Properties of Alkali Thio- and Selenoantimonides and Their Correlation with Chemical Bonding

  • S. I. Berul’
  • Ya. G. Finkel’shtein
  • N. P. Luzhnaya


Eight ternary compounds were synthesized and six of them were obtained for the first time. All these compounds had semiconducting properties. An approximate calculation of the bond ionicity Bi gave 25–28% for the thioantimonides and 20–23% for the selenoantimonides. This demonstrated that the dominant component of the bonding was covalent.


Ternary Compound Bond Ionicity Metal Fluoride Metallic Luster Tice Energy 
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Literature Cited

  1. 1.
    J. H. Wernick and K. E. Benson, J. Phys. Chem. Solids, 3: 157 (1957).CrossRefGoogle Scholar
  2. 2.
    L. I. Berger and R. Annamamedov, lzv. Akad. Nauk Turkm. SSR, Ser. Fiz.-Tekh. Khim. Geol. Nauk, No. 2, p. 129 (1965).Google Scholar
  3. 3.
    D. C. Bok and J. de Wit, Z. Anorg. Allg. Chem., 324: 162 (1963).CrossRefGoogle Scholar
  4. 4.
    E. D. Nensberg and E. L. Shtrum, Fiz. Tverd. Tela, 5: 3357 (1963).Google Scholar
  5. 5.
    L. Cambi, M. Elli, and I. Tangerini, Chim. Ind. (Milan), 47: 136 (1965).Google Scholar
  6. 6.
    N. Konopik and K. Fiala, Monatsh. Chem., 81: 497 (1950).CrossRefGoogle Scholar
  7. 7.
    G. Busch and F. Hulliger, Helv. Phys. Acta, 33: 657 (1960).Google Scholar
  8. 8.
    G. Gattow and J. Zemann, Z. Anorg. Allg. Chem., 279: 324 (1955).CrossRefGoogle Scholar
  9. 9.
    O. Glemser and M. Filcek, Z. Anorg. Allg. Chem., 279: 321 (1955).CrossRefGoogle Scholar
  10. 10.
    I. W. Boon, Recl. Tray. Chim. Pays-Bas, 63: 32 (1944).CrossRefGoogle Scholar
  11. 11.
    J. Berzelius, Pogg. Ann., 20: 365 (1830).Google Scholar
  12. 12.
    A. Dufflos, Schweigger’s J., 62: 210 (1831).Google Scholar
  13. 13.
    I. Pouget, Ann. Chim. Phys., 18: 524 (1899).Google Scholar
  14. 14.
    H. Sommerlad, Z. Anorg. Chem., 15: 173 (1897).Google Scholar
  15. 15.
    E. I. Banashek, Dissertation [in Russian], Moscow (1949).Google Scholar
  16. 16.
    N. P. Luzhnaya, S. I. Berul’, and Ya. G. Finkel’shtein, Izv. Akad. Nauk SSSR, Neorg. Mater., 4: 342 (1968).Google Scholar
  17. 17.
    S. I. Berul’, N. P. Luzhnaya, and Ya. G. Finkel’shtein, Zh. Neorg. Khim., 13: 1265 (1968).Google Scholar
  18. 18.
    L. Pauling, The Nature of the Chemical Bond and the Structure of Molecules and Crystals, 3rd ed., Cornell University Press, New York (1960).Google Scholar

Copyright information

© Consultants Bureau, New York 1972

Authors and Affiliations

  • S. I. Berul’
  • Ya. G. Finkel’shtein
  • N. P. Luzhnaya

There are no affiliations available

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