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Reaction Series in which the Electroactive Group is Directly Attached to an Alkyl or Aryl Substituent

  • Chapter
Substituent Effects in Organic Polarography

Abstract

In substances in which the electroactive group is attached directly to a substituent, a direct interaction between the reactive group and the substituent can take place. The shifts in the half-wave potentials of compounds of this kind, in which the polarographically active group is not cyclic system (as in some heterocyclic compounds treated in Chapter IV), are discussed in this chapter. Substituents of the type CH2X and phenyl, which exert predominantly polar effects, cause shifts in half-wave potential which follow

$$\Delta {{E}_{{1}/{2}\;}}=\rho _{\pi ,R}^{*}\sigma _{X}^{*}$$
(29)

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  1. Heyrovský Institute of Polarography, Czechoslovak Academy of Sciences, Prague, Czechoslovakia

    Petr Zuman

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Zuman, P. (1967). Reaction Series in which the Electroactive Group is Directly Attached to an Alkyl or Aryl Substituent. In: Substituent Effects in Organic Polarography. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-8661-2_5

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  • DOI: https://doi.org/10.1007/978-1-4684-8661-2_5

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