Abstract
Since the introduction of microcoulometric gas chromatography in 1960, considerable effort has been expended in the development of new fields of use for this unique analytical system. The instrumentation was used originally as a gas chromatographic detector and applied to the area of pesticide residue analysis because of the system’s specific response to chlorinated and sulfur-containing organic compounds. In recent years, however, use of this versatile analyzer has been extended to include applications in the chemical, petroleum, natural gas, and steel industries. Current development effort has resulted in increasing the capability of the microcoulometric titrating system to include specific response to volatile nitrogen-containing compounds in addition to sulfur and halogen analysis. Continuing investigation indicates the possibility for specific carbon and phosphorus detection as well as selective response to certain classes of organic compounds.
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References
Ronald L. Martin, “Selective Detection System for Nitrogen Compounds,” Seventeenth Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Pittsburgh, Pennsylvania, 1966.
P. J. Klaas, “Gas Chromatographic Determination of Sulfur Compounds in Naphthas Employing a Selective Detector,” Anal. Chem. 33:1851, 1961.
R.L. Martin and J. A. Grant, “Determination of Sulfur-Compound Distributions in Petroleum Samples with Coulometric Detector,” Anal. Chem. 37:644, 1965.
R.L. Martin and J.A. Grant, “Determination of Thiophenic Compounds by Types in Petroleum Samples,” Anal. Chem. 37:649, 1965.
V.T. Brand and D.A. Keyworth, “A Rapid Determination of Individual Mer-captans in Gasoline Boiling Range Stocks,” Anal. Chem. 37:1424, 1965.
B.H. Andreen and D.V. Kniebes, “Determination of Sulfur Compounds in Natural Gas by Chromatography,” Paper CEP-62–13, American Gas Association Conference, Baltimore, Md., 1962.
E.M. Fredericks and G.A. Harlow, “Determination of Mercaptans in Sour Natural Gases by Gas Liquid Chromatography and Microcoulometric Titration,” Anal. Chem. 36:263, 1964.
F. V. Wilby, “Determination of Sulfur Compounds in Natural Gas by Gas-Liquid Chromatography Using Low Temperature Sample Concentration, Temperature Programming, and Microcoulometric Detector,” American Gas Association Production Conference, Buffalo, New York, 1965.
R.A. Hofstader, “Microdetermination of Trace Quantities of Organic Chloride by Combustion and Microcoulometry —Application to Low Boiling Liquid,” Pennsylvania State Microchemical Symposium, State College, Pennsylvania, 1965.
W.R. Bandi, E.G. Buyok, and W.A. Straub, “The Determination of Trace Amounts of Sulfur in Iron and Steel,” Seventeenth Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Pittsburgh, Pennsylvania, 1966.
W. Swartz and W.A. Straub, “Qualitative and Quantitative Study of Individual Metal Sulfides in Steels by a Combustion-Microcoulometric Method,” Seventeenth Pittsburgh Conference on Analytical Chemistry and Applied Spectroscopy, Pittsburgh, Pennsylvania, 1966.
H.P. Burchfield, D.E. Johnson, J.W. Rhoades, and R.J. Wheeler, “Selective Detection of Phosphorus, Sulfur, and Halogen Compounds in the Gas Chromatography of Drugs and Pesticides,” J. Gas Chromatog. 3:28, 1965.
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© 1967 Plenum Press
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Stamm, J.A. (1967). Recent Advances in Applications of the Microcoulometric Titrating System. In: Mattick, L.R., Szymanski, H.A. (eds) Lectures on Gas Chromatography 1966. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-9102-9_4
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DOI: https://doi.org/10.1007/978-1-4684-9102-9_4
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-9104-3
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