Uch. Zap. Kishinevsk. Gos. Univ. (5): 131, 1952.Google Scholar
  47. 47.
    L. M. Shcherbakov and V. S. Baibakov, Surface Tension of Metals at the Interface with a Gas and Their Own Melt, this volume, p. 172.Google Scholar

Copyright information

© Consultants Bureau Enterprises, Inc. 1965

Authors and Affiliations

  • L. M. Shcherbakov
    • 1
  1. 1.Tul’sk Mechanical InstituteUSSR

Personalised recommendations