Radiation Self-Decomposition of Labeled Compounds

  • Bert M. Tolbert

Abstract

In order to discuss self-decomposition effects in labeled compounds, it is desirable first to review radiation chemistry of organic compounds. Under the influence of ionizing radiation (alpha, beta, and gamma rays), organic compounds undergo chemical changes resulting in fragmentation, polymerization, and isomerization. Synthetic processes are as important as degradative processes in these changes. In the radiation chemistry of a given compound a few chemical products usually predominate. In addition, a great variety of other chemical products may be produced from a single pure substance [1–4].

Keywords

Clay Acetone Phenolate Benzene Hexane 

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References

  1. (1).
    Collinson, E. and Swallow, A. J. Chem. Rev. 56, 571 (1956).CrossRefGoogle Scholar
  2. (2).
    Tolbert, B. M. and Lemmon, R. M. Radiation Research 31, 52 (1955).CrossRefGoogle Scholar
  3. (3).
    Tolbert, B. M. and Krinks, M. H. Radiation Research (in press).Google Scholar
  4. (4).
    Bovey, F. A. “Effects of Ionizing Radiation on Natural and Synthetic Polymers,” Publishers, Inc., New York (1958).Google Scholar
  5. (5).
    Fano, U. In: “Symposium on Radiobiology,” pp. 13–34, Nickerson, J. J. [ed.], John Wiley and Sons, New York (1952).Google Scholar
  6. (6).
    Burton, M. J. Chem. Ed. 36, 273 (1959).CrossRefGoogle Scholar
  7. (7).
    Burton, M., Hammil, W. H., and Magee, J. L. “Second U.N. Geneva Conference,” Pergamon Press, London (1959).Google Scholar
  8. (8).
    Gordy, W. Radiation Research, Supplement 1, 491–510 (1959).Google Scholar
  9. (9).
    Manion, J. P. and Burton, M. J. Phys. Chem. 56, 560 (1952).CrossRefGoogle Scholar
  10. (10).
    Burton, M. and Lipsky, S. J. Phys. Chem. 61, 1461 (1957).CrossRefGoogle Scholar
  11. (11).
    Burton, J., Chang, J., Lipsky, S., and Reddy, M.P. Radiation Research 8, 203 (1958).CrossRefGoogle Scholar
  12. (12).
    Burton, M. and Patrick, W. N. J. Phys. Chem. 58, 421 (1954).CrossRefGoogle Scholar

Copyright information

© New England Nuclear Corporation 1963

Authors and Affiliations

  • Bert M. Tolbert
    • 1
  1. 1.Chemistry DepartmentUniversity of ColoradoBoulderUSA

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