Abstract
Mössbauer spectroscopy, used in conjunction with the other spectroscopic methods which are normally employed in structure elucidation, such as infrared, nuclear magnetic resonance (NMR), and x-ray diffraction techniques, provides a powerful tool for the study of organometallic compounds incorporating the nuclides which are suitable for such studies. Fortunately, the two elements which are most readily accessible for Mössbauer work by chemists—iron and tin—have a very extensive and varied organometallic chemistry and are representative in many ways of transition metals and nontransition metals, respectively. In the present chapter, some of the broad outlines of Mössbauer studies on organometallic compounds of iron and tin will be summarized, and some examples from the recent literature will be reviewed. However, this discussion is intended to be neither encyclopedic nor exhaustive, and the interested reader is referred to some of the reviews on this topic which have appeared in the literature [1,2].
Keywords
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
E. Fluck, in Chemical Applications of Mössbauer Spectroscopy, V. I. Gol’danskii and R. H. Herber, Eds. (Academic Press, New York, 1968), Chap. 4.
V. I. Gol’danskii, V. V. Khrapov, O. Yu. Okhlobystin, and V. Ya. Rochev, in Chemical Applications of Mössbauer Spectroscopy, (Academic Press, New York, 1968), Chap. 6.
See also J. J. Zuckerman, Adv. Organomet, Chem. Vol 9, (Academic Press, New York, 1970).
R. H. Herber, R. B. King, and G. K. Wertheim, Inorg. Chem, 3, 101 (1964).
R. H. Herber and R. G. Hayter, J. Am. Chem. Soc. 86, 301 (1964).
R. R. Berrett and B. W. Fitzsimmons, Chem. Commun. 1966, 91.
V. I. Gordanskii et al, Dokl. Akad. Nauk. SSSR 147, 127 (1962).
R. H. Herber, H. A. Stöckler, and W. T. Reichle, Chem. Phys. 42, 2447 (1965).
H. A. Stöckler, H. Sano, and R. H. Herber, J. Chem. Phys. 45, 1182 (1966); 46, 2020 (1967).
R. H. Herber and G. I. Parisi, Inorg. Chem. 5, 769 (1966); R. H. Herber and Y. Goscinny (unpublished observations).
C. B. Harris, Inorg. Chem. 7, 1517 (1968).
R. L. Collins, J. Chem, Phys. 42, 1072 (1965).
S. L. Ruby and P. A. Flinn, Rev. Mod. Phys. 36, 351 (1964).
G. K. Wertheim and R. H. Herber, Chem. Phys. 38, 2106 (1963);
U. Zahn, P. Kienle, and H. Eicher, Proceedings of the Second International Conference on the Mössbauer Effect, D. M. J. Compton and A. H. Schoen, Eds. (John Wiley and Sons, New York, 1962), p. 271; Z. Physik. 166, 220 (1962).
M. F. Hawthorne, D. C. Young, and P. A. Wegner, J. Am. Chem. Soc. 87, 1818 (1965);
M. F. Hawthorne and T. D. Andrews, ibid., 87, 2496 (1965);
M. F. Hawthorne and R. L. Pilling, ibid., 87, 3987 (1965).
A. Zalkin, D. H. Templeton, and T. E. Hopkins, J. Am. Chem. Soc. 87, 3988 (1965).
R. H. Herber, Inorg. Chem. 8, 174 (1969).
R. H. Herber, Intern. At. Energy Agency, Tech. Rept. Ser. 50, 121 (1966).
T. C. Gibb and N. N. Greenwood, Intern. At. Energy Agency, Tech. Rept. Ser. 50, 163 (1966).
N. N. Greenwood, P. G. Perkins, and D. H. Wall, Symp. Faraday Soc. No. 1, 51 (1967).
H. A. Bent, J. Inorg. Nucl. Chem. 19, 43 (1961); Chem. Rev. 61, 275 (1961).
M. Cordey-Hayes, J. Inorg. Nucl. Chem. 26, 2307 (1964).
A. Yu. Aleksandrov et al, Dokl. Akad. Nauk SSSR 165, 593 (1965).
See discussion by V. I. Gol’danskii et al. [2], p. 343.
V. V. Khrapov, Ph.D. Thesis, Inst. Chem. Phys. Akad. Sci., USSR, Moscow, 1965.
B. Gassenheimer and R. H. Herber, Inorg. Chem. 8, 1120 (1969).
T. C. Gibb and N. N. Greenwood, J. Chem. Soc. 1966, 43.
N. N. Greenwood and J. N. R. Ruddick, Chem. Soc. A 1967, 1979.
T. A. Manuel and F. G. A. Stone, Proc. Chem. Soc. 1959, 90; J. Am. Chem. Soc. 82, 336 (1960).
M. D. Rausch and G. N. Schrautzer, Chem. Ind. (London) 957 (1959).
A. Nakamura and N. Hagihara, Bull. Chem. Soc. Japan 32, 880 (1959).
F. A. Cotton, J. Chem. Soc. 1960, 400.
B. Dickens and W. N. Lipscomb, J. Am. Chem. Soc. 83, 489 (1961).
C. G. Kreiter et al., J. Am. Chem. Soc. 88, 3444 (1966).
F. A. Cotton, A. Davidson, and J. W. Faller, J. Am. Chem. Soc. 88, 4507 (1966).
C. E. Keller, B. A. Shoulders, and R. Pettit, J. Am. Chem. Soc. 88, 4760 (1966).
R. Grubbs, R. Breslow, R. H. Herber, and S. J. Lippard, J. Am. Chem. Soc. 89, 6864 (1967).
F. Bonati and G. Wilkinson, J. Chem. Soc. 1964, 79.
R. H. Herber, Symp. Faraday Soc. No. 1, 86 (1967).
J. E. O’Connor and E. R. Corey, Inorg. Chem. 6, 969 (1967).
R. H. Herber and Y. Goscinny, Inorg. Chem. 7, 1293 (1968).
M. A. Bush and P. Woodward, J. Chem. Soc. A 1967, 1833.
W. Jetz and W. A. Graham, J. Am. Chem. Soc. 89, 2773 (1967).
W. Jetz, P. Simons, J. Thompson, and W. A. G. Graham, Inorg. Chem. 5, 2217 (1966).
H. R. H. Patil and W. A. G. Graham, Inorg. Chem. 5, 1401 (1966).
R. H. Herber and H. -S. Cheng, Inorg. Chem. 8, 2145 (1969).
H. -S. Cheng and R. H. Herber, Inorg. Chem. 9, 1686 (1970).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1971 Plenum Press, New York
About this chapter
Cite this chapter
Herber, R.H. (1971). Application to Organometallic Compounds. In: May, L. (eds) An Introduction to Mössbauer Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8911-8_7
Download citation
DOI: https://doi.org/10.1007/978-1-4684-8911-8_7
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-8913-2
Online ISBN: 978-1-4684-8911-8
eBook Packages: Springer Book Archive