An X-Ray Fluorescent Method for the Determination of Copper in Silver-Copper Alloys

  • A. Carnevale
  • A. J. Lincoln
Part of the Developments in Applied Spectroscopy book series (DAIS, volume 5)


An X-ray method for the production control of silver in silver-copper alloys is described. The silver is determined by difference using the CuK αline (1.54 A). The preparation of standards and the procedure for sampling production melts are discussed. Specimen surfaces are prepared by a lapping machine technique which is highly reproducible and minimizes required operator skills. An external standard technique is utilized to derive calibration curves for copper ranging to 12%. The accuracy of the method expressed as standard deviation was found to be 0.035% silver for the sterling silver alloy.


Sterling Silver External Standard Technique Lapping Machine Intensity Intensity Intensity Engelhard Industry 
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Copyright information

© Chicago Section of the Society for Applied Spectroscopy 1966

Authors and Affiliations

  • A. Carnevale
    • 1
  • A. J. Lincoln
    • 1
  1. 1.Research & Development DivisionEngelhard Industries, Inc.NewarkUSA

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