Abstract
Consider an array of interacting electric dipoles, for instance polar molecules such as HCl. Bilinear interactions between these dipoles may induce a dipolar ordering below a transition temperature T d: each dipole i then has a mean orientation along some direction +z i. Neglecting the possibility of non-collinearity and sub-lattice structure, suppose that the ordering is ferroelectric. The order parameter of the transition is the polarization <cosθ>, θ being the angle between a dipole and the polarization axis +z. Similarly, consider an array of interacting electric quadrupoles, for instance centro-symmetric linear molecules such as H 2, having no dipolar moment. Interactions between these quadrupoles may induce some kind of ordering below a transition temperature T q. In particular, if all quadrupoles are aligned by positive interactions, the ordering is called ferroquadrupolar. The order parameter is then the orientation <cos2θ - 1/3>, θ being the angle between the quadrupoles and the orientation axis z.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Krieger, T.J. and James, H.M. (1954). J. Chem. Phys., 22, 796.
Kobayashi, K.K., Hanamura, E. and Shishido, F. (1969). Phys. Lett., 28A, 454.
De Germes, P.G. (1969). Phys. Lett., 30A, 454.
Freiser, M.J. (1971). Mol. Liq. Cryst., 14, 165.
Bean, C.P. and Rodbell, D.S. (1962). Phys. Rev., 126, 104.
Allen, S.J. (1968). Phys. Rev., 166, 530; 167, 492.
Long, C. and Wang, Y.L. (1971). Phys. Rev., B3, 1656.
Moran, T.J., Thomas, R.L., Levy, P.M. and Chen, H.H. (1973). Phys. Rev., B7, 3238.
Elliott, R.J. and Thorpe, M.F. (1968). J. Appl. Phys., 39, 802.
Levy, P.M. (1964). Phys. Rev., 135, A155.
Khomski, D.I. and Kugel, K.I. (1972). JETP Lett., 15, 629.
Sivardière, J., Berker, A.N. and Wortis, M. (1973). Phys. Rev., B7, 343.
Sivardière, J. (1973). J. Phys. Chem. Solids, 34, 267.
Finch, G.I., Sinha, A.P.B. and Sinha, K.P. (1957). Pvoc. Roy. Soc., A242, 28.
Kino, Y., Lüthi, B. and Mullen, M.E. (1972). J. Phys. Soc. Jap., 33, 687.
Novak, P. (1970). J. Phys. Chem. Solids, 31, 125.
See: Sivardière, J. (1972). Phys. Rev., B6, 4284, and references therein.
Sivardière, J. (1973). Phys. Rev., B8, 2004.
Lüthi, B., Mullen, M.E., Andres, K., Bucher, E. and Maita, J.P. (1973). Phys. Rev., B8, 2639.
Harley, R.T., Hayes, W., Perry, A.M. and Smith, S.R.P. (1973). J. Phys., C6, 2382.
Felsteiner, J., Litvin, D.B. and Zak, J. (1971). Phys. Rev., B3, 2706.
Sivardière, J. (1972). Phys. Rev., B5, 2094.
See: Falk, H. (1970). Am. J. Phys., 38, 858.
Blume, M. and Hsieh, Y.Y. (1969). J. Appl. Phys., 40, 1249.
Chen, H.H. and Levy, P.M. (1971). Phys. Rev. Lett., 27, 1383.
Nauciel-Bloch, M., Sarma, G. and Castets, A. (1972). Phys. Rev., B5, 4603.
Sivardière, J. and Blume, M. (1972). Phys. Rev., B5, 1126.
Chen, H.H. and Levy, P.M. (1973). Phys. Rev., B7, 4267.
Elliott, R.J., Harley, R.T., Hayes, W. and Smith, S.R.P. (1972). Proc. Phys. Soc, A328, 217.
Kanamori, J. (1960). J. Appl. Phys., 31, 145.
Thomas, H. and Müller, K.A. (1972). Phys. Rev. Lett., 28, 820.
Sarfatt, J. and Stoneham, A.M. (1967). Proc. Phys. Soc., 91, 214.
See a similar calculation applied to DySb in: Ray, D.K. and Young, A.P. J. Phys., C, (to be published).
Wojtowicz, P.J. (1959). Phys. Rev., 116, 32.
See: Straley, J.P. and Fischer, M.E. (1973). J. Phys., A6, 1310.
Englman, R. and Halperin, B. (1970). Phys. Rev., B2, 75.
Trammel, G.T. (1963). Phys. Rev., 131, 932.
Pytte, E. and Stevens, K.W.H. (1971). Phys. Rev. Lett., 27, 862.
Becker, P.J. (private communication).
Novak, P. (1970). Czech. J. Phys., B20, 196.
Halperin, B. and Englman, R. (1970). Solid State Commun., 8, 1555.
Levy, P.M. (to be published); Sivardière, J. (to be published).
Kjems, J.K., Shirane, G., Birgeneau, R.J. and van Uitert, L.G. (1973). Phys. Rev. Lett., 31, 1300.
Blume, M., Emery, V.J. and Griffiths, R.B. (1971). Phys. Rev., A4, 1071.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1976 Plenum Press, New York
About this chapter
Cite this chapter
Sivardiere, J. (1976). Dipolar and Quadrupolar Ordering in Magnetic Crystals. In: Łopuszański, J.T., Pękalski, A., Przystawa, J. (eds) Magnetism in Metals and Metallic Compounds. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-0016-9_20
Download citation
DOI: https://doi.org/10.1007/978-1-4757-0016-9_20
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-0018-3
Online ISBN: 978-1-4757-0016-9
eBook Packages: Springer Book Archive