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Solvent Effects on the Infrared Spectra of Organophosphorus Compounds

  • John R. Ferraro
Part of the Developments in Applied Spectroscopy book series (DAIS, volume 2)

Abstract

Solvent effects on the P→O and [P-0]G absorptions in organophosphorus compounds of the type (GO)3P→0, (GO)2G-P→0, [(GO)G-PO(OH)]2, [(GO)2PO(OH)]2, and G3P→O are described, in which G is an alkyl or aryl group. The unassociated phosphoryl dipoles are affected by solvents in a manner similar to the carbonyl dipole. The consequences of the solvent effects on the physical properties of these compounds are discussed.

Keywords

Carbon Tetrachloride Solvent Effect Organophosphorus Compound Methyl Isobutyl Phoric Acid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Society for Applied Spectroscopy Chicago, Illinois 1963

Authors and Affiliations

  • John R. Ferraro
    • 1
  1. 1.Argonne National LaboratoryArgonneUSA

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