Abstract
Although the Kroll process for refining titanium was invented in 1937, significant production in the U.S. did not begin until 1948. It was the advent of the aircraft jet engine that stimulated growth of the titanium industry, primarily because of titanium’s excellent strength-to-weight ratio. A wide variety of alloy compositions evolved for various aircraft applications, not only for engines, but for airframe structures as well.1 As the demand for these applications ebbed and flowed in the years following 1948, the industry began to cultivate other areas for use. The corrosion resistance of Ti made it a viable replacement for stainless steels in many applications in the chemical processing industry.2 More recently, Ti has been used in various types of prostheses for surgical implant in humans.3
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Jaffee, R. I., and Promisel, N. E., eds. The Science, Technology and Application of Titanium. New York: Pergamon Press, Ltd., 1970.
Inomata, S.; Goto, A.; Yano, K.; Tsuchimoto, M.; Shibata, S.; Fujii, T.; Sakurai, T.; and Kanamoto, M. On the explosive bonding and forming of titanium. *Jaffee, R. I., and Promisel, N. E., eds. The Science, Technology and Application of Titanium. New York: Pergamon Press, Ltd., 1970*Ibid., pp. 1065–1080.
Zwicker, U.; Buhler, K.; Muller, R.; Beck, H.; Schmid, H. J; and Ferstl, J. Mechanical properties and tissue reactions of a titanium alloy for implant material. In Titanium ′80 Science and Technology, edited by Kimura, H., and Izumi, O., pp. 505–518. Warrendale, PA: Met. Soc. AIME, 1980.
Ogden, H. R., and Holden, F. C. Metallography of titanium alloys. TML Report No. 103. Columbus OH: Battelle Memorial Inst., 1958.
Frost, P. D.; Parris, W. M.; Hirsch, L. L.; Doig, J. R.; and Schwartz, C. M. Isothermal transformation of titanium-chromium alloys. Trans. ASM 46:231–256 (1954).
Holden, F. C., and Young, A. D. Electron micrographic study of aging in a beta titanium alloy. Trans. Met. Soc. AIME 212:287–288 (1958).
Fentiman, W. P.; Goosey, R. E.; Hubbard, R. T. J.; and Smith, M. D. Exploitation of a simple alpha titanium alloy base in the development of alloys of diverse mechanical properties. In The Science, Technology and Application of Titanium, edited by Jaffee, R. I., and Promisel, N. E., pp. 987–999. New York: Pergamon Press, Ltd., 1970.
Zwicker, U., and Katsch, E. Cracking of titanium alloys under stress during oxidation in air. *The Science, Technology and Application of Titanium, edited by Jaffee, R. I., and Promisel, N. E., pp. New York: Pergamon Press, Ltd., 1970*Ibid., pp. 299–306.
Coyne, J. R. The beta forging of titanium alloys. *The Science, Technology and Application of Titanium, edited by Jaffee, R. I., and Promisel, N. E., pp. New York: Pergamon Press, Ltd., 1970*Ibid., pp. 97–110.
Green, T. E., and Minton, C. D. T. The effect of beta processing on properties of titanium alloys. *The Science, Technology and Application of Titanium, edited by Jaffee, R. I., and Promisel, N. E., pp. New York: Pergamon Press, Ltd., 1970*Ibid., pp. 111–119.
Frederick, S. F., and Hanna, W. D. Fracture toughness and deformation of titanium alloys at low temperatures. Met. Trans. 1:347–352 (1970).
Kennedy, J. Fatigue behavior of solution treated and quenched Ti-6A1–4V. Grumman Res. Dept. Report RE-630. 1981.
Lee, D., and Backofen, W. A. Superplasticity in some titanium and zirconium alloys. Trans. TMS-AIME 239:1034–4040 (1967).
Hall, I. W., and Hammond, C. The relationship between crack propagation characteristics and fracture toughness in alpha+beta alloys, In Titanium Science and Technology, edited by Jaffee, R. I. and Burte, H. M., pp. 1365–1376. New York: Plenum Press, 1973.
Thompson, A. W.; Williams, J. C.; Frandsen, J. D.; and Chesnutt, J. C. The effect of microstructure on fatigue crack propagation rate in Ti-6A1–4V. In Titanium and Titanium Alloys, edited by Williams, J. C., and Belov, A. F., pp. 691–704, New York; Plenum Press, 1982.
Spurling, R. A. Rockwell International Science Center, Thousand Oaks, CA. Unpublished research.
Cortes, F. R. Electrolytic polishing of refractory metals. Metals Progress 88:97–100 (1961).
Rice, L.; Hinesley, C. P.; and Conrad, H. Techniques for optical and electron microscopy of titanium. Metallog. 4:257–268 (1971).
Blackburn, M. J.; and Williams, J. C. The preparation of thin foils of titanium alloys. Trans. TMS-AIME 239:287–288 (1967).
Spurling, R. A. A technique for preparing thin foils of Ti and Ti alloys for transmission electron microscopy. Met. Trans. 6A:1660–1661 (1975).
Spurling, R. A.; Rhodes, C. G.; and Williams, J. C. The microstructure of Ti alloys as influenced by thin foil artifacts. Met. Trans. 5:2597–2600 (1974).
