Abstract
The creep properties of the pure, polycrystalline refractory metals are reviewed and summarized. The creep behavior of all the pure metals is correlated in terms of their diffusivities and elastic moduli following the Sherby-type analysis. Experimental values of the activation energy and stress dependence of creep are also summarized for the pure metals, and the structural features of deformation and fracture are described. The general effects of alloying are delineated in terms of solid solution, dispersed phase, and strain hardening contributions to high temperature creep strength.
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W. Pollack, R. W. Buckman, R. T. Begley, K. C. Thomas and E. C. Bishop, “Development of High Strength Vanadium Alloys”, Final Report, AEC Contract AT(30–1) — 3487, Westinghouse Electric Corp., June, 1967
H. Bohm and M. Schirra, “Investigations of the Stress-Rupture and Creep Behavior of Binary and Ternary Vanadium Alloys”, J. Less Common Metals, 12, 1967, pp. 280–293
G. Brinson and B. B. Argent, “The Creep of Niobium”, J. Inst. of Metals, 91, 1962–63, pp. 293–298
J. D.W. Rawson and B. B. Argent, “The Effect of Oxygen and Carbon on the Creep Strength of Niobium”, J. Inst. of Metals, 95, 1967, pp. 212–216
W. V. Green, “High-Temperature Creep of Tantalum,” Trans AIME, October, 1965, pp. 1818–1825
R. L. Stephenson, “Creep-Rupture Properties of Unalloyed Tantalum, Ta-10%W and T-111 Alloys”, ORNL-TM-1994, December, 1967
C. S. Landau, H. T. Greenaway and A. R. Edwards, “Properties of Chromium and Chromium-Tungsten Alloys”, J. Inst. of Metals, 89, 1960–61, pp. 97–101
J. W. Pugh, “The Tensile and Stress-Rupture Properties of Chromium” Trans ASM, 50, 1958, pp. 1072–1080
J. B. Conway and P. N. Flagella (and others), Progress Reports on AEC Fuels and Materials Development Program, GE-NMPO, Cincinnati, Ohio, 1961–1967
W. V. Green, M. G Smith and D.M. Olson, “Short-Time Creep-Rupture Behavior of Molybdenum at High Temperatures”, Trans AIME, 215, 1959, pp. 1061–1066
H. Carvalhinhos and B. B. Argent, “The Creep of Molybdenum”, J. Inst, of Metals, 95, 1967, pp. 364–368
W. D. Klopp, W. R. Witzke and P. L. Raffo, “Effects of Grain Size on Tensile and Creep Properties of Arc-Melted and Electron-Beam-Melted Tungsten at 2250° to 4140°F”, Trans AIME, 233, 1966, pp. 1860–1866
W. V. Green, “Short-Time Creep-Rupture Behavior of Tungsten at 2250 to 2800°C,” Trans AIME, 215, 1959, pp. 1057–1060
E. R. Gilbert, J. E. Flinn and F. L. Yaggee, “Multimechanism Behavior in the Creep of Tungsten”, Paper Presented at the Fourth Symposium on Refractory Metals, French Lick, Indiana, October 3–5, 1965, to be published
H. E. McCoy, “Creep-Rupture Properties of W and W-Base Alloys,” ORNL-3992, August, 1966
J. H. Bechtold, E. T. Wessel and L. L. France, “Mechanical Behavior of the Refractory Metals”, Refractory Metals and Alloys, AIME Metall. Soc. Conferences, Volume 11, 1960, pp. 25–81
O. D. Sherby, “Factors Affecting the High Temperature Strength of Polycrys-talline Solids”, Acta Met, 10, 1962, pp. 135–147
P. E. Armstrong and H. L. Brown, “Dynamic Young’s Modulus Measurements Above 1000°C on Some Pure Polycrystalline Metals and Commercial Graphites”, Trans AIME, 230, 1964, pp. 962–966
P. E. Armstrong and H. L. Brown, “Anomalous Temperature Dependence of Elastic Moduli of Niobium Metal”, Trans ASM, 58, 1965, pp. 30–37
