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Solvent Effects on the Infrared Spectra of Organophosphorus Compounds

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Book cover Developments in Applied Spectroscopy

Part of the book series: Developments in Applied Spectroscopy ((DAIS,volume 2))

Abstract

Solvent effects on the P→O and [P-0]G absorptions in organophosphorus compounds of the type (GO)3P→0, (GO)2G-P→0, [(GO)G-PO(OH)]2, [(GO)2PO(OH)]2, and G3P→O are described, in which G is an alkyl or aryl group. The unassociated phosphoryl dipoles are affected by solvents in a manner similar to the carbonyl dipole. The consequences of the solvent effects on the physical properties of these compounds are discussed.

Published in the Journal of Applied Spectroscopy.

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Authors and Affiliations

  1. Argonne National Laboratory, Argonne, Illinois, USA

    John R. Ferraro

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  1. John R. Ferraro
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J. R. Ferraro J. S. Ziomek

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© 1963 Society for Applied Spectroscopy Chicago, Illinois

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Ferraro, J.R. (1963). Solvent Effects on the Infrared Spectra of Organophosphorus Compounds. In: Ferraro, J.R., Ziomek, J.S. (eds) Developments in Applied Spectroscopy. Developments in Applied Spectroscopy, vol 2. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8685-8_12

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  • DOI: https://doi.org/10.1007/978-1-4684-8685-8_12

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-8687-2

  • Online ISBN: 978-1-4684-8685-8

  • eBook Packages: Springer Book Archive

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