Conditions for High Yield in the Labeling of Hydrocarbons by Exchange
This report presents the results of a series of experiments to study the exchange between D2O and D2 and some hydrocarbons. The purpose was to evaluate Co/Mo/S on Al2O3 as a catalyst for this exchange, and to determine optimum conditions for yield and minimum decomposition. It was also hoped that as a result of determining the deuterium distribution in the molecule, some insight into the mechanism of exchange on this catalyst would be gained.
KeywordsRandom Exchange Deuterium Content Specific Rate Constant Label Species Deuterium Distribution
Unable to display preview. Download preview PDF.
- 4.Garnett, J. L., Nucleonics 20 (12): 86 (1962).Google Scholar
- 5.Aliprandi, B., and Cacace, F., Ann. chim. 49: 2011 (1959).Google Scholar
- 6.Aliprandi, B., and Cacace, F., Ann. chim. 50: 931 (1960).Google Scholar
- 11.Littlewood, A. B., and Burwell, R. L., Am. Chem. Soc. Meeting, Miami, Florida (1957), Div. of Petrol. Chem., Vol. 2, Paper No. 1.Google Scholar