R. P. Agarwala, S. P. Murarka and M. S. Anand, “Diffusion of Vanadium in Niobium, Zirconium and Vanadium”, Acta Met, 16, 1968, pp. 61–67
T. S. Lundy, F. R. Winslow, R. E. Pawel and C.J. McHargue, “Diffusion of Nb-95 and Ta-182 in Niobium (Columbium)”, Trans AIME, 233, 1965, pp. 1533–1539
R. E. Pawel and T. S. Lundy, “The Diffusion of Nb95 and Ta182 in Tantalum”, J. Phys Chem Solids, 26, 1965, pp. 937–942
J. Askill, “Self-Diffusion in Chromium”, Diffusion in Body-Centered Cubic Metals, Chapter 18, ASM, Metals Park, Ohio, 1965
J. Askill and D.H. Tomlin, “Self-Diffusion in Molybdenum”, Phil Mag, 8, 1963, pp. 997–1001
R. L. Andelin, J. D. Knight and M. Kahn, “Diffusion of Tungsten and Rhenium Tracers in Tungsten”, Trans AIME, 233, 1965, pp. 19–24
O. D. Sherby and P. M. Burke, “Mechanical Behavior of Crystalline Solids at Elevated Temperature”, First Technical Report to NASA (SC-NGR-05–020–084) August 1, 1967
J. Stoop and P. Shahinian, “Effect of Oxygen on Creep-Rupture of Niobium”, High Temperature Refractory Metals, Part 2, AIME Metallurgical Society Conferences, Volume 34, 1966, pp. 407–432
D. P. Gregory and G. H. Rowe, “Mechanisms of Creep in Columbium and Columbium-1% Zirconium Alloy”, Columbium Metallurgy, AIME Metallurgical Society Conferences, Volume 10, 1960, pp. 309–341
J. E. Flinn and E. R. Gilbert, “Discussion of High Temperature Creep of Tantalum”, Trans AIME, 236, 1966, pp. 1512–1513
G. W. King and H. G. Sell, “The Effect of Thoria on the Elevated-Temperature Tensile Properties of Recrystallized High-Purity Tungsten”, Trans AIME, 233, 1965, pp. 1104–1113
J. W. Pugh, “Tensile and Creep Properties of Tungsten at Elevated Temperatures”, Proc ASTM, 57, 1957, pp. 906–915
C. R. Barrett and W. D. Nix, “A Model for Steady State Creep Based on the Motion of Jogged Screw Dislocations”, Acta Met, 13, 1965, pp. 1247–1258
W. F. Sheely, “Mechanical Properties of Niobium-Oxygen Alloys”, J. Less Common Metals, 4, 1962, pp. 487–495
F.F. Schmidt, W. D. Klopp, W.M. Albrecht, F. C. Holden, H. R. Ogden and R. I. Jaffee, “Investigation of the Properties of Tantalum and Its Alloys”, WADD Technical Report 59–13, March, 1960
H. E. McCoy and D. A. Douglas, “Effect of Various Gaseous Contaminants on the Strength and Formability of Columbium”, Columbium Metallurgy, AIME Metallurgical Society Conferences, Volume 10, 1960, pp. 85–118
R. W. Armstrong, J. H. Bechtold and R. T. Begley, “Mechanisms of Alloy Strengthening in Refractory Metals” Refractory Metals and Alloys II, AIME Metallurgical Society Conferences, Volume 17, 1963, pp. 159–190
W. H. Chang, “Strengthening of Refractory Metals”, Refractory Metals and Alloys, AIME Metallurgical Society Conferences, Volume 11, 1961, pp. 83–117
G. D. McAdam, “Substitutional Niobium Alloys of High Creep Strength”, J. Inst, of Metals, 93, 1964–65, pp. 559–564
E. S. Bartlett, D. N. Williams, H. R. Ogden, R. I. Jaffee and E. F. Bradley, “High-Temperature Solid-Solution-Strengthened Columbium Alloys”, Trans AIME, 227, 1963, pp. 459–467
C. S. Hartley, J. E. Steedly and L. D. Parson, “Binary Interdiffusion in Body-Centered Cubic Transition Metal Systems”, Diffusion in Body-Centered Cubic Metals, Chapter 4, ASM, Metals Park, Ohio, 1965
W. H. Chang, “Influence of Heat Treatment on Microstructure and Properties of Columbium-Base and Chromium-Base Alloys”, ASD-TDR-62–211, Part IV, March, 1966
