Skip to main content

Recent Advances in Applications of the Microcoulometric Titrating System

  • Chapter
Lectures on Gas Chromatography 1966
  • 77 Accesses

Abstract

Since the introduction of microcoulometric gas chromatography in 1960, considerable effort has been expended in the development of new fields of use for this unique analytical system. The instrumentation was used originally as a gas chromatographic detector and applied to the area of pesticide residue analysis because of the system’s specific response to chlorinated and sulfur-containing organic compounds. In recent years, however, use of this versatile analyzer has been extended to include applications in the chemical, petroleum, natural gas, and steel industries. Current development effort has resulted in increasing the capability of the microcoulometric titrating system to include specific response to volatile nitrogen-containing compounds in addition to sulfur and halogen analysis. Continuing investigation indicates the possibility for specific carbon and phosphorus detection as well as selective response to certain classes of organic compounds.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Ronald L. Martin, “Selective Detection System for Nitrogen Compounds,” Seventeenth Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Pittsburgh, Pennsylvania, 1966.

    Google Scholar 

  2. P. J. Klaas, “Gas Chromatographic Determination of Sulfur Compounds in Naphthas Employing a Selective Detector,” Anal. Chem. 33:1851, 1961.

    Article  CAS  Google Scholar 

  3. R.L. Martin and J. A. Grant, “Determination of Sulfur-Compound Distributions in Petroleum Samples with Coulometric Detector,” Anal. Chem. 37:644, 1965.

    Article  CAS  Google Scholar 

  4. R.L. Martin and J.A. Grant, “Determination of Thiophenic Compounds by Types in Petroleum Samples,” Anal. Chem. 37:649, 1965.

    Article  CAS  Google Scholar 

  5. V.T. Brand and D.A. Keyworth, “A Rapid Determination of Individual Mer-captans in Gasoline Boiling Range Stocks,” Anal. Chem. 37:1424, 1965.

    Article  CAS  Google Scholar 

  6. B.H. Andreen and D.V. Kniebes, “Determination of Sulfur Compounds in Natural Gas by Chromatography,” Paper CEP-62–13, American Gas Association Conference, Baltimore, Md., 1962.

    Google Scholar 

  7. E.M. Fredericks and G.A. Harlow, “Determination of Mercaptans in Sour Natural Gases by Gas Liquid Chromatography and Microcoulometric Titration,” Anal. Chem. 36:263, 1964.

    Article  CAS  Google Scholar 

  8. F. V. Wilby, “Determination of Sulfur Compounds in Natural Gas by Gas-Liquid Chromatography Using Low Temperature Sample Concentration, Temperature Programming, and Microcoulometric Detector,” American Gas Association Production Conference, Buffalo, New York, 1965.

    Google Scholar 

  9. R.A. Hofstader, “Microdetermination of Trace Quantities of Organic Chloride by Combustion and Microcoulometry —Application to Low Boiling Liquid,” Pennsylvania State Microchemical Symposium, State College, Pennsylvania, 1965.

    Google Scholar 

  10. W.R. Bandi, E.G. Buyok, and W.A. Straub, “The Determination of Trace Amounts of Sulfur in Iron and Steel,” Seventeenth Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Pittsburgh, Pennsylvania, 1966.

    Google Scholar 

  11. W. Swartz and W.A. Straub, “Qualitative and Quantitative Study of Individual Metal Sulfides in Steels by a Combustion-Microcoulometric Method,” Seventeenth Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Pittsburgh, Pennsylvania, 1966.

    Google Scholar 

  12. H.P. Burchfield, D.E. Johnson, J.W. Rhoades, and R.J. Wheeler, “Selective Detection of Phosphorus, Sulfur, and Halogen Compounds in the Gas Chromatography of Drugs and Pesticides,” J. Gas Chromatog. 3:28, 1965.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1967 Plenum Press

About this chapter

Cite this chapter

Stamm, J.A. (1967). Recent Advances in Applications of the Microcoulometric Titrating System. In: Mattick, L.R., Szymanski, H.A. (eds) Lectures on Gas Chromatography 1966. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-9102-9_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-9102-9_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-9104-3

  • Online ISBN: 978-1-4684-9102-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics