Abstract
Normal coordinate analysis has been carried out for the trigonal bipyramidal XY5 -type molecules, and the results have been applied to SbCl5, SbF5, PCl5, and PF5 using the Urey—Bradley force field. It has been found that the introduction of an angle—angle interaction force constant to the simple Urey—Bradley force field is necessary to obtain good agreement between calculated and observed frequencies. The results provide consistent band assignments and force constants for the four molecules studied.
To be submitted by Robert A. Condrate to the faculty of Illinois Institute of Technology in partial fulfillment of the requirements for the degree of Doctor of Philosophy.
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© 1964 Chicago Section of the Society for Applied Spectroscopy
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Condrate, R.A., Nakamoto, K. (1964). The Urey — Bradley Force Constants of Trigonal Bipyramidal XY5 -Type Molecules. In: Forrette, J.E., Lanterman, E. (eds) Developments in Applied Spectroscopy. Developments in Applied Spectroscopy, vol 3. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8688-9_13
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DOI: https://doi.org/10.1007/978-1-4684-8688-9_13
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