R. F. Peart and D. H. Tomlin, “Diffusion of Solute Elements in Beta-Titanium”, Acta Met, 10, 1962, pp. 123–134
G. B. Gibbs, D. Graham and D. H. Tomlin, “Diffusion in Titanium and Titanium-Niobium Alloys”, Phil Mag, 8, 1963, pp. 1269–1282
V. P. Lubinov, P. V. Geld and G. P. Shveykin, Isv. Akad. Nauk SSSR, Met i Gorn, Delo 5, 137, 1964
P. V. Geld, Z. Ya. Velmozhnyi, V. D. Lubinov and G. P. Shveykin, Isv. Vysshikh Uchehn. Zavedenic Tsvetn, Met. 2, 135, 1966
R. W. Buckman, Jr. and R. C. Goods peed, “Considerations in the Development of Tantalum Base Alloys,” This Volume
E. S. Bartlett, F. F. Schmidt and H. R. Ogden, “Properties of Ta-W-Mo Alloys”, High Temperature Refractory Metals, Part 2, AIME Metallurgical Society Conferences, Volume 34, 1966, pp. 326–345
H. T. Greenaway, “Creep Testing of Chromium Alloys”, Report ARL/Met. 55, Aeronautical Research Laboratories, Melbourne, Australia, October, 1964
J. W. Clark and C. S. Wukusick, Preliminary Information Reported by General Electric Co., Evendale, Ohio, Under a NASA Contract (cited in Ref. 50, p. 12)
D. J. Maykuth and A. Gilbert, “Chromium and Chromium Alloys”, DMIC Report 234, October 1, 1966
M. Semchyshen, “Development and Properties of Arc-Cast Molybdenum-Base Alloys”, The Metal Molybdenum, (Edited by J.J. Harwood), Chapter 14, ASM, Cleveland, Ohio, 1958
P. L. Raffo, W. D. Klopp and W. R. Witzke, “Mechanical Properties of Arc-Melted and Electron-Beam-Melted Tungsten-Base Alloys”, NASA TN D-2561, January, 1965
W. D. Klopp, W. R. Witzke and P. L. Raffo, “Mechanical Properties of Dilute Tungsten-Rhenium Alloys”, NASA TN D-3483, September, 1966
P. L. Raffo and W. D. Klopp, “Mechanical Properties of Solid-Solution and Carbide-Strengthened Arc-Melted Tungsten Alloys”, NASA TN D-3248, February, 1966
L.L. Seigle, “Structural Considerations in Developing Refractory Metal Alloys”, The Science and Technology of Selected Refractory Metals, (Edited by N. E. Promisel) AGARD Conference on Refractory Metals held in Oslo, Norway, June 23–26, 1963, pp. 63–93
R. T. Begley and J. H. Bechtold, “Effect of Alloying on the Mechanical Properties of Niobium”, J. Less Common Metals, 3, 1961, pp. 1–12
R. T. Begley, J. A. Cornie and R. C. Goodspeed, “Development of Columbium Base Alloys”, AFML-TR-67–116, November, 1967
G. D. McAdam, “The Influence of Carbide and Boride Additions on the Creep Strength of Niobium Alloys”, J. Inst. of Metals, 96, 1968, pp. 13–16
N. E. Ryan, “The Formation, Stability and Influence of Carbide Dispersions in Chromium”, J. Less Common Metals, 11, 1966, pp. 221–248
L S. Rubenstein, “Effects of Composition and Heat Treatment on High-Temperature Strength of Arc-Melted Tungsten-Hafnium-Carbon Alloys, NASA TN D-4379, February, 1968
R. T. Begley, J. L. Godshall and R. Stickler, “Precipitation Hardening Columbium-Hafnium-Nitrogen Alloys”, Fifth Plansee Seminar, June 22–26, 1964, Reutte/Tyrol, pp. 401–420
A. K. Mukherjee and J. W. Martin, “The Effect of Nitriding upon the Creep Properties of Some Molybdenum Alloys”, J. Less Common Metals, 5, 1963, pp. 403–410
A. C. Barber and P. H. Morton, “A Study of the Niobium-Zirconium-Carbon and Niobium-Zirconium-Oxygen Systems”, High Temperature Refractory Metals, Part 2, AIME Metallurgical Society Conferences, Volume 34, 1966, pp. 391–406
