Kinetics of Homogeneous and Enzymatic Reactions Involving Charge Transfer

  • L. I. Krishtalik

Abstract

It was shown in Chapter 4 (sections 4.3–4.5) that the relations characteristic of kinetic isotope effect in hydrogen evolution reactions are in good agreement with the predictions of the reorganization model, and in contradiction to the bond stretching model. The latter model, however, has so far been used to explain the main features of the kinetic isotope effect in homogeneous proton transfer reactions[256,443].

Keywords

Entropy Hydrolysis Phenol Hydrocarbon Carboxyl 

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Copyright information

© Consultants Bureau, New York 1986

Authors and Affiliations

  • L. I. Krishtalik
    • 1
  1. 1.Institute of ElectrochemistryAcademy of Sciences of the USSRMoscowUSSR

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