Preparation and Properties of Pillared Synthetic Boron-Containing Saponite

  • Yi-Zhao Yao
  • Wen-Yang Xu
  • Xian-Mei Xie
  • Xian-Rong Li


A novel synthetic boron-containing saponite was prepared hydrothermally at 260°C under autogenous pressure in the system of Na2O-SiO2 -Al2 O3-B2O3 — MgO. The alumina-pillared synthetic boron-containing saponite [designated as Al-PSBCS(X), X is the added boron moles that are based on Mg=6 moles in the preparation] possessed both higher cumene dealkylation activity [93.4 wt.%] and better benzene selectivity [74.0 wt.%] than alumina-pillared non-boron clay Al-PSBCS(0) [ 73.5 wt.%, 70.0 wt.%, respectively]. Chemical analysis results showed that boron was incorporated into the pillared product. The dehydroxylation endotherm of structural OH of Al-PSBCS(3.0) [807°C] occurred at higher temperature than that of Al-PSBCS(0) [795°C].


Strong Acid Site Microporous Material Pillared Clay Bronsted Acid Site Chemical Analysis Result 
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Copyright information

© Springer Science+Business Media New York 1992

Authors and Affiliations

  • Yi-Zhao Yao
    • 1
  • Wen-Yang Xu
    • 1
  • Xian-Mei Xie
    • 1
  • Xian-Rong Li
    • 1
  1. 1.Research Institute of Specialty ChemicalsTaiyuan University of TechnologyTaiyuanP. R. China

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