Chemical Bond Approach to the Structures of Chalcogenide Glasses with Reversible Switching Properties

  • Josef Bicerano
  • Stanford R. Ovshinsky
Part of the Institute for Amorphous Studies Series book series (IASS)


Since the publication of the paper announcing the discovery of reversible switching phenomena in certain types of chalcogenide glasses [1], much effort has been devoted towards the characterization, improvement, and understanding of the properties of these materials [2]. This interest has been stimulated both by the basic scientific questions that have to be answered in order to understand the structures and properties of these alloys, and by their obvious potential as reversible threshold and memory switching elements in a wide variety of electronic devices [2,3].


Cohesive Energy Structural Phase Transition Chalcogenide Glass Average Coordination Number Memory Material 
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  1. [1]
    S.R. Ovshinsky, Phys. Rev. Lett. 21 (1968) 1450.ADSCrossRefGoogle Scholar
  2. [2]
    S.R. Ovshinsky, in: Physical Properties of Amorphous Materials, eds., D. Adler, B.B. Schwartz and M.C. Steele, Institute for Amorphous Studies Series, Vol. 1, Ch. 2 (Plenum, New York, 1985).Google Scholar
  3. [3]
    S.R. Ovshinsky, J. de Phys., C4, Suppl. 10, 42 (1981) C4–1095.Google Scholar
  4. [4]
    M. Kastner, D. Adler and H. Fritzsche, Phys. Rev. Lett. 37 (1976) 1504ADSCrossRefGoogle Scholar
  5. [4a]
    M. Kastner, J. Non-Crystalline Solids 31 (1978) 223ADSCrossRefGoogle Scholar
  6. [4b]
    D. Adler, J. de Phys. C4 Suppl. 10, 42 (1981) C4–3.Google Scholar
  7. [5]
    S.R. Ovshinsky and K. Sapru, Proc. 5th Int. Conf. on Amorphous and Liquid Semiconductors, eds., J. Stuke and W. Brenig, (1974) p. 447Google Scholar
  8. [5a]
    S.R. Ovshinsky, Phys. Rev. Lett. 36 (1976) 1469ADSCrossRefGoogle Scholar
  9. [5b]
    S.R. Ovshinsky, Proc. Int. Topical Conf. on Structure and Excitation of Amorphous Solids, Williamsburg, VA, March 24–27, 1976, p. 31.Google Scholar
  10. [6]
    J.P. deNeufville and H.K. Rockstad, Proc. 5th Int. Conf. on Amorphous and Liquid Semiconductors, eds., J. Stuke and W. Brenig (1974) p. 419Google Scholar
  11. [6a]
    D.J. Sarrach, J.P. deNeufville and W.L. Haworth, J. Non-Crystalline Solids 22 (1976) 245ADSCrossRefGoogle Scholar
  12. [6b]
    T. Shimizu, R. Negishi and N. Ishii, J. Non-Crystalline Solids 31 (1979) 287ADSCrossRefGoogle Scholar
  13. [6c]
    N. Tohge, T. Minami and M. Tanaka, J. Non-Crystalline Solids 38&39 (1980) 283; see also ref. [18].ADSCrossRefGoogle Scholar
  14. [7]
    D. Adler, H.K. Henisch and N. Mott, Rev. Mod. Phys. 50 (1978) 209ADSCrossRefGoogle Scholar
  15. [7a]
    D. Adler, M.S. Shur, M. Silver and S.R. Ovshinsky, J. Appl. Phys. 51 (1980) 3289ADSCrossRefGoogle Scholar
  16. [7b]
    S.R. Ovshinsky, J. Non-Crystalline Solids 2 (1970) 99.ADSCrossRefGoogle Scholar
  17. [8]
    S.C. Moss and J.P. deNeufville, Mat. Res. Bull. 7 (1972) 423CrossRefGoogle Scholar
  18. [8a]
    H.K. Rockstad and R. Flasck, Proc. 5th Int. Conf. on Amorphous and Liquid Semiconductors, eds., J. Stuke and W. Brenig (1974) p. 1311; N. Formigoni, unpublished experimental results; S.R. Ovshinsky, unpublished exp. results.Google Scholar
  19. [9]
    W.H. Zachariasen, J. Am. Chem. Soc. 54 (1932) 3841.CrossRefGoogle Scholar
  20. [10]
    L. Pauling, The Nature of the Chemical Bond, 3rd ed. (Cornell University Press, 1960) p. 91.Google Scholar
  21. [11]
    A.L. Allred, J. Inorg. Nucl. Chem. 17 (1961) 215.CrossRefGoogle Scholar
  22. [12]
    C. Kittel, Introduction to Solid State Physics, 5th ed. (Wiley, New York, 1976) p. 74.Google Scholar
  23. [13]
    H. F Schaefer III, The Electronic Structure of Atoms and Molecules (Addison-Wesley, New York. 1972).Google Scholar
  24. [14]
    Research on the Properties of Amorphous Semiconductors at High Temperature, ARPA Contract DAHC 15–70-C0187, Final Technical Report (1973).Google Scholar
  25. [15]
    Handbook of Chemistry and Physics, 64th ed., R.C. Weast. ed. (CRC Press, 1983) pp. B-33 and B-34.Google Scholar
  26. [16]
    DJ. Sarrach, J.P. DeNeufville and W.L. Haworth, J. Non-Crystalline Solids 27 (1978) 193.ADSCrossRefGoogle Scholar
  27. [17]
    R. Zallen, The Physics of Amorphous Solids (Wiley, New York, 1983) Ch. 4, 5.Google Scholar
  28. [18]
    S.R. Ovshinsky, Proc. 7th Int. Conf. on Amorphous and Liquid Semiconductors (1977), ed., W.E. Spear, p. 519Google Scholar
  29. [18]
    S.R. Ovshinsky and D. Adler, Contemp. Phys. 19 (1978) 109.ADSCrossRefGoogle Scholar
  30. [19]
    J.C. Phillips, J. Non-Crystalline Solids 35&36 (1980) 1157 and refs. therein.Google Scholar
  31. [20]
    M.F. Thorpe, J. Non-Crystalline Solids 57 (1983) 355.ADSCrossRefGoogle Scholar

Copyright information

© Plenum Press, New York 1991

Authors and Affiliations

  • Josef Bicerano
    • 1
  • Stanford R. Ovshinsky
    • 1
  1. 1.Energy Conversion Devices, Inc.TroyUSA

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