Rhodes, C. G., and Paton, N. E. Formation characteristics of the alpha/beta interface phase in Ti-6A1–4V. Met. Trans. A 10A:209–216 (1979).
Banerjee, D., and Williams, J. C. The effect of foil preparation technique on interface phase formation in Ti alloys. Scr. Met. 17:1125–1128 (1983).
Burgers, W. G. On the process of transition of the cubic-body-centered modification into the hexagonal-close-packed modification of zirconium. Physica 1:561–586 (1934).
Jaffee, R. I. Metallurgical synthesis. In Titanium Science and Technology, edited by Jaffee, R. I., and Burte, H. M., pp. 1665–1693. New York: Plenum Press, 1973.
Williams, J. C., and Belov, A. F., eds. Titanium and Titanium Alloys. New York: Plenum Press, 1982.
Kimura, H., and Izumi, O., eds. Titanium ′80 Science and Technology. Warrendale, PA: Metallurgical Society of AIME, 1980.
Rosenberg, H. W. Titanium alloying in theory and practice. In The Science, Technology and Applications of Titanium, edited by Jaffee, R. I., and Promisel, N. E., pp. 851–859. New York; Pergammon Press, Ltd., 1970.
Bohanek, E., and Kessler, H. D. An advanced titanium alloy for service at temperatures in excess of 800°F. In Reactive Metals, vol. 2, edited by Clough, W. R., pp. 23–41. NY: Interscience Publishers, (1959).
Blackburn, M. J. Relationship of microstructure to some mechanical properties of Ti-8Al-1Mo-1V. Trans. ASM 59:694–708 (1966).
Brown, B. F. ASTM Annual Meeting, *J. Electr. Soc. 114:551–556 (1967)*cited in Ref. 32.
Beck, T. R. Stress corrosion cracking of titanium alloys. J. Electr. Soc. 114:551–556 (1967).
Jackson, J. D., and Boyd, W. K. Stress corrosion cracking in titanium and titanium alloys. In The Science, Technology and Application of Titanium, edited by Jaffee, R. L, and Promisel, N. E., pp. 267–281. New York: Pergamon Press, Ltd., 1970.
Erdeman, V. J., and Ross, E. W. Long time stability of Ti-679 after creep exposure for times to 15,000 hour. Ibid., pp. *The Science, Technology and Application of Titanium, edited by Jaffee, R. L, and Promisel, N. E., pp. New York: Pergamon Press, Ltd., 1970*829–837.
Rosenberg, H. W. High temperature alloys. In Titanium Science and Technology, edited by Jaffee, R. I., and Burte, H. M., pp. 2127–2140. New York: Plenum Press, 1973.
Paton, N. E., and Mahoney, M. W. Creep of titanium-silicon alloys. Met. Trans. A 7A:1685–1694 (1976).
Neil, D. F. and Blenkinsop, P. A. Effect of heat treatment on structure and properties of IMI829. In Titanium ′80 Science and Technology, edited by Kimura, A., and Izumi, O., pp. 1287–1297. Warrendale, PA: Metallurgical Society of AIME, 1980.
Blenkinsop, P. A. IMI Titanium Limited, Birmingham, England. Private communication.
Rhodes, C. G.; Paton N. E.; and Mahoney, M. W. Creep properties of Ti-8Al-5Nb-5Zr-0.25Si. In Titanium Science and Technology, edited by Liitjering, G.; Zwicker, U.; and Bunk, W., pp. 2355–2361. Oberursel, W. Germany: Deutsche Gesellschaft für Metallkunde V., 1985.
Klier, E. P., and Feola, N. J. Notch tensile properties of selected titanium alloys. Trans. TMS-AIME 209:1271–1277 (1957).
Ogden, H. R.; Douglass, R. W.; Holden, F. C.; and Jaffee, R. I. The notch sensitivity of Ti-5Al-2.5Sn, Ti-6A1–4V and Ti-2Fe-2Cr-2Mo titanium alloys. Trans. Met. Soc. AIME 221:1235–1240 (1961).
Becker, D. W.; Messler, R. W. Jr.; and Baeslack, W. A., III. Titanium welding. In Titanium ′80 Science and Technology, edited by Kimura, A., and Izumi, O., pp. 255–275. Warrendale, PA: Metallurgical Society of AIME, 1980.
Craighead, C. M.; Simmon, O. W.; and Eastwood, L. W. Ternary alloys of titanium. Trans. AIME 188:514–538 (1950).
Berryman, R. G.; Froes, F. H.; Chesnutt, J. C.; Rhodes, C. G.; Williams, J. C.; and Malone, R. F. High toughness titanium alloy development. Technical Report TFD-74–657, Naval Air Systems Command, Washington, D.C., 1974.
Williams, J. C.; Froes, F. H.; Chesnutt, J. C.; Rhodes, C. G.; and Berryman, R. G. Development of high-fracture toughness titanium alloy. In Toughness and Fracture Behavior of Titanium, STP 651, pp. 64–114. Philadelphia: Am. Soc. for Testing and Materials, 1978.
