Direct Synthesis of Novel Intercalated Layer Silicates of the Metal Silicate Type

  • W. Schwieger
  • D. Freude
  • P. Werner
  • D. Heidemann


A family of new layered silicates has been synthesized in the quarternary system Na2O/SiO2/H2O/polymeric organic cation. The polymeric organic cation (poly-{dimethyl-diallyl-ammonium chloride}) was intercalated into the silicate during the crystallization. Composition, structure, and the x-ray diffraction patterns of the new silicate do not fit any known layered silicate. The new silicate differs from the former ones by having a higher structural stability. A schematic representation of the sheet structure is given. Furthermore, the crystallization has been studied and characterized by means of physical and chemical methods depending on the types and the amounts of the polymeric cation and the addition of alumina.


Basal Spacing Layer Silicate Direct Synthesis Polymeric Cation High Resolution Electron Microscopy 
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Copyright information

© Springer Science+Business Media New York 1992

Authors and Affiliations

  • W. Schwieger
    • 1
  • D. Freude
    • 2
  • P. Werner
    • 1
  • D. Heidemann
    • 3
  1. 1.Martin-Luther-Universität Halle-WittenbergGermany
  2. 2.Universität LeipzigGermany
  3. 3.Institut fur anorganische ChemieBerlinGermany

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