Abstract
The dynamics of gas-surface processes is one of the fastest developing areas within surface science. After the initial thrust to understand electronic, vibrational, and structural properties of clean and adsorbate covered surfaces, it is obvious that the next logical step is to understand the details of kinetic and dynamic phenomena. Following from the expertise developed in gas-phase studies (both experimental and theoretical), it is now possible to address a diverse range of fundamental problems which have considerable technological interest. The application of molecular beam scattering and laser diagnostic and pumping techniques to study the interaction of atoms and small molecules with well-characterized metal surfaces promises to revolutionize our understanding of the detailed dynamics involved in gas-surface interactions. For example, it is now possible to measure directly the vibrational and translational energy dependence of dissociative chemisorption at metal surfaces(1) and probe the internal energy distributions of scattered(2) or desorbed molecules.(3)
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References
C. T. Rettner, H. E. Pfnür, and D. J. Auerbach, J. Chem. Phys. 84, 4163 (1985).
A. W. Kleyn, A. C. Luntz, and D. J. Auerbach, Surf. Sci. 117, 33 (1982).
G. D. Kubiak, G. O. Sitz, and R. N. Zare, J. Chem. Phys. 81, 6397 (1984).
J. A. Barker and D. J. Auerbach, Surf. Sci. Rep. 4, 1 (1985);
D. S. King and R. R. Cavanagh, in: New Laser and Optical Investigations of Chemistry and Structure at Interfaces, Verlag Chemie, Berlin (1985);
M. C. Lin and G. Ertl, Annu. Rev. Phys. Chem. 37, 587 (1986).
J. E. Lennard-Jones, Trans. Faraday Soc. 28, 333 (1932).
J. C. Tully, in: Dynamics of Molecular Collisions (W. H. Miller, ed.), Plenum Press, New York (1976).
N. D. Lang, in: Theory of the Inhomogeneous Electron Gas (S. Lundqvist and N. H. March, eds.), Plenum Press, New York (1983).
T. F. O’Malley, Adv. At. Mol. Phys. 7, 223 (1971).
J. W. Gadzuk, Comments At. Mol. Phys. 16, 219 (1985).
J. von Neumann and E. P. Wigner, Phys. Z. 30, 467 (1929).
E. E. Nikitin, Chemische Elementarprozeße (H. Hartman, ed.), Springer-Verlag, Berlin (1968).
F. T. Smith, Phys. Rev. 179, 111 (1969).
B. Kasemo and L. Walldén Surf. Sci. 53, 393 (1975);
J. K. N0rskov, D. M. Newns, and B. I. Lundqvist, Surf. Sci. 80, 179 (1979).
P. Pechukas, in: Dynamics of Molecular Collisions (W. H. Miller, ed.), Plenum Press, New York (1976).
E. K. Grimmelmann, J. C. Tully, and E. Helfand, J. Chem. Phys. 74, 5300 (1981).
J. C. Keck, Adv. Chem. Phys. 13, 85 (1967).
S. Holloway and J. L. Beeby,J. Phys. C 9, 1907 (1976).
O. Beek, A. E. Smith, and A. Wheeler, Proc. R. Soc. London, Scr. A 177, 62 (1940).
A. F. H. Ward, Proc. R. Soc. London, Scr. A 133, 506 (1931).
D. D. Eley and D. R. Rossington, in: Chemisorption (W. Garner, ed.), Butterworths, London (1957).
C. S. Alexander and J. Prichard, J. Chem. Soc., Faraday Trans. 68, 202 (1972).
W. Van Willigen, Phys. Lett. 28A, 80 (1968).
T. L. Bradley and R. E. Stickney, Surf. Sci. 38, 313 (1973).
M. Balooch and R. E. Stickney, Surf. Sci. 44, 310 (1974).
G. Comsa and R. David, Surf. Sci. 117, 77 (1982).
G. Comsa and R. David, Surf. Sci. Rep. 5, 145 (1985).
G. Comsa and R. David, Chem. Phys. Lett. 49, 512 (1977).
M. Balooch, M. J. Cardillo, D. R. Miller, and R. E. Stickney, Surf. Sci. 46, 358 (1974).
T. Engel and G. Ertl, in: The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis (D. A. King and D. P. Woodruff, eds.), Elsevier, Amsterdam (1983).
M. J. Cardillo, M. Balooch, and R. E. Stickney, Surf. Sci. 50, 263 (1975).
J. Lapujoulade, Y. Le Cmer, M. Lefort, Y. Lejay, and E. Maurel, Surf. Sci. Lett. 103, L85 (1981);
J. Lapujoulade and J. Perreau, Phys. Scr. T4, 138 (1983).
J. Harris, S. Andersson, C. Holmberg, and P. Nordlander, Phys. Scr. T13, 155 (1986).
N. Esbjerg and J. K. N0rskov, Phys. Rev. Lett. 45, 807 (1980).
D. Halstead and S. Holloway, J. Chem. Phys. 88, 7197 (1988).
J. K. N0rskov and N. D. Lang, Phys. Rev. B 21, 2136 (1980).
M. J. Stott and E. Zaremba, Phys. Rev. B 22, 1564 (1980).
J. K. Norskov, Phys. Rev. B 26, 2875 (1982).
O. Gunnarsson, H. Hjelmberg, and B. I. Lundqvist, Phys. Rev. Lett. 37, 292 (1976).
P. Nordlander, S. Holloway, and J. K. N0rskov, Surf. Sci. 136, 59 (1984).
P. Nordlander and S. Holmström, Surf. Sci. 159, 443 (1985).
J. Harris, Z. Physik Appl. Phys. A 47, 63 1988.
J. K. N0rskov, A. Houm0ller, P. Johansson, and B. I. Lundqvist, Phys. Rev. Lett. 76, 257 (1981).
J. Harris, S. Holloway, T. Rahman, and K. Yang, J. Chem. Phys. 89, 4427 (1988).
W. Brenig and H. Kasai, Surf. Sci. 213, 170 (1989).
J. B. Anderson, J. Chem. Phys. 58, 4684 (1973).
P. K. Johansson, Surf. Sci. 104, 510 (1981).
R. D. Levine and R. B. Bernstein, Molecular Reaction Dynamics and Chemical Reactivity, Oxford University Press, Oxford (1987).
J. A. Fleck Jr., J. R. Morris, and M. D. Feit, Appl. Phys. 10, 129 (1976);
M. D. Feit, J. A. Fleck, and A. Steiger, J. Comput. Phys. 47, 412 (1982).
B. Jackson and H. Methiu, J. Chem. Phys. 86, 1026 (1986).
S. Holloway, D. Halstead, and A. Hodgson,J. Electron Spectrosc. Relat. Phenom. 45, 207 (1987);
S. Holloway, D. Halstead, and A. Hodgson, Chem. Phys. Lett. 147, 425 (1988);
M. R. Hand and S. Holloway, J. Chem. Phys. 91, 7209 (1989).
S. Holloway, J. Vac. Sci. Technol. A5, 476 (1987).
Chao-Ming Chiang and Bret Jackson, J. Chem. Phys. 87, 5497 (1987).
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Holloway, S. (1990). Theory of Adsorption-Desorption Kinetics and Dynamics. In: Bortolani, V., March, N.H., Tosi, M.P. (eds) Interaction of Atoms and Molecules with Solid Surfaces. Physics of Solids and Liquids. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8777-0_17
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DOI: https://doi.org/10.1007/978-1-4684-8777-0_17
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