D. O. Hobson, “Aging Phenomena in Columbium-Base Alloys”, High Temperature Materials II, AIME Metallurgical Society Conferences, Volume 18, 1963, pp. 325–334
J. R. Stewart, W. Lieberman and G. H. Rowe, “Recovery and Recrystallization of Columbium-1% Zirconium Alloy”, Columbium Metallurgy, AIME Metallurgical Society Conferences, Volume 10, 1960, pp. 407–434
R. T. Begley, R. L. Ammon and R. Stickler, “Development of Niobium Base Alloys”, WADC TR 57–344, Part VI, February, 1963
R. M. Bonesteel, J. L Lytton, D.J. Rowcliffe and T. E. Tietz, “Recovery and Internal Oxidation of Columbium and Columbium Alloys”, AFML-TR-66–253, August, 1966
R. W. Buckman, Jr., Unpublished Research on Studies of Internally Oxidized T-111 Alloy, Westinghouse Astronuclear Laboratory
R. W. Buckman, Jr., “Operation of Ultra High Vacuum Creep Testing Laboratory”, Transactions Vacuum Metallurgy Conference, 1966, American Vacuum Society, 1967, pp. 25–37
R. W. Buckman, Jr. and R. C. Goodspeed, Unpublished Research, Westinghouse Astronuclear Laboratory
R. H. Titran and R. W. Hall, “Ultrahigh-Vacuum Creep Behavior of Columbium and Tantalum Alloys at 2000° and 2200°F for Times Greater Than 1000 Hours”, NASA TN D-3222, January, 1966
TRW, Inc., “Generation of Long Time Creep Data on Refractory Alloys at Elevated Temperatures”, Final Report on Contract NAS 3–2545, June 6, 1967
R. A. Perkins, “Effect of Processing Variables on the Structure and Properties of Refractory Metals”, AFML-TR-65–234, Part II, May, 1967
R. T. Begley and J. A. Cornie, Unpublished Research, Westinghouse Astronuclear Laboratory
H. G. Sell, W. R. Morcom and G. W. King, “Development of Dispersion Strengthened Tungsten Base Alloys”, AFML-TR-65–407, Part II, November, 1966
R. T. Begley and J. L. Godshall, “Some Observations on the Role of Grain Boundaries in High Temperature Deformation and Fracture of Refractory Metals”, Paper Presented at the Fourth Symposium on Refractory Metals, French Lick, Indiana, October 3–5, 1965
E. Rudy and others, Aerojet-General Corporation, “Ternary Phase Equilibria in Transition MetaI-Boron-Carbon-SiIicon Systems”, AFML-TR-65–2, 1965–66
R. W. Buckman, Jr. and R. C. Goodspeed, “Development of Dispersion Strengthened Tantalum Base Alloy”, Sixth Quarterly Report on Contract NAS 3–2542, NAS CR-54658
R. N. Stevens, “Grain Boundary Sliding in Metals”, Metallurgical Reviews, 11, 1966, pp. 129–142
R. C. Gifkins, Fracture, (Edited by B. L. Averback, D. S. Felbeck, G. T. Hahn and D. A. Thomas), Technology Press and J. Wiley and Sons, New York, 1959
B. A. Wilcox, A. Gilbert and B. C. Allen, “Intermediate-Temperature Ductility and Strength of Tungsten and Molybdenum TZM”, AFML-TR-66–89, April, 1966
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© 1968 American Institute of Mining, Metallurgical, and Petrolium Engineers, Inc.
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Begley, R.T., Harrod, D.L., Gold, R.E. (1968). High Temperature Creep and Fracture Behavior of the Refractory Metals. In: Machlin, I., Begley, R.T., Weisert, E.D. (eds) Refractory Metal Alloys Metallurgy and Technology. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-9120-3_2
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DOI: https://doi.org/10.1007/978-1-4684-9120-3_2
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