Chesnutt, J. C.; Rhodes, C. G.; and Williams, J. C. Relationship between mechanical properties, microstructure and fracture topography in alpha+beta titanium alloys. In Fractography—Microscopic Cracking Processes, ASTM STP 600, pp. 99–138. Philadelphia: Am. Soc. for Testing and Materials, 1976.
Hamilton, C. H.; Stacher, G. W.; Mills, J. A.; and Li, H. Superplastic forming of titanium structures. AFML-TR-76–62, Wright-Patterson AFB, OH, April 1976.
Edington, J. W. Physical metallurgy of superplasticity. Met. Tech. 3:138–151 (1976).
Wert, J. A., and Paton, N. E. Enhanced superplasticity and strength in modified Ti-6A1–4V alloys. Met. Trans. 14A:2535–2544 (1983).
Hammond, C. Superplasticity in titanium base alloys. In Superplastic Forming of Structural Alloys, edited by Paton, N. E., and Hamilton, C. H., pp. 131–145. Warrendale, PA: TMS-AIME, 1982.
Blackburn, M. J.; and Smyri, W. H. Stress corrosion and hydrogen embrittlement. In Titanium Science and Technology, edited by Jaffee, R. I., and Burte, H. M., pp. 2577–2609. New York: Plenum Press, 1973.
Kerr, W. R.; Smith, P. R.; Rosenblum, M. E.; Gurney, F. J.; Mahajan, Y. R.; and Bidwell, L. R. Hydrogen as an alloying element in titanium (Hydrovac). In Titanium ′80 Science and Technology, edited by Kimura, A., and Izumi, O., pp. 2477–2846. Warrendale, PA: Metallurgical Society of AIME, 1980.
Molinier, R.; Moulin, J.; and Syre, R. A. A study of the metallurgical characteristics of Ti-6Al-6V-2Sn alloy. In The Science, Technology and Application of Titanium, edited by Jaffee, R. I., and Promisel, N. E., pp. 979–982. New York: Pergamon Press, Ltd., 1970.
McLean, D. Mechanical Properties of Metals: New York: John Wiley & Sons, Inc., 1962.
Petersen, V. C.; Bomberger, H. B.; and Vordahl, M. B. An age hardening titanium alloy. Metal Progress 76:119–122 (1959).
Hunter, D. B.; and Arnold, S. V. Metallurgical characteristics and structural properties of Ti-8Mo-8V-2Fe-3Al sheet, plate and forgings. In The Science, Technology and Application of Titanium, edited by Jaffee, R. I., and Promisel, N. E., pp. 959–967. New York: Pergamon Press, Ltd., 1970.
Bohanek, E. Deep hardenable titanium alloys for large airframe elements. In Titanium Science and Technology, edited by Jaffee, R. L, and Burte, H. M., pp. 1993–2007. New York: Plenum Press, 1973.
Petersen, V. C.; Froes, F. H.; and Malone, R. F. Metallurgical characteristics and mechanical properties of Beta III, a heat treatable titanium alloy. *Titanium Science and Technology, edited by Jaffee, R. L, and Burte, H. M., pp. New York: Plenum Press, 1973*Ibid., pp. 1969–1980.
Williams, J. C., and Rhodes, C. G. Rockwell International Science Center, Thousand Oaks, CA. Unpublished research.
Williams, J. C.; Froes, F. H.; and Yolton, C. F. Some observations on the structure of Ti-11.5Mo-6Zr-4.5Sn (Beta III). Met. Trans. 11A:356–358 (1980).
Hagemeyer, J. W., and Gordon, D. E. Properties of two beta titanium alloys after aging at several different temperatures. In The Science, Technology and Application of Titanium, edited by Jaffee, R. I., and Promisel, N. E., pp. 1957–1968. New York: Pergamon Press, Ltd., 1973.
Rhodes, C. G., and Paton, N. E. The influence of microstructure on mechanical properties in Ti-3Al-8V-6Cr-4Mo-4Zr (Beta C). Met. Trans. 8A:1749–1861 (1977).
Chen, C. C.; Hall, J. A.; and Boyer, R. R. High strength beta titanium alloy forgings for aircraft structural applications. In Titanium ′80 Science and Technology, edited by Kimura, A., and Izumi, O., pp. 459–466. Warrendale, PA: Metallurgical Society of AIME, 1980.
Hicks, A. G.; Nelson, G. W.; and Rosenberg, H. W. Beta titanium foil. J. Met. 34 (12):A35 (1982).
Rosenberg, H. W. Ti-15–3: A new cold-formable sheet titanium alloy. J. Met. 35 (11):30–34 (1983).
Author information
Authors and Affiliations
Editor information
Rights and permissions
Copyright information
© 1986 Van Nostrand Reinhold Company Inc.
About this chapter
Cite this chapter
Rhodes, C.G. (1986). Microscopy and Titanium Alloy Development. In: Vander Voort, G.F. (eds) Applied Metallography. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-9084-8_14
Download citation
DOI: https://doi.org/10.1007/978-1-4684-9084-8_14
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-9086-2
Online ISBN: 978-1-4684-9084-8
eBook Packages: Springer Book Archive