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Effects of Substituents in Quinonoid Compounds

  • Chapter
Substituent Effects in Organic Polarography

Abstract

It was shown in Chapter II that a measure of the influence of the substituent on the redox potential of a reversible electrode system is provided by the change in the increment of the standard free energy in the interconversion of the oxidized and reduced forms. The shift in the redox potential (or half-wave potential, denoted by ΔE°1/2), defined as ΔE° 1/2 = (E°1/2)x — (E° 1/2)H (where the index X denotes the compound containing the substituent X and the index H the parent reference compound) is proportional to the difference of the logarithms of the equilibrium constants KX and KH of the corresponding reversible process

$$\Delta E{{{}^\circ }_{1/2}}\sim \ln \frac{{{K}_{X}}}{{{K}_{H}}}$$
(58)

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Authors and Affiliations

  1. Heyrovský Institute of Polarography, Czechoslovak Academy of Sciences, Prague, Czechoslovakia

    Petr Zuman

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  1. Petr Zuman
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© 1967 Plenum Press

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Zuman, P. (1967). Effects of Substituents in Quinonoid Compounds. In: Substituent Effects in Organic Polarography. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-8661-2_8

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  • DOI: https://doi.org/10.1007/978-1-4684-8661-2_8

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4684-8663-6

  • Online ISBN: 978-1-4684-8661-2

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